Victoria Land Antarctica Pb and Ba concentrations and Pb isotope ratios 1872-1994 CE

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Autori principali: Van de Velde, K, Vallelonga, Paul T, Candelone, Jean-Pierre, Rosman, K J R, Gaspari, Vania, Cozzi, Giulio, Barbante, Carlo, Udisti, Roberto, Cescon, Paolo, Boutron, Claude F
Natura: Dataset Open Access
Lingua:en
Pubblicazione: PANGAEA 2011
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author Van de Velde, K
Vallelonga, Paul T
Candelone, Jean-Pierre
Rosman, K J R
Gaspari, Vania
Cozzi, Giulio
Barbante, Carlo
Udisti, Roberto
Cescon, Paolo
Boutron, Claude F
author_facet Van de Velde, K
Vallelonga, Paul T
Candelone, Jean-Pierre
Rosman, K J R
Gaspari, Vania
Cozzi, Giulio
Barbante, Carlo
Udisti, Roberto
Cescon, Paolo
Boutron, Claude F
collection Datos científicos de ciencias marinas y ambientales
contents Pb and Ba concentrations and Pb isotopic compositions are reported for firn core and snow pit samples from Victoria Land, Antarctica, dating from 1872 AD to 1994 AD. From variations in Pb/Ba ratios and Pb isotopic compositions, two periods of major Pb enhancements were identified, from 1891 to 1908 AD and from 1948 to 1994 AD. The earlier pollution event is attributed to Pb emissions from non-ferrous metal production and coal combustion in the Southern Hemisphere and is in excellent agreement with coincident pollution inputs reported in firn/ice cores from two other regions of Antarctica, at Coats Land and Law Dome. Using Pb isotopic systematics, it was calculated that ~50% of Pb deposited in Victoria Land in 1897 originated from anthropogenic emission sources. The more recent period of Pb enhancements, from 1948 to 1994 AD, corresponds to the introduction and widespread use of gasoline alkyl Pb additives in automobiles in the Southern Hemisphere, with anthropogenic Pb inputs averaging 60% of total Pb but with large uncertainty. Intra- and inter-annual variations in Pb concentrations and isotopic compositions were evaluated in snow pits samples corresponding to the period 1991-1994. Substantial variations in Pb/ Ba and 206Pb/207Pb ratios were detected but the absence of a regular seasonal pattern for these parameters suggests that the transport and deposition of aerosols to the Antarctic ice sheet are complex and vary from year to year.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_763778
institution PANGAEA
language en
publishDate 2011
publisher PANGAEA
record_format pangaea
spellingShingle Victoria Land Antarctica Pb and Ba concentrations and Pb isotope ratios 1872-1994 CE
Van de Velde, K
Vallelonga, Paul T
Candelone, Jean-Pierre
Rosman, K J R
Gaspari, Vania
Cozzi, Giulio
Barbante, Carlo
Udisti, Roberto
Cescon, Paolo
Boutron, Claude F
Electromechanical drill, dry hole; EMD-D; Hercules_Neve; Hercules Neve, Victoria Land, Antarctica; SNOWPIT; Snow pit; Styx; Styx Glacier, Victoria Land, Antarctica
Pb and Ba concentrations and Pb isotopic compositions are reported for firn core and snow pit samples from Victoria Land, Antarctica, dating from 1872 AD to 1994 AD. From variations in Pb/Ba ratios and Pb isotopic compositions, two periods of major Pb enhancements were identified, from 1891 to 1908 AD and from 1948 to 1994 AD. The earlier pollution event is attributed to Pb emissions from non-ferrous metal production and coal combustion in the Southern Hemisphere and is in excellent agreement with coincident pollution inputs reported in firn/ice cores from two other regions of Antarctica, at Coats Land and Law Dome. Using Pb isotopic systematics, it was calculated that ~50% of Pb deposited in Victoria Land in 1897 originated from anthropogenic emission sources. The more recent period of Pb enhancements, from 1948 to 1994 AD, corresponds to the introduction and widespread use of gasoline alkyl Pb additives in automobiles in the Southern Hemisphere, with anthropogenic Pb inputs averaging 60% of total Pb but with large uncertainty. Intra- and inter-annual variations in Pb concentrations and isotopic compositions were evaluated in snow pits samples corresponding to the period 1991-1994. Substantial variations in Pb/ Ba and 206Pb/207Pb ratios were detected but the absence of a regular seasonal pattern for these parameters suggests that the transport and deposition of aerosols to the Antarctic ice sheet are complex and vary from year to year.
title Victoria Land Antarctica Pb and Ba concentrations and Pb isotope ratios 1872-1994 CE
topic Electromechanical drill, dry hole; EMD-D; Hercules_Neve; Hercules Neve, Victoria Land, Antarctica; SNOWPIT; Snow pit; Styx; Styx Glacier, Victoria Land, Antarctica
url https://doi.org/10.1594/PANGAEA.763778