Carbonate system data on the Molokai reef flat

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Auteurs principaux: Yates, Kimberly Kaye, Halley, Roberet B
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 2006
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author Yates, Kimberly Kaye
Halley, Roberet B
author_facet Yates, Kimberly Kaye
Halley, Roberet B
collection Datos científicos de ciencias marinas y ambientales
contents The severity of the impact of elevated atmospheric pCO2 to coral reef ecosystems depends, in part, on how seawater pCO2 affects the balance between calcification and dissolution of carbonate sediments. Presently, there are insufficient published data that relate concentrations of pCO2 and CO3**2- to in situ rates of reef calcification in natural settings to accurately predict the impact of elevated atmospheric pCO2 on calcification and dissolution processes. Rates of net calcification and dissolution, CO3**2- concentrations, and pCO2 were measured, in situ, on patch reefs, bare sand, and coral rubble on the Molokai reef flat in Hawaii. Rates of calcification ranged from 0.03 to 2.30 mmol CaCO3/m**2/h and dissolution ranged from -0.05 to -3.3 mmol CaCO3/m**2/h. Calcification and dissolution varied diurnally with net calcification primarily occurring during the day and net dissolution occurring at night. These data were used to calculate threshold values for pCO2 and CO3**2- at which rates of calcification and dissolution are equivalent. Results indicate that calcification and dissolution are linearly correlated with both CO3**2- and pCO2. Threshold pCO2 and CO3**2- values for individual substrate types showed considerable variation. The average pCO2 threshold value for all substrate types was 654±195 µatm and ranged from 467 to 1003 µatm. The average CO3**2- threshold value was 152±24 µmol/kg, ranging from 113 to 184 µmol/kg. Ambient seawater measurements of pCO2 and CO3**2- indicate that CO3**2- and pCO2 threshold values for all substrate types were both exceeded, simultaneously, 13% of the time at present day atmospheric pCO2 concentrations. It is predicted that atmospheric pCO2 will exceed the average pCO2 threshold value for calcification and dissolution on the Molokai reef flat by the year 2100.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_743388
institution PANGAEA
language en
publishDate 2006
publisher PANGAEA
record_format pangaea
spellingShingle Carbonate system data on the Molokai reef flat
Yates, Kimberly Kaye
Halley, Roberet B
Benthos; Calcification/Dissolution; Coast and continental shelf; Entire community; EPOCA; EUR-OCEANS; European network of excellence for Ocean Ecosystems Analysis; European Project on Ocean Acidification; Field experiment; Hawaiian Arch; Mesocosm or benthocosm; Molokai_reef; North Pacific; OA-ICC; OCE; Ocean acidification; Ocean Acidification International Coordination Centre; Oceanography; Rocky-shore community; Tropical; Water sample; WS; YH_06
The severity of the impact of elevated atmospheric pCO2 to coral reef ecosystems depends, in part, on how seawater pCO2 affects the balance between calcification and dissolution of carbonate sediments. Presently, there are insufficient published data that relate concentrations of pCO2 and CO3**2- to in situ rates of reef calcification in natural settings to accurately predict the impact of elevated atmospheric pCO2 on calcification and dissolution processes. Rates of net calcification and dissolution, CO3**2- concentrations, and pCO2 were measured, in situ, on patch reefs, bare sand, and coral rubble on the Molokai reef flat in Hawaii. Rates of calcification ranged from 0.03 to 2.30 mmol CaCO3/m**2/h and dissolution ranged from -0.05 to -3.3 mmol CaCO3/m**2/h. Calcification and dissolution varied diurnally with net calcification primarily occurring during the day and net dissolution occurring at night. These data were used to calculate threshold values for pCO2 and CO3**2- at which rates of calcification and dissolution are equivalent. Results indicate that calcification and dissolution are linearly correlated with both CO3**2- and pCO2. Threshold pCO2 and CO3**2- values for individual substrate types showed considerable variation. The average pCO2 threshold value for all substrate types was 654±195 µatm and ranged from 467 to 1003 µatm. The average CO3**2- threshold value was 152±24 µmol/kg, ranging from 113 to 184 µmol/kg. Ambient seawater measurements of pCO2 and CO3**2- indicate that CO3**2- and pCO2 threshold values for all substrate types were both exceeded, simultaneously, 13% of the time at present day atmospheric pCO2 concentrations. It is predicted that atmospheric pCO2 will exceed the average pCO2 threshold value for calcification and dissolution on the Molokai reef flat by the year 2100.
title Carbonate system data on the Molokai reef flat
topic Benthos; Calcification/Dissolution; Coast and continental shelf; Entire community; EPOCA; EUR-OCEANS; European network of excellence for Ocean Ecosystems Analysis; European Project on Ocean Acidification; Field experiment; Hawaiian Arch; Mesocosm or benthocosm; Molokai_reef; North Pacific; OA-ICC; OCE; Ocean acidification; Ocean Acidification International Coordination Centre; Oceanography; Rocky-shore community; Tropical; Water sample; WS; YH_06
url https://doi.org/10.1594/PANGAEA.743388