Organic matter and trace element concentrations in sapropels from ODP Leg 160 sites

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Hauptverfasser: Nijenhuis, Ivar A, Bosch, Hendrik-Jan, Sinninghe Damsté, Jaap S, Brumsack, Hans-Jürgen, de Lange, Gert J
Format: Dataset Open Access
Sprache:en
Veröffentlicht: PANGAEA 1999
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author Nijenhuis, Ivar A
Bosch, Hendrik-Jan
Sinninghe Damsté, Jaap S
Brumsack, Hans-Jürgen
de Lange, Gert J
author_facet Nijenhuis, Ivar A
Bosch, Hendrik-Jan
Sinninghe Damsté, Jaap S
Brumsack, Hans-Jürgen
de Lange, Gert J
collection Datos científicos de ciencias marinas y ambientales
contents A distinct Pliocene eastern Mediterranean sapropel (i-282), recovered from three Ocean Drilling Program (ODP) Leg 160 Sites, has been investigated for its organic and inorganic composition. This sapropel is characterized by high organic carbon (Corg) and trace element contents, and the presence of isorenieratene derivatives. The latter suggests that the base of the photic zone was sulphidic during formation of the sapropel. Combined with evidence of bottom water anoxia (preservation of laminae, high redox-sensitive trace element contents, and the abundance and isotopic composition of pyrite) this leads to the tentative conclusion that almost the entire water column may have been anoxic. This anoxia resulted from high productivity and not from stagnation, because an approximation of the trace element budget during sapropel formation shows that water exchange with the western Mediterranean is needed. Entire water column anoxia has been suggested earlier for several black shales. With regard to the depositional environment and the Corg content, however, only the Cenomanian=Turonian Boundary Event (CTBE) black shales appear to be comparable to this sapropel. The proposed trace element removal mechanism of scavenging and (co-)precipitation in an anoxic water column, is thought to be similar for both types of deposits. The ultimate trace element source for the sapropel, however, is seawater, whereas it is hydrothermal and fluvial input for CTBE black shales (because they have a larger temporal and spatial distribution). Nonetheless, the Corg-rich eastern Mediterranean Pliocene sapropel discussed here may be considered to be a younger analogue of CTBE black shales.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_714946
institution PANGAEA
language en
publishDate 1999
publisher PANGAEA
record_format pangaea
spellingShingle Organic matter and trace element concentrations in sapropels from ODP Leg 160 sites
Nijenhuis, Ivar A
Bosch, Hendrik-Jan
Sinninghe Damsté, Jaap S
Brumsack, Hans-Jürgen
de Lange, Gert J
160-964D; 160-964E; 160-966C; 160-967C; 160-969E; DRILL; Drilling/drill rig; Eastern Basin; Joides Resolution; Leg160; Ocean Drilling Program; ODP
A distinct Pliocene eastern Mediterranean sapropel (i-282), recovered from three Ocean Drilling Program (ODP) Leg 160 Sites, has been investigated for its organic and inorganic composition. This sapropel is characterized by high organic carbon (Corg) and trace element contents, and the presence of isorenieratene derivatives. The latter suggests that the base of the photic zone was sulphidic during formation of the sapropel. Combined with evidence of bottom water anoxia (preservation of laminae, high redox-sensitive trace element contents, and the abundance and isotopic composition of pyrite) this leads to the tentative conclusion that almost the entire water column may have been anoxic. This anoxia resulted from high productivity and not from stagnation, because an approximation of the trace element budget during sapropel formation shows that water exchange with the western Mediterranean is needed. Entire water column anoxia has been suggested earlier for several black shales. With regard to the depositional environment and the Corg content, however, only the Cenomanian=Turonian Boundary Event (CTBE) black shales appear to be comparable to this sapropel. The proposed trace element removal mechanism of scavenging and (co-)precipitation in an anoxic water column, is thought to be similar for both types of deposits. The ultimate trace element source for the sapropel, however, is seawater, whereas it is hydrothermal and fluvial input for CTBE black shales (because they have a larger temporal and spatial distribution). Nonetheless, the Corg-rich eastern Mediterranean Pliocene sapropel discussed here may be considered to be a younger analogue of CTBE black shales.
title Organic matter and trace element concentrations in sapropels from ODP Leg 160 sites
topic 160-964D; 160-964E; 160-966C; 160-967C; 160-969E; DRILL; Drilling/drill rig; Eastern Basin; Joides Resolution; Leg160; Ocean Drilling Program; ODP
url https://doi.org/10.1594/PANGAEA.714946