Major ions in Fimbul Ice Shelf, Antarctica

Fuente: PANGAEA
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Autores principales: Vega, Carmen Paulina, Isaksson, Elisabeth, Schlosser, Elisabeth, Divine, Dmitry V, Martma, Tõnu, Mulvaney, Robert, Eichler, Anja, Schwikowski-Gigar, Margit
Formato: Dataset Open Access
Lenguaje:en
Publicado: PANGAEA 2018
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author Vega, Carmen Paulina
Isaksson, Elisabeth
Schlosser, Elisabeth
Divine, Dmitry V
Martma, Tõnu
Mulvaney, Robert
Eichler, Anja
Schwikowski-Gigar, Margit
author_facet Vega, Carmen Paulina
Isaksson, Elisabeth
Schlosser, Elisabeth
Divine, Dmitry V
Martma, Tõnu
Mulvaney, Robert
Eichler, Anja
Schwikowski-Gigar, Margit
collection Datos científicos de ciencias marinas y ambientales
contents Major ions were analysed in firn/ice cores located at Fimbul Ice Shelf (FIS), Dronning Maud Land – DML, Antarctica. FIS is the largest ice shelf in the Haakon VII Sea, with an extent of approximately 36 500 km2. Three shallow firn cores (about 20 m deep) were retrieved in different ice-rises, Kupol Ciolkovskogo (KC), Kupol Moskovskij (KM), and Blåskimen Island (BI), while a 100 m long core (S100) was drilled near the FIS edge. These sites are distributed over the entire FIS area so that they provide a variety of elevation (50–400 m a.s.l.) and distance (3– 42 km) to the sea. Sea-salt species (mainly Na+ and Cl−) generally dominate the precipitation chemistry in the study region. We associate a significant six-fold increase in median sea-salt concentrations, observed in the S100 core after the 1950s, to an enhanced exposure of the 100 site to primary sea-salt aerosol due to a shorter distance from the S100 site to the ice front, and to enhanced sea-salt aerosol production from blowing salty snow over sea ice, most likely related to the calving of Trolltunga occurred during the 1960s. This increase in sea-salt concentrations is synchronous with a shift in non-sea-salt sulfate (nssSO42−) toward negative values, suggesting a possible contribution of fractionated aerosol to the sea-salt load in the S100 core most likely originating from salty snow found on sea ice. In contrast, there is no evidence of a significant contribution of fractionated sea-salt to the ice-rises sites, where the signal would be most likely masked by the large inputs of biogenic sulfate estimated for these sites. In summary, these results suggest that the S100 core contains a sea-salt record dominated by the proximity of the site to the ocean, and processes of sea ice formation in the neighbouring waters. In contrast, the ice-rises firn cores register a larger-scale signal of atmospheric flow conditions and a less efficient transport of sea-salt aerosols to these sites. These findings are a contribution to the understanding of the mechanisms behind sea-salt aerosol production, transport and deposition at coastal Antarctic sites, and the improvement of the current Antarctic sea ice reconstructions based on sea-salt chemical proxies obtained from ice cores.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_889018
institution PANGAEA
language en
publishDate 2018
publisher PANGAEA
record_format pangaea
spellingShingle Major ions in Fimbul Ice Shelf, Antarctica
Vega, Carmen Paulina
Isaksson, Elisabeth
Schlosser, Elisabeth
Divine, Dmitry V
Martma, Tõnu
Mulvaney, Robert
Eichler, Anja
Schwikowski-Gigar, Margit

Major ions were analysed in firn/ice cores located at Fimbul Ice Shelf (FIS), Dronning Maud Land – DML, Antarctica. FIS is the largest ice shelf in the Haakon VII Sea, with an extent of approximately 36 500 km2. Three shallow firn cores (about 20 m deep) were retrieved in different ice-rises, Kupol Ciolkovskogo (KC), Kupol Moskovskij (KM), and Blåskimen Island (BI), while a 100 m long core (S100) was drilled near the FIS edge. These sites are distributed over the entire FIS area so that they provide a variety of elevation (50–400 m a.s.l.) and distance (3– 42 km) to the sea. Sea-salt species (mainly Na+ and Cl−) generally dominate the precipitation chemistry in the study region. We associate a significant six-fold increase in median sea-salt concentrations, observed in the S100 core after the 1950s, to an enhanced exposure of the 100 site to primary sea-salt aerosol due to a shorter distance from the S100 site to the ice front, and to enhanced sea-salt aerosol production from blowing salty snow over sea ice, most likely related to the calving of Trolltunga occurred during the 1960s. This increase in sea-salt concentrations is synchronous with a shift in non-sea-salt sulfate (nssSO42−) toward negative values, suggesting a possible contribution of fractionated aerosol to the sea-salt load in the S100 core most likely originating from salty snow found on sea ice. In contrast, there is no evidence of a significant contribution of fractionated sea-salt to the ice-rises sites, where the signal would be most likely masked by the large inputs of biogenic sulfate estimated for these sites. In summary, these results suggest that the S100 core contains a sea-salt record dominated by the proximity of the site to the ocean, and processes of sea ice formation in the neighbouring waters. In contrast, the ice-rises firn cores register a larger-scale signal of atmospheric flow conditions and a less efficient transport of sea-salt aerosols to these sites. These findings are a contribution to the understanding of the mechanisms behind sea-salt aerosol production, transport and deposition at coastal Antarctic sites, and the improvement of the current Antarctic sea ice reconstructions based on sea-salt chemical proxies obtained from ice cores.
title Major ions in Fimbul Ice Shelf, Antarctica
topic
url https://doi.org/10.1594/PANGAEA.889018