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Main Authors: Lattaud, Julie, Kim, Jung-Hyun, De Jonge, Cindy, Zell, Claudia, Sinninghe Damsté, Jaap S, Schouten, Stefan
Format: Dataset Open Access
Language:en
Published: PANGAEA 2017
Subjects:
Online Access:https://doi.org/10.1594/PANGAEA.870476
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author Lattaud, Julie
Kim, Jung-Hyun
De Jonge, Cindy
Zell, Claudia
Sinninghe Damsté, Jaap S
Schouten, Stefan
author_facet Lattaud, Julie
Kim, Jung-Hyun
De Jonge, Cindy
Zell, Claudia
Sinninghe Damsté, Jaap S
Schouten, Stefan
collection Datos científicos de ciencias marinas y ambientales
contents Long chain alkyl diols are lipids that occur ubiquitously in marine sediments and are used as a proxy for sea surface temperature (SST), using the Long chain Diol Index (LDI), and for upwelling intensity/high nutrient conditions. The distribution of 1,13- and 1,15-diols has been documented in open marine and lacustrine sediments and suspended particulate matter, but rarely in coastal seas receiving a significant riverine, and thus continental organic matter, input. Here we studied the distribution of diols in four shelf seas with major river outflows: the Gulf of Lion, the Kara Sea, the Amazon shelf and the Berau delta, covering a wide range of climate conditions. The relative abundance of the C32 1,15-diol is consistently higher close to the river mouth and particularly in the suspended particulate matter of the rivers suggesting a terrigenous source. This is supported by statistical analysis which points out a significant positive correlation between the C32 1,15-diol and the Branched and Isoprenoid Tetraether index, a proxy reflecting soil and riverine input in marine environments. However, the C32 1,15-diol was not detected in soils and is unlikely to be derived from vegetation, suggesting that the C32 1,15-diol is mainly produced in rivers. This agrees with the observation that it is a dominant diol in most cultivated freshwater eustigmatophyte algae. We, therefore, suggest that the relative abundance of the C32 1,15-diol can potentially be used as a proxy for riverine organic matter input in shelf seas. Our results also show that long chain alkyl diols delivered by rivers can substantially affect LDI-reconstructed SSTs in coastal regions close to river mouths.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_870476
institution PANGAEA
language en
publishDate 2017
publisher PANGAEA
record_format pangaea
spellingShingle Long chain alkyl diols distribution in costal seas
Lattaud, Julie
Kim, Jung-Hyun
De Jonge, Cindy
Zell, Claudia
Sinninghe Damsté, Jaap S
Schouten, Stefan

Long chain alkyl diols are lipids that occur ubiquitously in marine sediments and are used as a proxy for sea surface temperature (SST), using the Long chain Diol Index (LDI), and for upwelling intensity/high nutrient conditions. The distribution of 1,13- and 1,15-diols has been documented in open marine and lacustrine sediments and suspended particulate matter, but rarely in coastal seas receiving a significant riverine, and thus continental organic matter, input. Here we studied the distribution of diols in four shelf seas with major river outflows: the Gulf of Lion, the Kara Sea, the Amazon shelf and the Berau delta, covering a wide range of climate conditions. The relative abundance of the C32 1,15-diol is consistently higher close to the river mouth and particularly in the suspended particulate matter of the rivers suggesting a terrigenous source. This is supported by statistical analysis which points out a significant positive correlation between the C32 1,15-diol and the Branched and Isoprenoid Tetraether index, a proxy reflecting soil and riverine input in marine environments. However, the C32 1,15-diol was not detected in soils and is unlikely to be derived from vegetation, suggesting that the C32 1,15-diol is mainly produced in rivers. This agrees with the observation that it is a dominant diol in most cultivated freshwater eustigmatophyte algae. We, therefore, suggest that the relative abundance of the C32 1,15-diol can potentially be used as a proxy for riverine organic matter input in shelf seas. Our results also show that long chain alkyl diols delivered by rivers can substantially affect LDI-reconstructed SSTs in coastal regions close to river mouths.
title Long chain alkyl diols distribution in costal seas
topic
url https://doi.org/10.1594/PANGAEA.870476