Concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs) in liver samples of different marine mammals (1984-2009)

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Autores principales: Rotander, Anna, Kärrman, Anna, van Bavel, Bert, Polder, Anuschka, Rigét, Frank F, Auðunsson, Guðjón Atli, Víkingsson, Gísli, Gabrielsen, Geir W, Bloch, Dorete, Dam, Maria
Formato: Dataset Open Access
Lenguaje:en
Publicado: PANGAEA 2012
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author Rotander, Anna
Kärrman, Anna
van Bavel, Bert
Polder, Anuschka
Rigét, Frank F
Auðunsson, Guðjón Atli
Víkingsson, Gísli
Gabrielsen, Geir W
Bloch, Dorete
Dam, Maria
author_facet Rotander, Anna
Kärrman, Anna
van Bavel, Bert
Polder, Anuschka
Rigét, Frank F
Auðunsson, Guðjón Atli
Víkingsson, Gísli
Gabrielsen, Geir W
Bloch, Dorete
Dam, Maria
collection Datos científicos de ciencias marinas y ambientales
contents Temporal variations in concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs), including perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) structural isomers, were examined in livers of pilot whale (Globicephala melas), ringed seal (Phoca hispida), minke whale (Balaenoptera acutorostrata), harbor porpoise (Phocoena phocoena), hooded seal (Cystophora cristata), Atlantic white-sided dolphin (Lagenorhynchus acutus) and in muscle tissue of fin whales (Balaenoptera physalus). The sampling spanned over 20 years (1984-2009) and covered a large geographical area of the North Atlantic and West Greenland. Liver and muscle samples were homogenized, extracted with acetonitrile, cleaned up using hexane and solid phase extraction (SPE), and analyzed by liquid chromatography with negative electrospray tandem mass spectrometry (LC-MS/MS). In general, the levels of the long-chained PFCAs (C9-C12) increased whereas the levels of PFOS remained steady over the studied period. The PFOS isomer pattern in pilot whale liver was relatively constant over the sampling years. However, in ringed seals there seemed to be a decrease in linear PFOS (L-PFOS) with time, going from 91% in 1984 to 83% in 2006.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_834595
institution PANGAEA
language en
publishDate 2012
publisher PANGAEA
record_format pangaea
spellingShingle Concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs) in liver samples of different marine mammals (1984-2009)
Rotander, Anna
Kärrman, Anna
van Bavel, Bert
Polder, Anuschka
Rigét, Frank F
Auðunsson, Guðjón Atli
Víkingsson, Gísli
Gabrielsen, Geir W
Bloch, Dorete
Dam, Maria
International Polar Year (2007-2008); IPY
Temporal variations in concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs), including perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) structural isomers, were examined in livers of pilot whale (Globicephala melas), ringed seal (Phoca hispida), minke whale (Balaenoptera acutorostrata), harbor porpoise (Phocoena phocoena), hooded seal (Cystophora cristata), Atlantic white-sided dolphin (Lagenorhynchus acutus) and in muscle tissue of fin whales (Balaenoptera physalus). The sampling spanned over 20 years (1984-2009) and covered a large geographical area of the North Atlantic and West Greenland. Liver and muscle samples were homogenized, extracted with acetonitrile, cleaned up using hexane and solid phase extraction (SPE), and analyzed by liquid chromatography with negative electrospray tandem mass spectrometry (LC-MS/MS). In general, the levels of the long-chained PFCAs (C9-C12) increased whereas the levels of PFOS remained steady over the studied period. The PFOS isomer pattern in pilot whale liver was relatively constant over the sampling years. However, in ringed seals there seemed to be a decrease in linear PFOS (L-PFOS) with time, going from 91% in 1984 to 83% in 2006.
title Concentrations of perfluorinated carboxylic acids (PFCAs) and sulfonic acids (PFSAs) in liver samples of different marine mammals (1984-2009)
topic International Polar Year (2007-2008); IPY
url https://doi.org/10.1594/PANGAEA.834595