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Auteurs principaux: Schaefer, Rainer G, Leythaeuser, Detlev
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 1987
Sujets:
1,cis-2-Dimethylcyclopentane, per unit sediment mass; 1,cis-3-Dimethylcyclopentane, per unit sediment mass; 1,trans-2,cis-3-trimethylcyclopentane, per unit sediment mass; 1,trans-2,cis-4-trimethylcyclopentane, per unit sediment mass; 1 trans-2-Dimethylcyclopentane, per unit sediment mass; 1 trans-3-Dimethylcyclopentane, per unit sediment mass; 2,2-Dimethylbutane, per unit sediment mass; 2,3-Dimethylbutane, per unit sediment mass; 2,3-Dimethylpentane, per unit sediment mass; 2,4-Dimethylpentane, per unit sediment mass; 2,5-Dimethylhexane, per unit sediment mass; 2-Methylhexane, per unit sediment mass; 2-Methylpentane, per unit sediment mass; 3-Methylhexane, per unit sediment mass; 3-Methylpentane, per unit sediment mass; 93-603B; Benzene, per unit sediment mass; Carbon, organic, total; Carbon analyser, LECO; Combined gas-stripping/thermovaporization method; Cyclohexane, per unit sediment mass; Cyclopentane, per unit sediment mass; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Ethane, per unit sediment mass; Ethene, per unit sediment mass; Ethylcyclopentane, per unit sediment mass; Glomar Challenger; Hydrogen index, mass HC, per unit mass total organic carbon; Isobutane, per unit sediment mass; Isopentane, per unit sediment mass; Leg93; Lithology/composition/facies; Methylcyclohexane, per unit sediment mass; Methylcyclopentane, per unit sediment mass; n-Butane, per unit sediment mass; n-Heptane, per unit sediment mass; n-Hexane, per unit sediment mass; n-Octane, per unit sediment mass; n-Pentane, per unit sediment mass; Oxygen index, mass CO2, per unit mass total organic carbon; Propane, per unit sediment mass; Propene, per unit sediment mass; Pyrolysis temperature maximum; Rock eval pyrolysis (Behar et al., 2001); Sample code/label; Toluene, per unit sediment mass; Visual description
Accès en ligne:https://doi.org/10.1594/PANGAEA.789287
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author Schaefer, Rainer G
Leythaeuser, Detlev
author_facet Schaefer, Rainer G
Leythaeuser, Detlev
collection Datos científicos de ciencias marinas y ambientales
contents C2-C8 hydrocarbon concentrations (about 35 compounds identified, including saturated, aromatic, and olefinic compounds) from 27 shipboard-sealed, deep-frozen core samples of DSDP Hole 603B off the east coast of North America were determined by a gas-stripping/thermovaporization method. Total yields representing the hydrocarbons dissolved in the pore water and adsorbed on the mineral surfaces of the sediments vary from 22 to 2400 ng/g of dryweight sediment. Highest yields are measured in the two black shale samples of Core 603B-34 (hydrogen index of 360 and 320 mg/g Corg, respectively). In organic-carbon-normalized units these samples have hydrocarbon contents of 12,700 and 21,500 ng/g Corg, respectively, indicating the immaturity of their kerogens. Unusually high organic-carbonnormalized yields are associated with samples that are extremely lean in organic carbon. It is most likely that they are enriched by small amounts of migrated light hydrocarbons. This applies even to those samples with high organic-carbon contents (1.3-2.2%) of Sections 603B-28-4, 603B-29-1, 603B-49-2, and 603B-49-3, because they have an extremely low hydrocarbon potential (hydrogen index between 40 and 60 mg/g Corg). Nearly all samples were found to be contaminated by varying amounts of acetone that is used routinely in large quantities on board ship during core-cutting procedures. Therefore, 48 samples from the original set of 75 collected had to be excluded from the present study.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_789287
institution PANGAEA
language en
publishDate 1987
publisher PANGAEA
record_format pangaea
spellingShingle (Table 1) Organic carbon, hydrogen and oxygen index and hydrocarbons at DSDP Hole 93-603B
Schaefer, Rainer G
Leythaeuser, Detlev
