(Table 2) Calcium carbonate content in deep-sea surface sediments

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Hauptverfasser: Broecker, Wallace S, Clark, Elizabeth
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Sprache:en
Veröffentlicht: PANGAEA 2009
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author Broecker, Wallace S
Clark, Elizabeth
author_facet Broecker, Wallace S
Clark, Elizabeth
collection Datos científicos de ciencias marinas y ambientales
contents The reconstruction of paleocarbonate ion concentrations provides an important constraint on the contribution of the CaCO3 cycle to the decrease in atmospheric CO2 content during glacial time. Such reconstructions have been challenging because each of the existing paleo-[CO3]2- indices has serious limitations. In this study, we reexamine the Broecker-Clark CaCO3 size index by analyzing the <20 µm, 20 to 38 µm, and 38 to 63 µm fractions in sediments from the Ontong-Java Plateau and the Ceara Rise. Scanning electron microscope analyses demonstrate that the less than 20 µm CaCO3 is dominated by coccoliths and the greater than 20 µm CaCO3 is dominated by foraminifera. Our results clearly indicate that the coccoliths are far more resistant to dissolution than the foraminifera. Referenced to a core top sample from 2.31 km depth in a core top sample from 4.04 km depth on the Ontong-Java Plateau, ~70% of the foraminifera CaCO3 was dissolved as opposed to only ~7% of the coccolith CaCO3. We found that the dissolution of foraminifera shells did not produce a significant amount of fragments smaller than 63 µm in size, and thus the Broecker-Clark size index is not a measure of the extent of fragmentation. Rather, it is a measure of the extent of differential dissolution of foraminifera relative to coccoliths. On the basis of these results, we propose a new dissolution index which involves the ratio of dissolution-susceptible foraminifera CaCO3 to total CaCO3.
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language en
publishDate 2009
publisher PANGAEA
record_format pangaea
spellingShingle (Table 2) Calcium carbonate content in deep-sea surface sediments
Broecker, Wallace S
Clark, Elizabeth
also published as VM28-122; Calcium carbonate; Calcium carbonate, fractionated; Central Pacific; DEPTH, sediment/rock; Elevation of event; Event label; GC; Gear; GGC; Giant gravity corer; Gravity corer; Latitude of event; Longitude of event; Moana Wave; MW9109; MW9109-15GGC; PC; Piston corer; Ratio; RC08; RC08-107; RC09; RC09-124; RC09-189; RC09-201; RC09-99; RC10; RC10-264; RC11; RC1112; RC11-37; RC12; RC12-107; RC12-108; RC12-293; RC12-365; RC12-5; RC13; RC13-187; RC13-187TW; RC13-210; RC13-210TW; RC13-43; RC13-43TW; RC14; RC14-35; RC14-35TW; RC14-36; RC14-36TW; RC15; RC15-143; RC15-143TW; RC15-175; RC15-175TW; RC16; RC16-118; RC16-118TW; RC17; RC17-176TW; RC17-91; RC17-91TW; RC17-92; RC17-92TW; RC17-93; RC17-93TW; RC17-94; RC17-95; RC17-95TW; RC19; RC19-48; RC19-48TW; RC25; RC25-35; RC25-35TW; Robert Conrad; V03; V03-36; V10; V10-72; V13; V13-2; V18; V18-200; V20; V20-171; V20-173; V20-234; V21; V21-93; V22; V22-218; V22-219; V22-221; V22-222; V22-226; V22-32; V23; V23-91; V24; V24-109; V24-15; V24-96; V25; V25-15; V25-26; V25-54; V26; V26-13; V27; V27-193; V28; V28-122; V28-304; V29; V29-64; V29-97; V30; V30-236; V30-61; V30-63; V30-9; V30-96; V31; V31-139; V32; V32-173; V32-173TW; V32-38; V32-38TW; V32-43; V32-43TW; V34; V34-54; V34-58; V34-91TW; Vema
The reconstruction of paleocarbonate ion concentrations provides an important constraint on the contribution of the CaCO3 cycle to the decrease in atmospheric CO2 content during glacial time. Such reconstructions have been challenging because each of the existing paleo-[CO3]2- indices has serious limitations. In this study, we reexamine the Broecker-Clark CaCO3 size index by analyzing the <20 µm, 20 to 38 µm, and 38 to 63 µm fractions in sediments from the Ontong-Java Plateau and the Ceara Rise. Scanning electron microscope analyses demonstrate that the less than 20 µm CaCO3 is dominated by coccoliths and the greater than 20 µm CaCO3 is dominated by foraminifera. Our results clearly indicate that the coccoliths are far more resistant to dissolution than the foraminifera. Referenced to a core top sample from 2.31 km depth in a core top sample from 4.04 km depth on the Ontong-Java Plateau, ~70% of the foraminifera CaCO3 was dissolved as opposed to only ~7% of the coccolith CaCO3. We found that the dissolution of foraminifera shells did not produce a significant amount of fragments smaller than 63 µm in size, and thus the Broecker-Clark size index is not a measure of the extent of fragmentation. Rather, it is a measure of the extent of differential dissolution of foraminifera relative to coccoliths. On the basis of these results, we propose a new dissolution index which involves the ratio of dissolution-susceptible foraminifera CaCO3 to total CaCO3.
title (Table 2) Calcium carbonate content in deep-sea surface sediments
topic also published as VM28-122; Calcium carbonate; Calcium carbonate, fractionated; Central Pacific; DEPTH, sediment/rock; Elevation of event; Event label; GC; Gear; GGC; Giant gravity corer; Gravity corer; Latitude of event; Longitude of event; Moana Wave; MW9109; MW9109-15GGC; PC; Piston corer; Ratio; RC08; RC08-107; RC09; RC09-124; RC09-189; RC09-201; RC09-99; RC10; RC10-264; RC11; RC1112; RC11-37; RC12; RC12-107; RC12-108; RC12-293; RC12-365; RC12-5; RC13; RC13-187; RC13-187TW; RC13-210; RC13-210TW; RC13-43; RC13-43TW; RC14; RC14-35; RC14-35TW; RC14-36; RC14-36TW; RC15; RC15-143; RC15-143TW; RC15-175; RC15-175TW; RC16; RC16-118; RC16-118TW; RC17; RC17-176TW; RC17-91; RC17-91TW; RC17-92; RC17-92TW; RC17-93; RC17-93TW; RC17-94; RC17-95; RC17-95TW; RC19; RC19-48; RC19-48TW; RC25; RC25-35; RC25-35TW; Robert Conrad; V03; V03-36; V10; V10-72; V13; V13-2; V18; V18-200; V20; V20-171; V20-173; V20-234; V21; V21-93; V22; V22-218; V22-219; V22-221; V22-222; V22-226; V22-32; V23; V23-91; V24; V24-109; V24-15; V24-96; V25; V25-15; V25-26; V25-54; V26; V26-13; V27; V27-193; V28; V28-122; V28-304; V29; V29-64; V29-97; V30; V30-236; V30-61; V30-63; V30-9; V30-96; V31; V31-139; V32; V32-173; V32-173TW; V32-38; V32-38TW; V32-43; V32-43TW; V34; V34-54; V34-58; V34-91TW; Vema
url https://doi.org/10.1594/PANGAEA.831705