Rare earth element composition of manganese nodules and micronodules from the northwest Atlantic

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Main Author: Addy, Sunit Kumar
Format: Dataset Open Access
Language:en
Published: PANGAEA 2022
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author Addy, Sunit Kumar
author_facet Addy, Sunit Kumar
collection Datos científicos de ciencias marinas y ambientales
contents The shale-normalized REE patterns of manganese nodules from the northwest Atlantic show enrichment in Sm and Eu relative to the heavier and lighter REE, excluding Ce, and are similar to the patterns previously observed in deep water (> 3000m) nodules from the Pacific. The inverse relation of this pattern to that of sea water and the high Ce anomaly (average 5.5) indicate that probably the REE in the nodules originate from sea water and the nodules are possibly hydrogenous. The patterns for micronodules are similar to those of the nodules but the concentrations of REE were substantially higher in two of them. The red clay occurring on abyssal hills where nodules and micronodules are found also shows higher REE concentrations over terrigenous gray clay. The latter is devoid of nodules and micronodules and occurs in abyssal plains. The excess REE in the red clay also show a pattern similar to those of the nodules and micronodules. Most of the micronodule samples show a lower Ce anomaly (1.7) and lower Co concentration compared to the nodules, so it is inferred that at least some micronodules were formed during post-depositional periods when the conditions were less oxidizing than average.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_943839
institution PANGAEA
language en
publishDate 2022
publisher PANGAEA
record_format pangaea
spellingShingle Rare earth element composition of manganese nodules and micronodules from the northwest Atlantic
Addy, Sunit Kumar
Geochemistry; manganese micronodule; manganese nodule; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; ocean; Sediment
The shale-normalized REE patterns of manganese nodules from the northwest Atlantic show enrichment in Sm and Eu relative to the heavier and lighter REE, excluding Ce, and are similar to the patterns previously observed in deep water (> 3000m) nodules from the Pacific. The inverse relation of this pattern to that of sea water and the high Ce anomaly (average 5.5) indicate that probably the REE in the nodules originate from sea water and the nodules are possibly hydrogenous. The patterns for micronodules are similar to those of the nodules but the concentrations of REE were substantially higher in two of them. The red clay occurring on abyssal hills where nodules and micronodules are found also shows higher REE concentrations over terrigenous gray clay. The latter is devoid of nodules and micronodules and occurs in abyssal plains. The excess REE in the red clay also show a pattern similar to those of the nodules and micronodules. Most of the micronodule samples show a lower Ce anomaly (1.7) and lower Co concentration compared to the nodules, so it is inferred that at least some micronodules were formed during post-depositional periods when the conditions were less oxidizing than average.
title Rare earth element composition of manganese nodules and micronodules from the northwest Atlantic
topic Geochemistry; manganese micronodule; manganese nodule; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; ocean; Sediment
url https://doi.org/10.1594/PANGAEA.943839