Halogen deposition in polar snow and ice

Fuente: PANGAEA
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Dettagli Bibliografici
Autori principali: Spolaor, Andrea, Vallelonga, Paul T, Gabrieli, Jacopo, Martma, Tõnu, Björkman, Mats P, Isaksson, Elisabeth, Cozzi, Giulio, Turetta, Clara, Kjær, Helle Astrid, Curran, Mark A J, Moy, Andrew D, Schönhardt, Anja, Blechschmidt, Anne-Marlene, Burrows, John Philipp, Plane, J M C, Barbante, Carlo
Natura: Dataset Open Access
Lingua:en
Pubblicazione: PANGAEA 2014
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author Spolaor, Andrea
Vallelonga, Paul T
Gabrieli, Jacopo
Martma, Tõnu
Björkman, Mats P
Isaksson, Elisabeth
Cozzi, Giulio
Turetta, Clara
Kjær, Helle Astrid
Curran, Mark A J
Moy, Andrew D
Schönhardt, Anja
Blechschmidt, Anne-Marlene
Burrows, John Philipp
Plane, J M C
Barbante, Carlo
author_facet Spolaor, Andrea
Vallelonga, Paul T
Gabrieli, Jacopo
Martma, Tõnu
Björkman, Mats P
Isaksson, Elisabeth
Cozzi, Giulio
Turetta, Clara
Kjær, Helle Astrid
Curran, Mark A J
Moy, Andrew D
Schönhardt, Anja
Blechschmidt, Anne-Marlene
Burrows, John Philipp
Plane, J M C
Barbante, Carlo
collection Datos científicos de ciencias marinas y ambientales
contents The atmospheric chemistry of iodine and bromine in polar regions is of interest due to the key role of halogens in many atmospheric processes, particularly tropospheric ozone destruction. Bromine is emitted from the open ocean but is enriched above first-year sea ice during springtime bromine explosion events, whereas iodine is emitted from biological communities hosted by sea ice. It has been previously demonstrated that bromine and iodine are present in Antarctic ice over glacial-interglacial cycles. Here we investigate seasonal variability of bromine and iodine in polar snow and ice, to evaluate their emission, transport and deposition in Antarctica and the Arctic and better understand potential links to sea ice. We find that bromine enrichment (relative to sea salt content) and iodine concentrations in polar ice do vary seasonally in Arctic snow and Antarctic ice and we relate such variability to satellite-based observations of tropospheric halogen concentrations. Peaks of bromine enrichment in Arctic snow and Antarctic ice occur in spring and summer, when sunlight is present. Iodine concentrations are largest in winter Antarctic ice strata, contrary to contemporary observations of summer maxima in iodine emissions.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_833942
institution PANGAEA
language en
publishDate 2014
publisher PANGAEA
record_format pangaea
spellingShingle Halogen deposition in polar snow and ice
Spolaor, Andrea
Vallelonga, Paul T
Gabrieli, Jacopo
Martma, Tõnu
Björkman, Mats P
Isaksson, Elisabeth
Cozzi, Giulio
Turetta, Clara
Kjær, Helle Astrid
Curran, Mark A J
Moy, Andrew D
Schönhardt, Anja
Blechschmidt, Anne-Marlene
Burrows, John Philipp
Plane, J M C
Barbante, Carlo

The atmospheric chemistry of iodine and bromine in polar regions is of interest due to the key role of halogens in many atmospheric processes, particularly tropospheric ozone destruction. Bromine is emitted from the open ocean but is enriched above first-year sea ice during springtime bromine explosion events, whereas iodine is emitted from biological communities hosted by sea ice. It has been previously demonstrated that bromine and iodine are present in Antarctic ice over glacial-interglacial cycles. Here we investigate seasonal variability of bromine and iodine in polar snow and ice, to evaluate their emission, transport and deposition in Antarctica and the Arctic and better understand potential links to sea ice. We find that bromine enrichment (relative to sea salt content) and iodine concentrations in polar ice do vary seasonally in Arctic snow and Antarctic ice and we relate such variability to satellite-based observations of tropospheric halogen concentrations. Peaks of bromine enrichment in Arctic snow and Antarctic ice occur in spring and summer, when sunlight is present. Iodine concentrations are largest in winter Antarctic ice strata, contrary to contemporary observations of summer maxima in iodine emissions.
title Halogen deposition in polar snow and ice
topic
url https://doi.org/10.1594/PANGAEA.833942