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Main Authors: Cai, Yue, LaGatta, Alexandra, Goldstein, Steven L, Langmuir, Charles H, Gómez-Tuena, Arturo, Martín-del Pozzo, Ana Lillian, Carrasco-Núñez, Gerardo
Format: Dataset Open Access
Language:en
Published: PANGAEA 2016
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Online Access:https://doi.org/10.1594/PANGAEA.857524
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author Cai, Yue
LaGatta, Alexandra
Goldstein, Steven L
Langmuir, Charles H
Gómez-Tuena, Arturo
Martín-del Pozzo, Ana Lillian
Carrasco-Núñez, Gerardo
author_facet Cai, Yue
LaGatta, Alexandra
Goldstein, Steven L
Langmuir, Charles H
Gómez-Tuena, Arturo
Martín-del Pozzo, Ana Lillian
Carrasco-Núñez, Gerardo
collection Datos científicos de ciencias marinas y ambientales
contents This study presents evidence that Quaternary frontal arc calc-alkaline lavas from Central Mexican Volcanic Belt (CMVB) contain contributions from partial melts of the subducting garnet-bearing eclogitic oceanic crust and sediment, based on chemical and Hf-Nd isotope data. The CMVB includes both calc-alkaline lavas with arc-type trace element patterns such as aqueous fluid mobile element enrichments and high field strength element depletions; and "high-Nb" alkaline lavas with trace element patterns similar to ocean island basalts. The two types of lavas are closely related geographically and temporally. Distinct from the high-Nb lavas, the calc-alkaline lavas show trends toward higher 176Hf/177Hf and 143Nd/144Nd ratios coupled with lower Lu/Hf. The high Hf-Nd isotope ratios fingerprint contributions of subducted basaltic ocean crust, while the correlation with low Lu/Hf indicates melting in the presence of residual garnet, which reflects conversion of the subducted oceanic crust to eclogite. Isotopic and chemical mass balance considerations indicate that the slab melts are ~ 80% basaltic oceanic crust and ~ 20% subducted sediment. The calc-alkaline lavas have higher SiO2 at a given Mg# compared to the high-Nb alkaline lavas, also reflecting melt contributions from the subducted slab. A survey of global arc lavas shows that calc-alkaline lavas with low Lu/Hf ratios, reflecting melting in the presence of residual garnet and preferential mobilization of Hf over Lu from the subducted slab, are generally associated with hot slab conditions. These include arcs where young (< 30 Ma old) ocean crust is subducted (e.g. Mexican Volcanic Belt, Cascades, Austral Andes, Luzon, Setouchi), where slab tearing occurred and hot asthenospheric mantle could upwell through the slab window (e.g., western Aleutians, Sunda, southern Scotia), and where oblique or slow subduction leads to higher slab temperatures (e.g. Lesser Antilles, western Aleutians). In some of these hot slab arcs, where low Lu/Hf ratios are coupled with high Nd-Hf isotope ratios, slab melt contributions are dominated by partial melts from the subducted oceanic basalt (e.g., Mexican Volcanic Belt, Aleutians and Cascades). In other hot slab arcs, low Lu/Hf ratios are coupled with low Nd-Hf isotope ratios, reflecting slab contributions dominated by sediment melts (e.g. Setouchi, Lesser Antilles, Luzon, Sunda, and southern Scotia). Arcs associated with colder subducted oceanic crust (e.g. Izu-Bonin-Marianas, Tonga-Kermadec, central and northern Scotia) erupt lavas with high Lu/Hf along with high Hf-Nd isotope ratios, similar to mid-ocean ridge basalts, thus they lack the signature of residual garnet as well as significant slab melt input.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_857524
institution PANGAEA
language en
publishDate 2016
publisher PANGAEA
record_format pangaea
spellingShingle Geochemical analysis on lavas from Nevado de Toluca, Central Mexican Volcanic Belt and from the Cocos plate
Cai, Yue
LaGatta, Alexandra
Goldstein, Steven L
Langmuir, Charles H
Gómez-Tuena, Arturo
Martín-del Pozzo, Ana Lillian
Carrasco-Núñez, Gerardo

This study presents evidence that Quaternary frontal arc calc-alkaline lavas from Central Mexican Volcanic Belt (CMVB) contain contributions from partial melts of the subducting garnet-bearing eclogitic oceanic crust and sediment, based on chemical and Hf-Nd isotope data. The CMVB includes both calc-alkaline lavas with arc-type trace element patterns such as aqueous fluid mobile element enrichments and high field strength element depletions; and "high-Nb" alkaline lavas with trace element patterns similar to ocean island basalts. The two types of lavas are closely related geographically and temporally. Distinct from the high-Nb lavas, the calc-alkaline lavas show trends toward higher 176Hf/177Hf and 143Nd/144Nd ratios coupled with lower Lu/Hf. The high Hf-Nd isotope ratios fingerprint contributions of subducted basaltic ocean crust, while the correlation with low Lu/Hf indicates melting in the presence of residual garnet, which reflects conversion of the subducted oceanic crust to eclogite. Isotopic and chemical mass balance considerations indicate that the slab melts are ~ 80% basaltic oceanic crust and ~ 20% subducted sediment. The calc-alkaline lavas have higher SiO2 at a given Mg# compared to the high-Nb alkaline lavas, also reflecting melt contributions from the subducted slab. A survey of global arc lavas shows that calc-alkaline lavas with low Lu/Hf ratios, reflecting melting in the presence of residual garnet and preferential mobilization of Hf over Lu from the subducted slab, are generally associated with hot slab conditions. These include arcs where young (< 30 Ma old) ocean crust is subducted (e.g. Mexican Volcanic Belt, Cascades, Austral Andes, Luzon, Setouchi), where slab tearing occurred and hot asthenospheric mantle could upwell through the slab window (e.g., western Aleutians, Sunda, southern Scotia), and where oblique or slow subduction leads to higher slab temperatures (e.g. Lesser Antilles, western Aleutians). In some of these hot slab arcs, where low Lu/Hf ratios are coupled with high Nd-Hf isotope ratios, slab melt contributions are dominated by partial melts from the subducted oceanic basalt (e.g., Mexican Volcanic Belt, Aleutians and Cascades). In other hot slab arcs, low Lu/Hf ratios are coupled with low Nd-Hf isotope ratios, reflecting slab contributions dominated by sediment melts (e.g. Setouchi, Lesser Antilles, Luzon, Sunda, and southern Scotia). Arcs associated with colder subducted oceanic crust (e.g. Izu-Bonin-Marianas, Tonga-Kermadec, central and northern Scotia) erupt lavas with high Lu/Hf along with high Hf-Nd isotope ratios, similar to mid-ocean ridge basalts, thus they lack the signature of residual garnet as well as significant slab melt input.
title Geochemical analysis on lavas from Nevado de Toluca, Central Mexican Volcanic Belt and from the Cocos plate
topic
url https://doi.org/10.1594/PANGAEA.857524