(Table 2, page 1208) Average of 8 partial chemical analyses of opaque mineral grains bordering aragonite veins crossing serpentinized peridotite rocks from the Romanche Fracture Zone, Atlantic Ocean

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Main Authors: Bonatti, Enrico, Lawrence, James R, Hamlyn, P R, Breger, Dee
Format: Dataset Open Access
Language:en
Published: PANGAEA 1980
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author Bonatti, Enrico
Lawrence, James R
Hamlyn, P R
Breger, Dee
author_facet Bonatti, Enrico
Lawrence, James R
Hamlyn, P R
Breger, Dee
collection Datos científicos de ciencias marinas y ambientales
contents Aragonite mineralization was observed in serpentinized peridotites from the Romanche and Vema Fracture Zones in the Atlantic and the Owen Fracture Zone in the Indian Ocean, either in veins or as radial aggregates in cavities within the serpentinites. Evidence of incipient dissolution of the aragonite crystals was observed in one case. The aragonites tend to have lower Mg content (< 0.03%) and higher Sr content (> 0.95%) relative to other marine aragonites. Their 18O16O, 13C12C and 87Sr86Sr isotopic ratios suggest the aragonite was deposited at ocean floor temperatures from solutions derived from sea water circulating in fissures and fractures within the ultramafic rocks. The 18O16O ratios of the serpentines indicate serpentinization occurred at higher temperatures, probably deeper in the crust. Low-T reactions between circulating seawater and Mg-silicates (primarily serpentine and pyroxenes) caused high pH and enrichment of Mg and Ca in the solution, conditions favoring carbonate precipitation. Aragonite was formed rather than calcite presumably because the high Mg2+ concentration in the solution inhibited calcite precipitation. The high Sr content of the aragonites is probably related, at least in part, to their low temperature of formation. Opaque mineral grains containing over 8% NiO and over 40% MnO were observed concentrated along the margins of some of the aragonite veins, suggesting that Ni is one of the elements mobilized during reactions between ultramafic rocks and circulating seawater.
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institution PANGAEA
language en
publishDate 1980
publisher PANGAEA
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spellingShingle (Table 2, page 1208) Average of 8 partial chemical analyses of opaque mineral grains bordering aragonite veins crossing serpentinized peridotite rocks from the Romanche Fracture Zone, Atlantic Ocean
Bonatti, Enrico
Lawrence, James R
Hamlyn, P R
Breger, Dee
Aluminium oxide; Calcium oxide; Deposit type; DEPTH, sediment/rock; Description; Dredge; DRG; Electron microprobe (EMP); G-7309; G-7309-81; Gerda; Identification; Iron oxide, FeO; Magnesium oxide; Manganese oxide; Nickel oxide; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Potassium oxide; Romanche Fracture Zone, Atlantic Ocean; Sample code/label; Silicon dioxide; Sodium oxide; Substrate type
Aragonite mineralization was observed in serpentinized peridotites from the Romanche and Vema Fracture Zones in the Atlantic and the Owen Fracture Zone in the Indian Ocean, either in veins or as radial aggregates in cavities within the serpentinites. Evidence of incipient dissolution of the aragonite crystals was observed in one case. The aragonites tend to have lower Mg content (< 0.03%) and higher Sr content (> 0.95%) relative to other marine aragonites. Their 18O16O, 13C12C and 87Sr86Sr isotopic ratios suggest the aragonite was deposited at ocean floor temperatures from solutions derived from sea water circulating in fissures and fractures within the ultramafic rocks. The 18O16O ratios of the serpentines indicate serpentinization occurred at higher temperatures, probably deeper in the crust. Low-T reactions between circulating seawater and Mg-silicates (primarily serpentine and pyroxenes) caused high pH and enrichment of Mg and Ca in the solution, conditions favoring carbonate precipitation. Aragonite was formed rather than calcite presumably because the high Mg2+ concentration in the solution inhibited calcite precipitation. The high Sr content of the aragonites is probably related, at least in part, to their low temperature of formation. Opaque mineral grains containing over 8% NiO and over 40% MnO were observed concentrated along the margins of some of the aragonite veins, suggesting that Ni is one of the elements mobilized during reactions between ultramafic rocks and circulating seawater.
title (Table 2, page 1208) Average of 8 partial chemical analyses of opaque mineral grains bordering aragonite veins crossing serpentinized peridotite rocks from the Romanche Fracture Zone, Atlantic Ocean
topic Aluminium oxide; Calcium oxide; Deposit type; DEPTH, sediment/rock; Description; Dredge; DRG; Electron microprobe (EMP); G-7309; G-7309-81; Gerda; Identification; Iron oxide, FeO; Magnesium oxide; Manganese oxide; Nickel oxide; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Potassium oxide; Romanche Fracture Zone, Atlantic Ocean; Sample code/label; Silicon dioxide; Sodium oxide; Substrate type
url https://doi.org/10.1594/PANGAEA.873506