Sr/Ca and Cd/Ca ratios of benthic foraminifera in surface deep-sea sediments

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Autori principali: Elderfield, Henry, Bertram, Caroline J, Erez, Jonathan
Natura: Dataset Open Access
Lingua:en
Pubblicazione: PANGAEA 1996
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author Elderfield, Henry
Bertram, Caroline J
Erez, Jonathan
author_facet Elderfield, Henry
Bertram, Caroline J
Erez, Jonathan
collection Datos científicos de ciencias marinas y ambientales
contents Measurements of Sr/Ca of benthic foraminifera show a linear decrease with water depth which is superimposed upon significant variability identified by analyses of individual foraminifera. New data for Cd/Ca support previous work in defining a contrast between waters shallower and deeper than ~2500 m. Measured element partition coefficients in foraminiferal calcium carbonate relative to sea water (D) have been described by means of a one-box model in which elements are extracted by Rayleigh distillation from a biomineralization reservoir that serves for calcification with a constant fractionation factor (alpha), such that D = (1 - f**alpha)/(l - f), where f is the proportion of Ca remaining after precipitation. A modification to the model recognises differences in element speciation. The model is consistent with differences between D[Sr], D[Ba], and D[Cd] in benthic but not planktonic foraminifera. Depth variations in D for Sr and Ba are consistent with the model, as are differences in depth variation of D[Cd] in calcitic and aragonitic benthic foraminifera. The shallower depth variations may reflect increasing calcification rates with increasing water depth to an optimum of about 2500 m. Observations of unusually lower DCd for some deep waters, not accompanied by similar [Sr], or D[Ba] may be because of dissolution or a calcification response to a lower carbonate saturation state.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_708384
institution PANGAEA
language en
publishDate 1996
publisher PANGAEA
record_format pangaea
spellingShingle Sr/Ca and Cd/Ca ratios of benthic foraminifera in surface deep-sea sediments
Elderfield, Henry
Bertram, Caroline J
Erez, Jonathan
BC; Biogeochemical Ocean Flux Study; BOFS; BOFS10K; BOFS11882#4; BOFS11890#2; BOFS11896#1; BOFS11905#1; BOFS14K; BOFS17K; BOFS5K; Box corer; Charles Darwin; D184; Discovery (1962); JGOFS; Joint Global Ocean Flux Study; KAL; Kasten corer; NEAP; NEAP-02B; NEAP-05B; NEAP-08B; NEAP-10B; NEAP-18B; NEAP-19B; NEAP-20B; Northeast Atlantic; PC; Piston corer; TR163-31; V22; V22-197; V27; V27-60; Vema
Measurements of Sr/Ca of benthic foraminifera show a linear decrease with water depth which is superimposed upon significant variability identified by analyses of individual foraminifera. New data for Cd/Ca support previous work in defining a contrast between waters shallower and deeper than ~2500 m. Measured element partition coefficients in foraminiferal calcium carbonate relative to sea water (D) have been described by means of a one-box model in which elements are extracted by Rayleigh distillation from a biomineralization reservoir that serves for calcification with a constant fractionation factor (alpha), such that D = (1 - f**alpha)/(l - f), where f is the proportion of Ca remaining after precipitation. A modification to the model recognises differences in element speciation. The model is consistent with differences between D[Sr], D[Ba], and D[Cd] in benthic but not planktonic foraminifera. Depth variations in D for Sr and Ba are consistent with the model, as are differences in depth variation of D[Cd] in calcitic and aragonitic benthic foraminifera. The shallower depth variations may reflect increasing calcification rates with increasing water depth to an optimum of about 2500 m. Observations of unusually lower DCd for some deep waters, not accompanied by similar [Sr], or D[Ba] may be because of dissolution or a calcification response to a lower carbonate saturation state.
title Sr/Ca and Cd/Ca ratios of benthic foraminifera in surface deep-sea sediments
topic BC; Biogeochemical Ocean Flux Study; BOFS; BOFS10K; BOFS11882#4; BOFS11890#2; BOFS11896#1; BOFS11905#1; BOFS14K; BOFS17K; BOFS5K; Box corer; Charles Darwin; D184; Discovery (1962); JGOFS; Joint Global Ocean Flux Study; KAL; Kasten corer; NEAP; NEAP-02B; NEAP-05B; NEAP-08B; NEAP-10B; NEAP-18B; NEAP-19B; NEAP-20B; Northeast Atlantic; PC; Piston corer; TR163-31; V22; V22-197; V27; V27-60; Vema
url https://doi.org/10.1594/PANGAEA.708384