1,cis-2-Dimethylcyclopentane, per unit sediment mass; 1,cis-3-Dimethylcyclopentane, per unit sediment mass; 1,trans-2,cis-3-trimethylcyclopentane, per unit sediment mass; 1,trans-2,cis-4-trimethylcyclopentane, per unit sediment mass; 1 trans-2-Dimethylcyclopentane, per unit sediment mass; 1 trans-3-Dimethylcyclopentane, per unit sediment mass; 2,2-Dimethylbutane, per unit sediment mass; 2,3-Dimethylbutane, per unit sediment mass; 2,3-Dimethylpentane, per unit sediment mass; 2,4-Dimethylpentane, per unit sediment mass; 2,5-Dimethylhexane, per unit sediment mass; 2-Methylhexane, per unit sediment mass; 2-Methylpentane, per unit sediment mass; 3-Methylhexane, per unit sediment mass; 3-Methylpentane, per unit sediment mass; 93-603B; Benzene, per unit sediment mass; Carbon, organic, total; Carbon analyser, LECO; Combined gas-stripping/thermovaporization method; Cyclohexane, per unit sediment mass; Cyclopentane, per unit sediment mass; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Ethane, per unit sediment mass; Ethene, per unit sediment mass; Ethylcyclopentane, per unit sediment mass; Glomar Challenger; Hydrogen index, mass HC, per unit mass total organic carbon; Isobutane, per unit sediment mass; Isopentane, per unit sediment mass; Leg93; Lithology/composition/facies; Methylcyclohexane, per unit sediment mass; Methylcyclopentane, per unit sediment mass; n-Butane, per unit sediment mass; n-Heptane, per unit sediment mass; n-Hexane, per unit sediment mass; n-Octane, per unit sediment mass; n-Pentane, per unit sediment mass; Oxygen index, mass CO2, per unit mass total organic carbon; Propane, per unit sediment mass; Propene, per unit sediment mass; Pyrolysis temperature maximum; Rock eval pyrolysis (Behar et al., 2001); Sample code/label; Toluene, per unit sediment mass; Visual description
C2-C8 hydrocarbon concentrations (about 35 compounds identified, including saturated, aromatic, and olefinic compounds) from 27 shipboard-sealed, deep-frozen core samples of DSDP Hole 603B off the east coast of North America were determined by a gas-stripping/thermovaporization method. Total yields representing the hydrocarbons dissolved in the pore water and adsorbed on the mineral surfaces of the sediments vary from 22 to 2400 ng/g of dryweight sediment. Highest yields are measured in the two black shale samples of Core 603B-34 (hydrogen index of 360 and 320 mg/g Corg, respectively). In organic-carbon-normalized units these samples have hydrocarbon contents of 12,700 and 21,500 ng/g Corg, respectively, indicating the immaturity of their kerogens. Unusually high organic-carbonnormalized yields are associated with samples that are extremely lean in organic carbon. It is most likely that they are enriched by small amounts of migrated light hydrocarbons. This applies even to those samples with high organic-carbon contents (1.3-2.2%) of Sections 603B-28-4, 603B-29-1, 603B-49-2, and 603B-49-3, because they have an extremely low hydrocarbon potential (hydrogen index between 40 and 60 mg/g Corg). Nearly all samples were found to be contaminated by varying amounts of acetone that is used routinely in large quantities on board ship during core-cutting procedures. Therefore, 48 samples from the original set of 75 collected had to be excluded from the present study.
title (Table 1) Organic carbon, hydrogen and oxygen index and hydrocarbons at DSDP Hole 93-603B
topic 1,cis-2-Dimethylcyclopentane, per unit sediment mass; 1,cis-3-Dimethylcyclopentane, per unit sediment mass; 1,trans-2,cis-3-trimethylcyclopentane, per unit sediment mass; 1,trans-2,cis-4-trimethylcyclopentane, per unit sediment mass; 1 trans-2-Dimethylcyclopentane, per unit sediment mass; 1 trans-3-Dimethylcyclopentane, per unit sediment mass; 2,2-Dimethylbutane, per unit sediment mass; 2,3-Dimethylbutane, per unit sediment mass; 2,3-Dimethylpentane, per unit sediment mass; 2,4-Dimethylpentane, per unit sediment mass; 2,5-Dimethylhexane, per unit sediment mass; 2-Methylhexane, per unit sediment mass; 2-Methylpentane, per unit sediment mass; 3-Methylhexane, per unit sediment mass; 3-Methylpentane, per unit sediment mass; 93-603B; Benzene, per unit sediment mass; Carbon, organic, total; Carbon analyser, LECO; Combined gas-stripping/thermovaporization method; Cyclohexane, per unit sediment mass; Cyclopentane, per unit sediment mass; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Ethane, per unit sediment mass; Ethene, per unit sediment mass; Ethylcyclopentane, per unit sediment mass; Glomar Challenger; Hydrogen index, mass HC, per unit mass total organic carbon; Isobutane, per unit sediment mass; Isopentane, per unit sediment mass; Leg93; Lithology/composition/facies; Methylcyclohexane, per unit sediment mass; Methylcyclopentane, per unit sediment mass; n-Butane, per unit sediment mass; n-Heptane, per unit sediment mass; n-Hexane, per unit sediment mass; n-Octane, per unit sediment mass; n-Pentane, per unit sediment mass; Oxygen index, mass CO2, per unit mass total organic carbon; Propane, per unit sediment mass; Propene, per unit sediment mass; Pyrolysis temperature maximum; Rock eval pyrolysis (Behar et al., 2001); Sample code/label; Toluene, per unit sediment mass; Visual description
url https://doi.org/10.1594/PANGAEA.789287