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Main Authors: Fehrenbacher, Jennifer, Russell, Ann D, Davis, Catherine V, Spero, Howard J, Chu, Edward, Hönisch, Bärbel
Format: Dataset Open Access
Language:en
Published: PANGAEA 2018
Subjects:
Online Access:https://doi.org/10.1594/PANGAEA.895794
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author Fehrenbacher, Jennifer
Russell, Ann D
Davis, Catherine V
Spero, Howard J
Chu, Edward
Hönisch, Bärbel
author_facet Fehrenbacher, Jennifer
Russell, Ann D
Davis, Catherine V
Spero, Howard J
Chu, Edward
Hönisch, Bärbel
collection Datos científicos de ciencias marinas y ambientales
contents Dataset contains seawater and foraminiferal chemical composition from the paper referenced above. Paper abstract: Ba/Ca ratios in many non-spinose planktic foraminifera are markedly higher than those observed in spinose planktic species, but the cause for these high Ba/Ca ratios is not understood. A better understanding of this geochemical anomaly could provide insights into the habitat and/or controls over Ba incorporation in these species and expand their utility in paleoclimate research. In spinose species, shell Ba/Ca depends only on the Ba/Ca ratio of seawater. Proposed explanations for high non-spinose Ba/Ca include (1) the empirical partition coefficient, DBa, differs from the spinose species, (2) shell Ba varies with seawater temperature and pH, or (3) non-spinose foraminifers have a preference for prey that has elevated Ba. We performed laboratory culture experiments to determine DBa for the thermocline-dwelling non-spinose planktic foraminifer Neogloboquadrina dutertrei. We find that the Ba/Ca ratio of foraminiferal calcite secreted in the laboratory varies linearly with the Ba/Ca ratio of the seawater. The DBa for this species, 0.11 ± 0.008 (2SE; 95% CL), is similar to the DBa for spinose species (0.13 ± 0.004, 2SE; 95% CL). As in spinose species, the Ba/Ca ratio of cultured specimens of N. dutertrei is not influenced by culture temperature (12-22 °C) or seawater pHNBS (range 7.8-8.3). However, the Ba/Ca ratio of individual plankton-tow N. dutertrei specimens that completed their lifecycle in the ocean exceeds the Ba/Ca ratio of cultured specimens by up to three orders of magnitude. It is unlikely this difference between cultured specimens and ocean-grown specimens is due to seawater [Ba] variability, since seawater Ba/Ca ratios calculated using our DBa are much higher than exist in the ocean. Rather, we suggest that elevated shell Ba/Ca in plankton tow and fossil N. dutertrei is due to calcification in the microenvironment of marine organic aggregates such as marine snow, where [Ba] is elevated as a result of Ba release from biogenic particulates.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_895794
institution PANGAEA
language en
publishDate 2018
publisher PANGAEA
record_format pangaea
spellingShingle Barium/calcium ratios in planktic foraminifer Neogloboquadrina dutertrei
Fehrenbacher, Jennifer
Russell, Ann D
Davis, Catherine V
Spero, Howard J
Chu, Edward
Hönisch, Bärbel

Dataset contains seawater and foraminiferal chemical composition from the paper referenced above. Paper abstract: Ba/Ca ratios in many non-spinose planktic foraminifera are markedly higher than those observed in spinose planktic species, but the cause for these high Ba/Ca ratios is not understood. A better understanding of this geochemical anomaly could provide insights into the habitat and/or controls over Ba incorporation in these species and expand their utility in paleoclimate research. In spinose species, shell Ba/Ca depends only on the Ba/Ca ratio of seawater. Proposed explanations for high non-spinose Ba/Ca include (1) the empirical partition coefficient, DBa, differs from the spinose species, (2) shell Ba varies with seawater temperature and pH, or (3) non-spinose foraminifers have a preference for prey that has elevated Ba. We performed laboratory culture experiments to determine DBa for the thermocline-dwelling non-spinose planktic foraminifer Neogloboquadrina dutertrei. We find that the Ba/Ca ratio of foraminiferal calcite secreted in the laboratory varies linearly with the Ba/Ca ratio of the seawater. The DBa for this species, 0.11 ± 0.008 (2SE; 95% CL), is similar to the DBa for spinose species (0.13 ± 0.004, 2SE; 95% CL). As in spinose species, the Ba/Ca ratio of cultured specimens of N. dutertrei is not influenced by culture temperature (12-22 °C) or seawater pHNBS (range 7.8-8.3). However, the Ba/Ca ratio of individual plankton-tow N. dutertrei specimens that completed their lifecycle in the ocean exceeds the Ba/Ca ratio of cultured specimens by up to three orders of magnitude. It is unlikely this difference between cultured specimens and ocean-grown specimens is due to seawater [Ba] variability, since seawater Ba/Ca ratios calculated using our DBa are much higher than exist in the ocean. Rather, we suggest that elevated shell Ba/Ca in plankton tow and fossil N. dutertrei is due to calcification in the microenvironment of marine organic aggregates such as marine snow, where [Ba] is elevated as a result of Ba release from biogenic particulates.
title Barium/calcium ratios in planktic foraminifer Neogloboquadrina dutertrei
topic
url https://doi.org/10.1594/PANGAEA.895794