_version_ 1867171811380166656
author Kraemer, Lisa M
Owen, Robert M
Dickens, Gerald Roy
author_facet Kraemer, Lisa M
Owen, Robert M
Dickens, Gerald Roy
collection Datos científicos de ciencias marinas y ambientales
contents Gas hydrate on the crest of the Blake Ridge is concentrated over two depth zones: between 185 and 260 mbsf, and between 380 and 450 mbsf. Although the abundance of hydrate in the lower zone may be explained by methane cycling across the phase boundary between free gas bubbles and gas hydrate, the upper zone lacks a satisfactory explanation. Chemical analyses of sediment samples from Hole 994C (31º47.139'N, 75º32.753'W) were performed to determine if the relatively high hydrate accumulation between 185 and 260 mbsf coincides with an observable change in sediment composition and microporosity. Our analyses indicate a distinct change in lithology across the upper hydrate zone: the carbonate content decreases from about 25% to about 8% with a corresponding increase in siliceous microfossils and bulk porosity. An increase in the abundance of siliceous microfossils increases the size and roundness of pore spaces. Large and round pores should provide nucleation sites for gas hydrate that are uninhibited by capillary forces between grains. Upward advecting fluids that are supersaturated with methane may deposit gas hydrate as they pass through the diatom-rich depth interval. Results presented here are consistent with the hypothesis that gas hydrate distribution is influenced by sediment lithology and microporosity.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_804226
institution PANGAEA
language en
publishDate 2000
publisher PANGAEA
record_format pangaea
spellingShingle (Table 1) Porosity, and calcium carbonate, scandium and opal content of ODP Hole 164-994C sediments
Kraemer, Lisa M
Owen, Robert M
Dickens, Gerald Roy
164-994C; Atomic absorption spectrometry (AAS); Calcium carbonate; Calculated; Carbonate bomb (Müller & Gastner, 1971); DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Instrumental neutron activation analysis (INAA); Joides Resolution; Leg164; North Atlantic Ocean; Ocean Drilling Program; ODP; Opal, biogenic silica; Porosity; Sample code/label; Scandium
Gas hydrate on the crest of the Blake Ridge is concentrated over two depth zones: between 185 and 260 mbsf, and between 380 and 450 mbsf. Although the abundance of hydrate in the lower zone may be explained by methane cycling across the phase boundary between free gas bubbles and gas hydrate, the upper zone lacks a satisfactory explanation. Chemical analyses of sediment samples from Hole 994C (31º47.139'N, 75º32.753'W) were performed to determine if the relatively high hydrate accumulation between 185 and 260 mbsf coincides with an observable change in sediment composition and microporosity. Our analyses indicate a distinct change in lithology across the upper hydrate zone: the carbonate content decreases from about 25% to about 8% with a corresponding increase in siliceous microfossils and bulk porosity. An increase in the abundance of siliceous microfossils increases the size and roundness of pore spaces. Large and round pores should provide nucleation sites for gas hydrate that are uninhibited by capillary forces between grains. Upward advecting fluids that are supersaturated with methane may deposit gas hydrate as they pass through the diatom-rich depth interval. Results presented here are consistent with the hypothesis that gas hydrate distribution is influenced by sediment lithology and microporosity.
title (Table 1) Porosity, and calcium carbonate, scandium and opal content of ODP Hole 164-994C sediments
topic 164-994C; Atomic absorption spectrometry (AAS); Calcium carbonate; Calculated; Carbonate bomb (Müller & Gastner, 1971); DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Instrumental neutron activation analysis (INAA); Joides Resolution; Leg164; North Atlantic Ocean; Ocean Drilling Program; ODP; Opal, biogenic silica; Porosity; Sample code/label; Scandium
url https://doi.org/10.1594/PANGAEA.804226