Sample locations, CTD data, mean spring and annual temperatures and salinities from World Ocean Atlas (WOA, 2001), and ICP-OES Mg/Ca data

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Auteurs principaux: van Raden, Ulrike Jannette, Groeneveld, Jeroen, Raitzsch, Markus, Kucera, Michal
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 2011
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author van Raden, Ulrike Jannette
Groeneveld, Jeroen
Raitzsch, Markus
Kucera, Michal
author_facet van Raden, Ulrike Jannette
Groeneveld, Jeroen
Raitzsch, Markus
Kucera, Michal
collection Datos científicos de ciencias marinas y ambientales
contents Due to its strong gradient in salinity and small temperature gradient the Mediterranean provides an ideal setting to study the impact of salinity on the incorporation of Mg into foraminiferal tests. We have investigated tests of Globorotalia inflata and Globigerina bulloides in plankton tow and core top samples from the Western Mediterranean using ICP-OES for bulk analyses and LA-ICP-MS for analyses of individual chambers in single specimens. Mg/Ca observed in G. inflata are consistent with existing calibrations, whereas G. bulloides had significantly higher Mg/Ca than predicted, particularly in core top samples from the easterly stations. Scanning Electron Microscopy and Laser Ablation ICP-MS revealed secondary overgrowths on some tests, which could explain the observed high core top Mg/Ca. We suggest that the Mediterranean intermediate and deep water supersaturated with respect to calcite cause these overgrowths and therefore increased bulk Mg/Ca. However, the different species are influenced by diagenesis to different degrees probably due to different test morphologies. Our results provide new perspectives on reported anomalously high Mg/Ca in sedimentary foraminifera and the applicability of the Mg/Ca paleothermometry in high salinity settings, by showing that (1) part of the signal is generated by precipitation of inorganic calcite on the foraminifer test due to increased calcite saturation state of the water and (2) species with high surface-to-volume shell surfaces are potentially more affected by secondary Mg-rich calcite encrustation.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_782926
institution PANGAEA
language en
publishDate 2011
publisher PANGAEA
record_format pangaea
spellingShingle Sample locations, CTD data, mean spring and annual temperatures and salinities from World Ocean Atlas (WOA, 2001), and ICP-OES Mg/Ca data
van Raden, Ulrike Jannette
Groeneveld, Jeroen
Raitzsch, Markus
Kucera, Michal
Alboran Sea; Center for Marine Environmental Sciences; GeoTü; MARUM; Mediterranean Sea, Western Basin; MSN; MUC; MultiCorer; Multiple opening/closing net; Paleoceanography at Tübingen University; POS334; POS334_74-1; POS334_74-6; POS334_75-7; POS334_77-5; POS334_79-7; POS334_81-3; POS334_81-6; Poseidon; Tirreno Sea
Due to its strong gradient in salinity and small temperature gradient the Mediterranean provides an ideal setting to study the impact of salinity on the incorporation of Mg into foraminiferal tests. We have investigated tests of Globorotalia inflata and Globigerina bulloides in plankton tow and core top samples from the Western Mediterranean using ICP-OES for bulk analyses and LA-ICP-MS for analyses of individual chambers in single specimens. Mg/Ca observed in G. inflata are consistent with existing calibrations, whereas G. bulloides had significantly higher Mg/Ca than predicted, particularly in core top samples from the easterly stations. Scanning Electron Microscopy and Laser Ablation ICP-MS revealed secondary overgrowths on some tests, which could explain the observed high core top Mg/Ca. We suggest that the Mediterranean intermediate and deep water supersaturated with respect to calcite cause these overgrowths and therefore increased bulk Mg/Ca. However, the different species are influenced by diagenesis to different degrees probably due to different test morphologies. Our results provide new perspectives on reported anomalously high Mg/Ca in sedimentary foraminifera and the applicability of the Mg/Ca paleothermometry in high salinity settings, by showing that (1) part of the signal is generated by precipitation of inorganic calcite on the foraminifer test due to increased calcite saturation state of the water and (2) species with high surface-to-volume shell surfaces are potentially more affected by secondary Mg-rich calcite encrustation.
title Sample locations, CTD data, mean spring and annual temperatures and salinities from World Ocean Atlas (WOA, 2001), and ICP-OES Mg/Ca data
topic Alboran Sea; Center for Marine Environmental Sciences; GeoTü; MARUM; Mediterranean Sea, Western Basin; MSN; MUC; MultiCorer; Multiple opening/closing net; Paleoceanography at Tübingen University; POS334; POS334_74-1; POS334_74-6; POS334_75-7; POS334_77-5; POS334_79-7; POS334_81-3; POS334_81-6; Poseidon; Tirreno Sea
url https://doi.org/10.1594/PANGAEA.782926