Pore-water concentration of chloride in sediment cores and equilibrium temperatures and gas bubble analysis at ROV stations from the Vodyanitskii mud volcano

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Autori principali: Sahling, Heiko, Bohrmann, Gerhard, Artemov, Yuriy G, Bahr, André, Brüning, Markus, Klapp, Stephan A, Klaucke, Ingo, Kozlova, Elena, Nikolovska, Aneta, Pape, Thomas, Reitz, Anja, Wallmann, Klaus
Natura: Dataset Open Access
Lingua:en
Pubblicazione: PANGAEA 2010
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author Sahling, Heiko
Bohrmann, Gerhard
Artemov, Yuriy G
Bahr, André
Brüning, Markus
Klapp, Stephan A
Klaucke, Ingo
Kozlova, Elena
Nikolovska, Aneta
Pape, Thomas
Reitz, Anja
Wallmann, Klaus
author_facet Sahling, Heiko
Bohrmann, Gerhard
Artemov, Yuriy G
Bahr, André
Brüning, Markus
Klapp, Stephan A
Klaucke, Ingo
Kozlova, Elena
Nikolovska, Aneta
Pape, Thomas
Reitz, Anja
Wallmann, Klaus
collection Datos científicos de ciencias marinas y ambientales
contents Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to 650 mmol L**-1 at 150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at 60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (dD-CH4 = -170.8 per mil (SMOW), d13C-CH4 = -61.0 per mil (V-PDB), d13C-C2H6 = -44.0 per mil (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 x 10**6 mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_737657
institution PANGAEA
language en
publishDate 2010
publisher PANGAEA
record_format pangaea
spellingShingle Pore-water concentration of chloride in sediment cores and equilibrium temperatures and gas bubble analysis at ROV stations from the Vodyanitskii mud volcano
Sahling, Heiko
Bohrmann, Gerhard
Artemov, Yuriy G
Bahr, André
Brüning, Markus
Klapp, Stephan A
Klaucke, Ingo
Kozlova, Elena
Nikolovska, Aneta
Pape, Thomas
Reitz, Anja
Wallmann, Klaus
Center for Marine Environmental Sciences; GC; GC-1; GC-28; GeoB11913; GeoB11917; GeoB11917-2; GeoB11990; Gravity corer; M72/3a; M72/3b; MARUM; Meteor (1986); Remote operated vehicle; ROV; ROV-7; TST; T-Stick; T-stick-1; Vodyanitskii Mud Volcano
Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to 650 mmol L**-1 at 150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at 60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (dD-CH4 = -170.8 per mil (SMOW), d13C-CH4 = -61.0 per mil (V-PDB), d13C-C2H6 = -44.0 per mil (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 x 10**6 mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.
title Pore-water concentration of chloride in sediment cores and equilibrium temperatures and gas bubble analysis at ROV stations from the Vodyanitskii mud volcano
topic Center for Marine Environmental Sciences; GC; GC-1; GC-28; GeoB11913; GeoB11917; GeoB11917-2; GeoB11990; Gravity corer; M72/3a; M72/3b; MARUM; Meteor (1986); Remote operated vehicle; ROV; ROV-7; TST; T-Stick; T-stick-1; Vodyanitskii Mud Volcano
url https://doi.org/10.1594/PANGAEA.737657