A MATLAB algorithm for the quantification of NGR spectra

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Auteurs principaux: De Vleeschouwer, David, Dunlea, Ann G, Auer, Gerald, Anderson, Chloe H, Brumsack, Hans-Jürgen, de Loach, Aaron, Gurnis, Michael, Huh, Youngsook, Ishiwa, Takeshige, Jang, Kwangchul, Kominz, Michelle A, März, Christian, Schnetger, Bernhard, Murray, Richard W, Pälike, Heiko, Expedition 356 shipboard scientists
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 2017
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author De Vleeschouwer, David
Dunlea, Ann G
Auer, Gerald
Anderson, Chloe H
Brumsack, Hans-Jürgen
de Loach, Aaron
Gurnis, Michael
Huh, Youngsook
Ishiwa, Takeshige
Jang, Kwangchul
Kominz, Michelle A
März, Christian
Schnetger, Bernhard
Murray, Richard W
Pälike, Heiko
Expedition 356 shipboard scientists
author_facet De Vleeschouwer, David
Dunlea, Ann G
Auer, Gerald
Anderson, Chloe H
Brumsack, Hans-Jürgen
de Loach, Aaron
Gurnis, Michael
Huh, Youngsook
Ishiwa, Takeshige
Jang, Kwangchul
Kominz, Michelle A
März, Christian
Schnetger, Bernhard
Murray, Richard W
Pälike, Heiko
Expedition 356 shipboard scientists
collection Datos científicos de ciencias marinas y ambientales
contents During International Ocean Discovery Program (IODP) expeditions, shipboardgenerated data provide the first insights into the cored sequences. The natural gamma radiation (NGR) of the recovered material, for example, is routinely measured on the ocean drilling research vessel DV JOIDES Resolution. At present, only total NGR counts are readily available as shipboard data, although full NGR spectra (counts as a function of gamma-ray energy level) are produced and archived. These spectra contain unexploited information, as one can estimate the sedimentary contents of potassium (K), thorium (Th), and uranium (U) from the characteristic gamma-ray energies of isotopes in the 40K, 232Th, and 238U radioactive decay series. Dunlea et al. [2013] quantified K, Th and U contents in sediment from the South Pacific Gyre by integrating counts over specific energy levels of the NGR spectrum. However, the algorithm used in their study is unavailable to the wider scientific community due to commercial proprietary reasons. Here, we present a new MATLAB algorithm for the quantification of NGR spectra that is transparent and accessible to future NGR users. We demonstrate the algorithm's performance by comparing its results to shore-based inductively coupled plasma-mass spectrometry (ICP-MS), inductively coupled plasma-emission spectrometry (ICP-ES), and quantitative wavelength-dispersive X-ray fluorescence (XRF) analyses. Samples for these comparisons come from eleven sites (U1341, U1343, U1366-U1369, U1414, U1428- U1430, U1463) cored in two oceans during five expeditions. In short, our algorithm rapidly produces detailed high-quality information on sediment properties during IODP expeditions at no extra cost.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_872654
institution PANGAEA
language en
publishDate 2017
publisher PANGAEA
record_format pangaea
spellingShingle A MATLAB algorithm for the quantification of NGR spectra
De Vleeschouwer, David
Dunlea, Ann G
Auer, Gerald
Anderson, Chloe H
Brumsack, Hans-Jürgen
de Loach, Aaron
Gurnis, Michael
Huh, Youngsook
Ishiwa, Takeshige
Jang, Kwangchul
Kominz, Michelle A
März, Christian
Schnetger, Bernhard
Murray, Richard W
Pälike, Heiko
Expedition 356 shipboard scientists
Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP
During International Ocean Discovery Program (IODP) expeditions, shipboardgenerated data provide the first insights into the cored sequences. The natural gamma radiation (NGR) of the recovered material, for example, is routinely measured on the ocean drilling research vessel DV JOIDES Resolution. At present, only total NGR counts are readily available as shipboard data, although full NGR spectra (counts as a function of gamma-ray energy level) are produced and archived. These spectra contain unexploited information, as one can estimate the sedimentary contents of potassium (K), thorium (Th), and uranium (U) from the characteristic gamma-ray energies of isotopes in the 40K, 232Th, and 238U radioactive decay series. Dunlea et al. [2013] quantified K, Th and U contents in sediment from the South Pacific Gyre by integrating counts over specific energy levels of the NGR spectrum. However, the algorithm used in their study is unavailable to the wider scientific community due to commercial proprietary reasons. Here, we present a new MATLAB algorithm for the quantification of NGR spectra that is transparent and accessible to future NGR users. We demonstrate the algorithm's performance by comparing its results to shore-based inductively coupled plasma-mass spectrometry (ICP-MS), inductively coupled plasma-emission spectrometry (ICP-ES), and quantitative wavelength-dispersive X-ray fluorescence (XRF) analyses. Samples for these comparisons come from eleven sites (U1341, U1343, U1366-U1369, U1414, U1428- U1430, U1463) cored in two oceans during five expeditions. In short, our algorithm rapidly produces detailed high-quality information on sediment properties during IODP expeditions at no extra cost.
title A MATLAB algorithm for the quantification of NGR spectra
topic Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP
url https://doi.org/10.1594/PANGAEA.872654