Rare earth elements of modern seeps from the Gulf of Mexico, the Black Sea, and the Congo Fan

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Auteurs principaux: Feng, Dong, Lin, Zhijia, Bian, Y, Chen, Duofu, Peckmann, Jörn, Bohrmann, Gerhard, Roberts, Harry H
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 2013
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author Feng, Dong
Lin, Zhijia
Bian, Y
Chen, Duofu
Peckmann, Jörn
Bohrmann, Gerhard
Roberts, Harry H
author_facet Feng, Dong
Lin, Zhijia
Bian, Y
Chen, Duofu
Peckmann, Jörn
Bohrmann, Gerhard
Roberts, Harry H
collection Datos científicos de ciencias marinas y ambientales
contents At marine seeps, methane is microbially oxidized resulting in the precipitation of carbonates close to the seafloor. Methane oxidation leads to sulfate depletion in sediment pore water, which induces a change in redox conditions. Rare earth element (REE) patterns of authigenic carbonate phases collected from modern seeps of the Gulf of Mexico, the Black Sea, and the Congo Fan were analyzed. Different carbonate minerals including aragonite and calcite with different crystal habits have been selected for analysis. Total REE content (SumREE) of seep carbonates varies widely, from 0.1 ppm to 42.5 ppm, but a common trend is that the SumREE in microcrystalline phases is higher than that of the associated later phases including micospar, sparite and blocky cement, suggesting that SumREE may be a function of diagenesis. The shale-normalized REE patterns of the seep carbonates often show different Ce anomalies even in samples from a specific site, suggesting that the formation conditions of seep carbonates are variable and complex. Overall, our results show that apart from anoxic, oxic conditions are at least temporarily common in seep environments.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_834248
institution PANGAEA
language en
publishDate 2013
publisher PANGAEA
record_format pangaea
spellingShingle Rare earth elements of modern seeps from the Gulf of Mexico, the Black Sea, and the Congo Fan
Feng, Dong
Lin, Zhijia
Bian, Y
Chen, Duofu
Peckmann, Jörn
Bohrmann, Gerhard
Roberts, Harry H
Center for Marine Environmental Sciences; MARUM
At marine seeps, methane is microbially oxidized resulting in the precipitation of carbonates close to the seafloor. Methane oxidation leads to sulfate depletion in sediment pore water, which induces a change in redox conditions. Rare earth element (REE) patterns of authigenic carbonate phases collected from modern seeps of the Gulf of Mexico, the Black Sea, and the Congo Fan were analyzed. Different carbonate minerals including aragonite and calcite with different crystal habits have been selected for analysis. Total REE content (SumREE) of seep carbonates varies widely, from 0.1 ppm to 42.5 ppm, but a common trend is that the SumREE in microcrystalline phases is higher than that of the associated later phases including micospar, sparite and blocky cement, suggesting that SumREE may be a function of diagenesis. The shale-normalized REE patterns of the seep carbonates often show different Ce anomalies even in samples from a specific site, suggesting that the formation conditions of seep carbonates are variable and complex. Overall, our results show that apart from anoxic, oxic conditions are at least temporarily common in seep environments.
title Rare earth elements of modern seeps from the Gulf of Mexico, the Black Sea, and the Congo Fan
topic Center for Marine Environmental Sciences; MARUM
url https://doi.org/10.1594/PANGAEA.834248