Mg/Ca variability in Globigerinoides ruber tests

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Main Authors: Sadekov, Aleksey Y, Eggins, Stephen M, De Deckker, Patrick, Kroon, Dick
Format: Dataset Open Access
Language:en
Published: PANGAEA 2008
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author Sadekov, Aleksey Y
Eggins, Stephen M
De Deckker, Patrick
Kroon, Dick
author_facet Sadekov, Aleksey Y
Eggins, Stephen M
De Deckker, Patrick
Kroon, Dick
collection Datos científicos de ciencias marinas y ambientales
contents Laser ablation inductively coupled plasma-mass spectrometry microanalysis of fossil and live Globigerinoides ruber from the eastern Indian Ocean reveals large variations of Mg/Ca composition both within and between individual tests from core top or plankton pump samples. Although the extent of intertest and intratest compositional variability exceeds that attributable to calcification temperature, the pooled mean Mg/Ca molar values obtained for core top samples between the equator and >30°S form a strong exponential correlation with mean annual sea surface temperature (Mg/Ca mmol/mol = 0.52 exp**0.076SST°C, r**2 = 0.99). The intertest Mg/Ca variability within these deep-sea core top samples is a source of significant uncertainty in Mg/Ca seawater temperature estimates and is notable for being site specific. Our results indicate that widely assumed uncertainties in Mg/Ca thermometry may be underestimated. We show that statistical power analysis can be used to evaluate the number of tests needed to achieve a target level of uncertainty on a sample by sample case. A varying bias also arises from the presence and varying mix of two morphotypes (G. ruber ruber and G. ruber pyramidalis), which have different mean Mg/Ca values. Estimated calcification temperature differences between these morphotypes range up to 5°C and are notable for correlating with the seasonal range in seawater temperature at different sites.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_832514
institution PANGAEA
language en
publishDate 2008
publisher PANGAEA
record_format pangaea
spellingShingle Mg/Ca variability in Globigerinoides ruber tests
Sadekov, Aleksey Y
Eggins, Stephen M
De Deckker, Patrick
Kroon, Dick

Laser ablation inductively coupled plasma-mass spectrometry microanalysis of fossil and live Globigerinoides ruber from the eastern Indian Ocean reveals large variations of Mg/Ca composition both within and between individual tests from core top or plankton pump samples. Although the extent of intertest and intratest compositional variability exceeds that attributable to calcification temperature, the pooled mean Mg/Ca molar values obtained for core top samples between the equator and >30°S form a strong exponential correlation with mean annual sea surface temperature (Mg/Ca mmol/mol = 0.52 exp**0.076SST°C, r**2 = 0.99). The intertest Mg/Ca variability within these deep-sea core top samples is a source of significant uncertainty in Mg/Ca seawater temperature estimates and is notable for being site specific. Our results indicate that widely assumed uncertainties in Mg/Ca thermometry may be underestimated. We show that statistical power analysis can be used to evaluate the number of tests needed to achieve a target level of uncertainty on a sample by sample case. A varying bias also arises from the presence and varying mix of two morphotypes (G. ruber ruber and G. ruber pyramidalis), which have different mean Mg/Ca values. Estimated calcification temperature differences between these morphotypes range up to 5°C and are notable for correlating with the seasonal range in seawater temperature at different sites.
title Mg/Ca variability in Globigerinoides ruber tests
topic
url https://doi.org/10.1594/PANGAEA.832514