Marine barite in sediments of DSDP Site 54-424

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1. Verfasser: Varnavas, Soterios
Format: Dataset Open Access
Sprache:en
Veröffentlicht: PANGAEA 1987
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_version_ 1867171360841662464
author Varnavas, Soterios
author_facet Varnavas, Soterios
collection Datos científicos de ciencias marinas y ambientales
contents The distribution of barite in sediments from D.S.D.P. sites 424 and 424A at the Galapagos hydrothermal mounds field is determined and the process of its formation is deduced. Barite in these deposits is associated with calcareous sediments and is completely absent from the hydrothermal material (manganese crusts and nontronite). Its concentrations tend to increase in the deeper sediments. Since manganese crusts contain significant amounts of Ba, a lack of barite in them is probably due to low concentrations of [SO4]2 in the sediment-seawater interface where they form. The formation of barite occurs within buried sediments, the interstitial waters of which are saturated with [SO4]2. The most probable source of [SO4]2- is the oxidation of H2S which is released from the hydrothermal fluids percolating upwards through the sediments. Although nontronite is formed within buried sediments the environmental conditions occurring during its formation (reducing) prevent barite formation. The association of barite with calcareous sediments is due to the release of Ba by calcareous microorganisms and/or to high concentrations of Ca in the pore waters which maintain a high pH and hence [SO4]2- is stable.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_756995
institution PANGAEA
language en
publishDate 1987
publisher PANGAEA
record_format pangaea
spellingShingle Marine barite in sediments of DSDP Site 54-424
Varnavas, Soterios
54-424; 54-424A; Deep Sea Drilling Project; DRILL; Drilling/drill rig; DSDP; Glomar Challenger; Leg54; North Pacific/MOUND
The distribution of barite in sediments from D.S.D.P. sites 424 and 424A at the Galapagos hydrothermal mounds field is determined and the process of its formation is deduced. Barite in these deposits is associated with calcareous sediments and is completely absent from the hydrothermal material (manganese crusts and nontronite). Its concentrations tend to increase in the deeper sediments. Since manganese crusts contain significant amounts of Ba, a lack of barite in them is probably due to low concentrations of [SO4]2 in the sediment-seawater interface where they form. The formation of barite occurs within buried sediments, the interstitial waters of which are saturated with [SO4]2. The most probable source of [SO4]2- is the oxidation of H2S which is released from the hydrothermal fluids percolating upwards through the sediments. Although nontronite is formed within buried sediments the environmental conditions occurring during its formation (reducing) prevent barite formation. The association of barite with calcareous sediments is due to the release of Ba by calcareous microorganisms and/or to high concentrations of Ca in the pore waters which maintain a high pH and hence [SO4]2- is stable.
title Marine barite in sediments of DSDP Site 54-424
topic 54-424; 54-424A; Deep Sea Drilling Project; DRILL; Drilling/drill rig; DSDP; Glomar Challenger; Leg54; North Pacific/MOUND
url https://doi.org/10.1594/PANGAEA.756995