δDeuterium measurements of selected n-alkanes (corrected to the VSMOW scale) in sediment core Haem13 from lake Hämelsee

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Auteurs principaux: Engels, Stefan, Lane, Christine S, Hoek, Wim Z, Baneschi, Ilaria, Bouwman, Annerieke, Brogan, Eilis, Ramsey, Christopher Bronk, Collins, James A, de Bruijn, Renee, Haliuc, Aritina, Heiri, Oliver, Hubay, Katalin, Jones, Gwydion, Jones, Vivienne, Laug, Andreas, Merkt, Josef, Muschitiello, Francesco, Müller, Meike, Peters, Tom, Peterse, Francien, Pueschel, Ashley, Staff, Richard A, ter Schure, Anneke, van den Bos, Valerie, Wagner-Cremer, Frederike
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 2024
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author Engels, Stefan
Lane, Christine S
Hoek, Wim Z
Baneschi, Ilaria
Bouwman, Annerieke
Brogan, Eilis
Ramsey, Christopher Bronk
Collins, James A
de Bruijn, Renee
Haliuc, Aritina
Heiri, Oliver
Hubay, Katalin
Jones, Gwydion
Jones, Vivienne
Laug, Andreas
Merkt, Josef
Muschitiello, Francesco
Müller, Meike
Peters, Tom
Peterse, Francien
Pueschel, Ashley
Staff, Richard A
ter Schure, Anneke
van den Bos, Valerie
Wagner-Cremer, Frederike
author_facet Engels, Stefan
Lane, Christine S
Hoek, Wim Z
Baneschi, Ilaria
Bouwman, Annerieke
Brogan, Eilis
Ramsey, Christopher Bronk
Collins, James A
de Bruijn, Renee
Haliuc, Aritina
Heiri, Oliver
Hubay, Katalin
Jones, Gwydion
Jones, Vivienne
Laug, Andreas
Merkt, Josef
Muschitiello, Francesco
Müller, Meike
Peters, Tom
Peterse, Francien
Pueschel, Ashley
Staff, Richard A
ter Schure, Anneke
van den Bos, Valerie
Wagner-Cremer, Frederike
collection Datos científicos de ciencias marinas y ambientales
contents This dataset provides delta-Deuterium data for the Lateglacial sediment sequence retrieved from Lake Hämelsee (Germany) in 2013. Compound-specific hydrogen isotope ratios (expressed as δD) normalized to the Vienna Standard Mean Ocean Water (VSMOW) as well as measurement uncertainties (expressed as SD) are presented against both depth (m) and age (cal yr. BP). The data provides information on the Lateglacial development of local climate dynamics: the plant-wax derived δD signal is typically considered to reflect the hydrogen-isotopic composition of plant leaf water and, by extension, precipitation. We therefore interpret the trends in δD record here as an indicator of past hydrological change (cf Sachse et al., 2012). A total of 167 samples from the Lateglacial section of the core were processed using a Dionex 350 accelerated solvent extraction (ASE) system. Solid phase extraction (SPE) was used to separate the extracts into an aliphatic, aromatic and alcohol/fatty acid fraction. Prior to isotope ratio measurement, the aliphatic fraction was further fractionated on a Pasteur pipette column containing activated AgNO3 (10%) coated silica gel. Compound-specific hydrogen isotope ratios (expressed as δD) were subsequently measured on an isotope ratio mass spectrometer. All δD values are normalized to the Vienna Standard Mean Ocean Water (VSMOW) scale using a linear regression function between measured and certified δD values of a standard mix. We refer to Rach et al. (2020) for further details on the exact analytical setup. All measurements were performed in the laboratories of GeoForschungsZentrum Potsdam.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_964525
institution PANGAEA
language en
publishDate 2024
publisher PANGAEA
record_format pangaea
