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Main Authors: Vance, Derek, Scrivner, Adam E, Beney, Patricia, Staubwasser, Michael, Henderson, Gideon M, Slowey, Niall C
Format: Dataset Open Access
Language:en
Published: PANGAEA 2004
Subjects:
Online Access:https://doi.org/10.1594/PANGAEA.839893
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author Vance, Derek
Scrivner, Adam E
Beney, Patricia
Staubwasser, Michael
Henderson, Gideon M
Slowey, Niall C
author_facet Vance, Derek
Scrivner, Adam E
Beney, Patricia
Staubwasser, Michael
Henderson, Gideon M
Slowey, Niall C
collection Datos científicos de ciencias marinas y ambientales
contents We present new isotopic data for sedimentary planktonic foraminifera, as well as for potential water column and sedimentary sources of neodymium (Nd), which confirm that the isotopic composition of the foraminifera is the same as surface seawater and very different from deep water and sedimentary Nd. The faithfulness with which sedimentary foraminifera record the isotopic signature of surface seawater Nd is difficult to explain given their variable and high Nd/Ca ratios, ratios that are often sedimentary foraminifera, ratios that are often much higher than is plausible for direct incorporation within the calcite structure. We present further data that demonstrate a similarly large range in Nd/Ca ratios in plankton tow foraminifera, a range that may be controlled by redox conditions in the water column. Cleaning experiments reveal, in common with earlier work, that large amounts of Nd are released by cleaning with both hydrazine and diethylene triamine penta-acetic acid, but that the Nd released at each step is of surface origin. While further detailed studies are required to verify the exact location of the surface isotopic signature and the key controls on foraminiferal Nd isotope systematics, these new data place the use of planktonic foraminifera as recorders of surface water Nd isotope ratios, and thus of variations in the past supply of Nd to the oceans from the continents via weathering and erosion, on a reasonably sure footing.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_839893
institution PANGAEA
language en
publishDate 2004
publisher PANGAEA
record_format pangaea
spellingShingle Nd-Sr isotopic composition of foraminifera and bulk sediments
Vance, Derek
Scrivner, Adam E
Beney, Patricia
Staubwasser, Michael
Henderson, Gideon M
Slowey, Niall C
Ocean Drilling Program; ODP
We present new isotopic data for sedimentary planktonic foraminifera, as well as for potential water column and sedimentary sources of neodymium (Nd), which confirm that the isotopic composition of the foraminifera is the same as surface seawater and very different from deep water and sedimentary Nd. The faithfulness with which sedimentary foraminifera record the isotopic signature of surface seawater Nd is difficult to explain given their variable and high Nd/Ca ratios, ratios that are often sedimentary foraminifera, ratios that are often much higher than is plausible for direct incorporation within the calcite structure. We present further data that demonstrate a similarly large range in Nd/Ca ratios in plankton tow foraminifera, a range that may be controlled by redox conditions in the water column. Cleaning experiments reveal, in common with earlier work, that large amounts of Nd are released by cleaning with both hydrazine and diethylene triamine penta-acetic acid, but that the Nd released at each step is of surface origin. While further detailed studies are required to verify the exact location of the surface isotopic signature and the key controls on foraminiferal Nd isotope systematics, these new data place the use of planktonic foraminifera as recorders of surface water Nd isotope ratios, and thus of variations in the past supply of Nd to the oceans from the continents via weathering and erosion, on a reasonably sure footing.
title Nd-Sr isotopic composition of foraminifera and bulk sediments
topic Ocean Drilling Program; ODP
url https://doi.org/10.1594/PANGAEA.839893