Branched tetraether lipids from the Tagus River basin to the coastal ocean of the Portuguese margin

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Auteurs principaux: Zell, Claudia, Kim, Jung-Hyun, Balsinha, M, Dorhout, Denise J C, Fernandes, C, Baas, Marianne, Sinninghe Damsté, Jaap S
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 2014
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author Zell, Claudia
Kim, Jung-Hyun
Balsinha, M
Dorhout, Denise J C
Fernandes, C
Baas, Marianne
Sinninghe Damsté, Jaap S
author_facet Zell, Claudia
Kim, Jung-Hyun
Balsinha, M
Dorhout, Denise J C
Fernandes, C
Baas, Marianne
Sinninghe Damsté, Jaap S
collection Datos científicos de ciencias marinas y ambientales
contents Branched glycerol dialkyl glycerol tetraethers (brGDGTs), which are thought to be transported from soil to marine sediment by rivers, have been used to reconstruct the mean annual air temperature (MAAT) and soil pH of the drainage basin using the methylation index of branched tetraethers (MBT, recently refined as MBT') and cyclization index of branched tetraethers (CBT) from coastal marine sediment records. In this study we are tracing the brGDGTs from source to sink in the Tagus River basin, the longest river system on the Iberian Peninsula, by determining their concentration and distribution in soils, river suspended particulate matter (SPM), riverbank sediments, marine SPM, and marine surface sediments. The concentrations of brGDGTs in river SPM were substantially higher and their distributions were different compared to those of the drainage basin soils. This indicates that brGDGTs are mainly produced in the river itself. In the marine environment, the brGDGT concentrations rapidly decreased with increasing distance from the Tagus estuary. At the same time, the brGDGT distributions in marine sediments also changed, indicating that marine in-situ production also takes place. These results show that there are various problems that complicate the use of the MBT'/CBT for paleoreconstructions using coastal marine sediments in the vicinity of a river. However, if the majority of brGDGTs are produced in the river, it might be possible to reconstruct the environmental (temperature and pH) conditions of the river water using appropriate aquatic calibrations, provided that marine core locations are chosen in such a way that the brGDGTs in their sediments are predominantly derived from riverine in-situ production.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_879332
institution PANGAEA
language en
publishDate 2014
publisher PANGAEA
record_format pangaea
spellingShingle Branched tetraether lipids from the Tagus River basin to the coastal ocean of the Portuguese margin
Zell, Claudia
Kim, Jung-Hyun
Balsinha, M
Dorhout, Denise J C
Fernandes, C
Baas, Marianne
Sinninghe Damsté, Jaap S
NIOZ_UU; NIOZ Royal Netherlands Institute for Sea Research, and Utrecht University
Branched glycerol dialkyl glycerol tetraethers (brGDGTs), which are thought to be transported from soil to marine sediment by rivers, have been used to reconstruct the mean annual air temperature (MAAT) and soil pH of the drainage basin using the methylation index of branched tetraethers (MBT, recently refined as MBT') and cyclization index of branched tetraethers (CBT) from coastal marine sediment records. In this study we are tracing the brGDGTs from source to sink in the Tagus River basin, the longest river system on the Iberian Peninsula, by determining their concentration and distribution in soils, river suspended particulate matter (SPM), riverbank sediments, marine SPM, and marine surface sediments. The concentrations of brGDGTs in river SPM were substantially higher and their distributions were different compared to those of the drainage basin soils. This indicates that brGDGTs are mainly produced in the river itself. In the marine environment, the brGDGT concentrations rapidly decreased with increasing distance from the Tagus estuary. At the same time, the brGDGT distributions in marine sediments also changed, indicating that marine in-situ production also takes place. These results show that there are various problems that complicate the use of the MBT'/CBT for paleoreconstructions using coastal marine sediments in the vicinity of a river. However, if the majority of brGDGTs are produced in the river, it might be possible to reconstruct the environmental (temperature and pH) conditions of the river water using appropriate aquatic calibrations, provided that marine core locations are chosen in such a way that the brGDGTs in their sediments are predominantly derived from riverine in-situ production.
title Branched tetraether lipids from the Tagus River basin to the coastal ocean of the Portuguese margin
topic NIOZ_UU; NIOZ Royal Netherlands Institute for Sea Research, and Utrecht University
url https://doi.org/10.1594/PANGAEA.879332