spellingShingle δDeuterium measurements of selected n-alkanes (corrected to the VSMOW scale) in sediment core Haem13 from lake Hämelsee
Engels, Stefan
Lane, Christine S
Hoek, Wim Z
Baneschi, Ilaria
Bouwman, Annerieke
Brogan, Eilis
Ramsey, Christopher Bronk
Collins, James A
de Bruijn, Renee
Haliuc, Aritina
Heiri, Oliver
Hubay, Katalin
Jones, Gwydion
Jones, Vivienne
Laug, Andreas
Merkt, Josef
Muschitiello, Francesco
Müller, Meike
Peters, Tom
Peterse, Francien
Pueschel, Ashley
Staff, Richard A
ter Schure, Anneke
van den Bos, Valerie
Wagner-Cremer, Frederike
AGE; alkanes; Biodiversity; Chironomidae; DEPTH, sediment/rock; deuterium; diatoms; ecosystem dynamics; GDGTs; Germany; Haemelsee; Haemelsee_Haem13; Isotope ratio mass spectrometer (IRMS); Lake Haemelsee, Germany; LOI; n-Alkane C23, δD; n-Alkane C23, δD, standard deviation; n-Alkane C25, δD; n-Alkane C25, δD, standard deviation; n-Alkane C27, δD; n-Alkane C27, δD, standard deviation; n-Alkane C29, δD; n-Alkane C29, δD, standard deviation; n-Alkane C31, δD; n-Alkane C31, δD, standard deviation; Niederreiter Piston corer; NPC; ORDINAL NUMBER; Pediastrum; XRF; δ Deuterium, n-alkanes
This dataset provides delta-Deuterium data for the Lateglacial sediment sequence retrieved from Lake Hämelsee (Germany) in 2013. Compound-specific hydrogen isotope ratios (expressed as δD) normalized to the Vienna Standard Mean Ocean Water (VSMOW) as well as measurement uncertainties (expressed as SD) are presented against both depth (m) and age (cal yr. BP). The data provides information on the Lateglacial development of local climate dynamics: the plant-wax derived δD signal is typically considered to reflect the hydrogen-isotopic composition of plant leaf water and, by extension, precipitation. We therefore interpret the trends in δD record here as an indicator of past hydrological change (cf Sachse et al., 2012). A total of 167 samples from the Lateglacial section of the core were processed using a Dionex 350 accelerated solvent extraction (ASE) system. Solid phase extraction (SPE) was used to separate the extracts into an aliphatic, aromatic and alcohol/fatty acid fraction. Prior to isotope ratio measurement, the aliphatic fraction was further fractionated on a Pasteur pipette column containing activated AgNO3 (10%) coated silica gel. Compound-specific hydrogen isotope ratios (expressed as δD) were subsequently measured on an isotope ratio mass spectrometer. All δD values are normalized to the Vienna Standard Mean Ocean Water (VSMOW) scale using a linear regression function between measured and certified δD values of a standard mix. We refer to Rach et al. (2020) for further details on the exact analytical setup. All measurements were performed in the laboratories of GeoForschungsZentrum Potsdam.
title δDeuterium measurements of selected n-alkanes (corrected to the VSMOW scale) in sediment core Haem13 from lake Hämelsee
topic AGE; alkanes; Biodiversity; Chironomidae; DEPTH, sediment/rock; deuterium; diatoms; ecosystem dynamics; GDGTs; Germany; Haemelsee; Haemelsee_Haem13; Isotope ratio mass spectrometer (IRMS); Lake Haemelsee, Germany; LOI; n-Alkane C23, δD; n-Alkane C23, δD, standard deviation; n-Alkane C25, δD; n-Alkane C25, δD, standard deviation; n-Alkane C27, δD; n-Alkane C27, δD, standard deviation; n-Alkane C29, δD; n-Alkane C29, δD, standard deviation; n-Alkane C31, δD; n-Alkane C31, δD, standard deviation; Niederreiter Piston corer; NPC; ORDINAL NUMBER; Pediastrum; XRF; δ Deuterium, n-alkanes
url https://doi.org/10.1594/PANGAEA.964525