Sulphur isotope analyses in the southern ocean and the central Dronning Maud Land, East Antarctica

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Main Authors: Wand, Ulrich, Maaß, Ingeborg, Haendel, Dietmar
Format: Dataset Open Access
Language:en
Published: PANGAEA 1992
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author Wand, Ulrich
Maaß, Ingeborg
Haendel, Dietmar
author_facet Wand, Ulrich
Maaß, Ingeborg
Haendel, Dietmar
collection Datos científicos de ciencias marinas y ambientales
contents Sulphur isotope analyses are an important tool for the study of the natural sulphur cycle. On the northern hemisphere such studies of the atmospheric part of the cycle are practically impossible due to the high emission rate of anthropogenic sulphur. Merely in remote areas of the world such as the Antarctic 34S analyses can be used to identify the various sulphur sources (sea spray, biogenic und volcanic sources). We report here results of 34S measurements on sulphates from recent atmospheric precipitations (snow), lake waters, and salt efflorescences sampled in the Schirmacher Oasis and the Gruber Mountains, central Dronning Maud Land, East Antarctica. By plotting the delta 34S of precipitation versus % sea-spray sulphate the isotopic composition of the excess sulphate (which is probably of marine-biogenic origin) is extrapolated to be +4 per mil. Lake water sulphate and atmospheric precipitations have a comparable sulphur isotope composition (about +5 per mil). The analyzed secondary sulphates from the salt efflorescences, mainly gypsum and a few water-soluble sulphatcs (hexahydrite, epsomite, burkeite. and pickeringite), vary in their isotopic composition between about -12 and +8 per mil. This wide scatter is probably due to chemical weathering of primary sulphides having different delta 34S values in the substratum.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_763872
institution PANGAEA
language en
publishDate 1992
publisher PANGAEA
record_format pangaea
spellingShingle Sulphur isotope analyses in the southern ocean and the central Dronning Maud Land, East Antarctica
Wand, Ulrich
Maaß, Ingeborg
Haendel, Dietmar
Dronning Maud Land, Antarctica; MULT; Multiple investigations; Novolazarevskaya_Station; Rozovoye; Schirmacher_Oasis; Untersee_Oasis
Sulphur isotope analyses are an important tool for the study of the natural sulphur cycle. On the northern hemisphere such studies of the atmospheric part of the cycle are practically impossible due to the high emission rate of anthropogenic sulphur. Merely in remote areas of the world such as the Antarctic 34S analyses can be used to identify the various sulphur sources (sea spray, biogenic und volcanic sources). We report here results of 34S measurements on sulphates from recent atmospheric precipitations (snow), lake waters, and salt efflorescences sampled in the Schirmacher Oasis and the Gruber Mountains, central Dronning Maud Land, East Antarctica. By plotting the delta 34S of precipitation versus % sea-spray sulphate the isotopic composition of the excess sulphate (which is probably of marine-biogenic origin) is extrapolated to be +4 per mil. Lake water sulphate and atmospheric precipitations have a comparable sulphur isotope composition (about +5 per mil). The analyzed secondary sulphates from the salt efflorescences, mainly gypsum and a few water-soluble sulphatcs (hexahydrite, epsomite, burkeite. and pickeringite), vary in their isotopic composition between about -12 and +8 per mil. This wide scatter is probably due to chemical weathering of primary sulphides having different delta 34S values in the substratum.
title Sulphur isotope analyses in the southern ocean and the central Dronning Maud Land, East Antarctica
topic Dronning Maud Land, Antarctica; MULT; Multiple investigations; Novolazarevskaya_Station; Rozovoye; Schirmacher_Oasis; Untersee_Oasis
url https://doi.org/10.1594/PANGAEA.763872