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Main Authors: Vopel, Kay, Del-Río, Vopel, Pilditch, Conrad A
Format: Dataset Open Access
Language:en
Published: PANGAEA 2018
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Online Access:https://doi.org/10.1594/PANGAEA.887792
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author Vopel, Kay
Del-Río, Vopel
Pilditch, Conrad A
author_facet Vopel, Kay
Del-Río, Vopel
Pilditch, Conrad A
collection Datos científicos de ciencias marinas y ambientales
contents Ocean acidification may alter the cycling of nitrogen in coastal sediment and so the sediment-seawater nitrogen flux, an important driver of pelagic productivity. To investigate how this perturbation affects the fluxes of NOX- (nitrite/nitrate), NH4+ and O2, we incubated estuarine sand and subtidal silt in recirculating seawater with a CO2-adjusted pH of 8.1 and 7.9. During a 41-day incubation, the seawater kept at pH 8.1 lost 97% of its NOX- content but the seawater kept at pH 7.9 lost only 18%. Excess CO2 increased benthic photosynthesis. In the silt, this was accompanied by a reversal of the initial NOX- efflux into influx. The estuarine sand sustained its initial NOX- influx but, by the end of the incubation, released more NH4+ at pH 7.9 than at pH 8.1. We hypothesise that these effects share a common cause; excess CO2 increased the growth of benthic microalgae and so nutrient competition with ammonia oxidising bacteria (AOB). In the silt, diatoms likely outcompeted AOB for NH4+ and photosynthesis increased the dark/light fluctuations in the pore water oxygenation inhibiting nitrification and coupled nitrification/denitrification. If this is correct, then excess CO2 may lead to retention of inorganic nitrogen adding to the pressures of increasing coastal eutrophication.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_887792
institution PANGAEA
language en
publishDate 2018
publisher PANGAEA
record_format pangaea
spellingShingle Seawater carbonate chemistry and benthic primary production and inorganic nitrogen fluxes in two coastal sediments
Vopel, Kay
Del-Río, Vopel
Pilditch, Conrad A
Alkalinity, total; Alkalinity, total, standard deviation; Ammonium; Ammonium, flux; Ammonium, standard deviation; Aragonite saturation state; Benthos; Bicarbonate ion; Calcite saturation state; Calculated using CO2calc; Calculated using seacarb after Nisumaa et al. (2010); Carbon, inorganic, dissolved; Carbon, inorganic, dissolved, standard deviation; Carbonate ion; Carbonate system computation flag; Carbon dioxide; Coast and continental shelf; Containers and aquaria (20-1000 L or < 1 m**2); Difference; Entire community; Event label; EXP; Experiment; Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Hauraki_Gulf; Identification; Laboratory experiment; Light mode; Nitrate and Nitrite; Nitrate and Nitrite, standard deviation; Nitrite and nitrate, flux; OA-ICC; Ocean acidification; Ocean Acidification International Coordination Centre; Other studied parameter or process; Oxygen uptake, total; Partial pressure of carbon dioxide, standard deviation; Partial pressure of carbon dioxide (water) at sea surface temperature (wet air); pH, standard deviation; pH, total scale; Potentiometric; Salinity; Salinity, standard deviation; Sediment type; Soft-bottom community; South Pacific; Tauranga_Harbour; Temperate; Temperature, water; Temperature, water, standard deviation; Time point, descriptive; Treatment; Type
Ocean acidification may alter the cycling of nitrogen in coastal sediment and so the sediment-seawater nitrogen flux, an important driver of pelagic productivity. To investigate how this perturbation affects the fluxes of NOX- (nitrite/nitrate), NH4+ and O2, we incubated estuarine sand and subtidal silt in recirculating seawater with a CO2-adjusted pH of 8.1 and 7.9. During a 41-day incubation, the seawater kept at pH 8.1 lost 97% of its NOX- content but the seawater kept at pH 7.9 lost only 18%. Excess CO2 increased benthic photosynthesis. In the silt, this was accompanied by a reversal of the initial NOX- efflux into influx. The estuarine sand sustained its initial NOX- influx but, by the end of the incubation, released more NH4+ at pH 7.9 than at pH 8.1. We hypothesise that these effects share a common cause; excess CO2 increased the growth of benthic microalgae and so nutrient competition with ammonia oxidising bacteria (AOB). In the silt, diatoms likely outcompeted AOB for NH4+ and photosynthesis increased the dark/light fluctuations in the pore water oxygenation inhibiting nitrification and coupled nitrification/denitrification. If this is correct, then excess CO2 may lead to retention of inorganic nitrogen adding to the pressures of increasing coastal eutrophication.
title Seawater carbonate chemistry and benthic primary production and inorganic nitrogen fluxes in two coastal sediments
topic Alkalinity, total; Alkalinity, total, standard deviation; Ammonium; Ammonium, flux; Ammonium, standard deviation; Aragonite saturation state; Benthos; Bicarbonate ion; Calcite saturation state; Calculated using CO2calc; Calculated using seacarb after Nisumaa et al. (2010); Carbon, inorganic, dissolved; Carbon, inorganic, dissolved, standard deviation; Carbonate ion; Carbonate system computation flag; Carbon dioxide; Coast and continental shelf; Containers and aquaria (20-1000 L or < 1 m**2); Difference; Entire community; Event label; EXP; Experiment; Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Hauraki_Gulf; Identification; Laboratory experiment; Light mode; Nitrate and Nitrite; Nitrate and Nitrite, standard deviation; Nitrite and nitrate, flux; OA-ICC; Ocean acidification; Ocean Acidification International Coordination Centre; Other studied parameter or process; Oxygen uptake, total; Partial pressure of carbon dioxide, standard deviation; Partial pressure of carbon dioxide (water) at sea surface temperature (wet air); pH, standard deviation; pH, total scale; Potentiometric; Salinity; Salinity, standard deviation; Sediment type; Soft-bottom community; South Pacific; Tauranga_Harbour; Temperate; Temperature, water; Temperature, water, standard deviation; Time point, descriptive; Treatment; Type
url https://doi.org/10.1594/PANGAEA.887792