XRF, carbon and CaCO3 data from the loess-paleosol sequence Süttö, Hungary

Fuente: PANGAEA
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Autores principales: Profe, Jörn, Neumann, Lena, Novothny, Ágnes, Barta, Gabriella, Rolf, Christian, Frechen, Manfred, Ohlendorf, Christian, Zolitschka, Bernd
Formato: Dataset Open Access
Lenguaje:en
Publicado: PANGAEA 2017
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author Profe, Jörn
Neumann, Lena
Novothny, Ágnes
Barta, Gabriella
Rolf, Christian
Frechen, Manfred
Ohlendorf, Christian
Zolitschka, Bernd
author_facet Profe, Jörn
Neumann, Lena
Novothny, Ágnes
Barta, Gabriella
Rolf, Christian
Frechen, Manfred
Ohlendorf, Christian
Zolitschka, Bernd
collection Datos científicos de ciencias marinas y ambientales
contents This study provides a detailed geochemical record of one of the most detailed loess-paleosol sequence (LPS) in Hungary covering Marine Isotope Stage (MIS) 6 to MIS 2. Süttő is situated in the northwestern Carpathian Basin at the transition between oceanic and continental climate. We investigated weathering intensity, dust provenance and sedimentation dynamics by high-resolution X-ray fluorescence (XRF) scanning of discrete samples in comparison with quantitative XRF and other published proxy data such as grain-size, magnetic susceptibility and micromorphology. Multivariate statistics unravel pedogenesis in terms of decalcification and grain-size dynamics as processes controlling the elemental composition. Furthermore, high-resolution chemostratigraphy indicates geochemical homogeneity for mature MIS 5 paleosols and the modern soil. Together with the A-CN-K plot providing no hint for K-feldspar weathering, semi-arid continental paleoenvironmental conditions are considered as prevailing. Dust provenance is studied by geochemical reference literature data from potential ultimate dust source areas, Th/metal ratios and comparison with the composition of the upper continental crust (UCC). Results indicate a felsic rock composition and a stable dust source, albeit immediate (adjacent Danube floodplains) and ultimate dust sources (surrounding mountain belts) need to be distinguished. According to the Sr-K-Rb plot, the Austroalpine cover nappes area northwest of Süttő might be the dominant ultimate dust source. The weathering-resistant elements Al, Ti and Zr as well as Zr/metal ratios indicate Zr addition and thus strongest sediment sorting and/ or recycling during MIS 6. Since Al, Ti and Zr show minimal correlations with grain-size, we suggest a cascade-alike transport pathway from ultimate source to sink involving multiple sediment recycling and sorting cycles in both fluvial and eolian domains. Therefore, this study highlights how high-resolution qualitative geochemical data contributes to a better understanding of paleoenvironmental and sedimentation dynamics at LPS. Application of such a versatile geochemical screening tool is of broad interest to the scientific community working on (terrestrial) paleoenvironmental archives that are commonly discretely sampled.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_884092
institution PANGAEA
language en
publishDate 2017
publisher PANGAEA
record_format pangaea
spellingShingle XRF, carbon and CaCO3 data from the loess-paleosol sequence Süttö, Hungary
Profe, Jörn
Neumann, Lena
Novothny, Ágnes
Barta, Gabriella
Rolf, Christian
Frechen, Manfred
Ohlendorf, Christian
Zolitschka, Bernd
Aluminium; Barium; Calcium; Calcium carbonate; Carbon, inorganic, total; Carbon, organic, total; Carbon, total; Hungary; Iron; Lithologic unit/sequence; Manganese; Mean squared error; Molybdenum; Potassium; Rubidium; SECTION, height; Silicon; Strontium; Suettoe; Titanium; X-ray fluorescence ITRAX core scanner, Mo-tube 30kV 31mA 100s, Bremen; Zirconium
This study provides a detailed geochemical record of one of the most detailed loess-paleosol sequence (LPS) in Hungary covering Marine Isotope Stage (MIS) 6 to MIS 2. Süttő is situated in the northwestern Carpathian Basin at the transition between oceanic and continental climate. We investigated weathering intensity, dust provenance and sedimentation dynamics by high-resolution X-ray fluorescence (XRF) scanning of discrete samples in comparison with quantitative XRF and other published proxy data such as grain-size, magnetic susceptibility and micromorphology. Multivariate statistics unravel pedogenesis in terms of decalcification and grain-size dynamics as processes controlling the elemental composition. Furthermore, high-resolution chemostratigraphy indicates geochemical homogeneity for mature MIS 5 paleosols and the modern soil. Together with the A-CN-K plot providing no hint for K-feldspar weathering, semi-arid continental paleoenvironmental conditions are considered as prevailing. Dust provenance is studied by geochemical reference literature data from potential ultimate dust source areas, Th/metal ratios and comparison with the composition of the upper continental crust (UCC). Results indicate a felsic rock composition and a stable dust source, albeit immediate (adjacent Danube floodplains) and ultimate dust sources (surrounding mountain belts) need to be distinguished. According to the Sr-K-Rb plot, the Austroalpine cover nappes area northwest of Süttő might be the dominant ultimate dust source. The weathering-resistant elements Al, Ti and Zr as well as Zr/metal ratios indicate Zr addition and thus strongest sediment sorting and/ or recycling during MIS 6. Since Al, Ti and Zr show minimal correlations with grain-size, we suggest a cascade-alike transport pathway from ultimate source to sink involving multiple sediment recycling and sorting cycles in both fluvial and eolian domains. Therefore, this study highlights how high-resolution qualitative geochemical data contributes to a better understanding of paleoenvironmental and sedimentation dynamics at LPS. Application of such a versatile geochemical screening tool is of broad interest to the scientific community working on (terrestrial) paleoenvironmental archives that are commonly discretely sampled.
title XRF, carbon and CaCO3 data from the loess-paleosol sequence Süttö, Hungary
topic Aluminium; Barium; Calcium; Calcium carbonate; Carbon, inorganic, total; Carbon, organic, total; Carbon, total; Hungary; Iron; Lithologic unit/sequence; Manganese; Mean squared error; Molybdenum; Potassium; Rubidium; SECTION, height; Silicon; Strontium; Suettoe; Titanium; X-ray fluorescence ITRAX core scanner, Mo-tube 30kV 31mA 100s, Bremen; Zirconium
url https://doi.org/10.1594/PANGAEA.884092