Major and trace elements in surface inputs to Deming Lake, MN, USA (2022-2023)

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Auteurs principaux: Rico, Kathryn, Ostrander, Chadlin, Heard, Andrew, Swanner, Elizabeth
Format: Dataset Open Access
Langue:en
Publié: PANGAEA 2024
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_version_ 1867170432005701632
author Rico, Kathryn
Ostrander, Chadlin
Heard, Andrew
Swanner, Elizabeth
author_facet Rico, Kathryn
Ostrander, Chadlin
Heard, Andrew
Swanner, Elizabeth
collection Datos científicos de ciencias marinas y ambientales
contents Several sites around Itasca State Park that are potentially representative of input sources to Deming Lake were sampled in August 2023. Water from a bog on the southeast margin of Deming Lake represent surface inputs, and water from springs along Nicollet Creek, and from Elk Spring on the margins of Elk Lake represent regional groundwaters. These were sampled with syringes fit 0.22 μm syringe filters, waters were acidified at the University of Minnesota Itasca Biological Station. Water elemental compositions were determined using a Thermo Fisher iCAP-Q inductively coupled plasma mass spectrometer (ICP-MS) at the WHOI Plasma Facility following 200 dilution of a 10 μL aliquot in 2 % HNO3. Indium (In) was added to samples at a concentration of 1 ng/g prior to analyses to monitor and correct for instrument drift by normalizing to In intensities. Concentrations were calculated using a five-point calibration curve obtained by fitting of ion beam intensities measured for serial dilutions of a gravimetrically prepared multi-element standard. The relative standard deviation (RSD) for five measurements of each sample was ~10% on the iCAP-Q. The accuracy and precision of similar concentration measurements on iCAP-Q at WHOI have previously been determined to be ± 5-10 % (1SD) based on comparison with USGS reference materials AGV-1, AGV-2, BHVO-1, BHVO-2, BIR-1, and BCR-2 prepared and analyzed as unknowns during earlier runs (Jochum et al., 2016; Shu et al., 2017).
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_971080
institution PANGAEA
language en
publishDate 2024
publisher PANGAEA
record_format pangaea
spellingShingle Major and trace elements in surface inputs to Deming Lake, MN, USA (2022-2023)
Rico, Kathryn
Ostrander, Chadlin
Heard, Andrew
Swanner, Elizabeth
Aluminium, dissolved; Barium, dissolved; Cadmium, dissolved; Calcium, dissolved; Cerium, dissolved; Chromium, dissolved; Cobalt, dissolved; Copper, dissolved; DATE/TIME; Deming Lake, Minnesota; DL_Aug2023_Surface-Inputs_0.22; DL_TraceElements_2022-2023; Dysprosium, dissolved; Erbium, dissolved; Europium, dissolved; Gadolinium, dissolved; Holmium, dissolved; Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific Inc., iCAP Q; Iron, dissolved; Lake; Lake sediment; lake water; Lanthanum, dissolved; LATITUDE; Lead, dissolved; Lithium, dissolved; Location; LONGITUDE; Lutetium, dissolved; Magnesum, dissolved; Manganese, dissolved; Molybdenum, dissolved; Neodymium, dissolved; Nickel, dissolved; Phosphorus, dissolved; Praseodymium, dissolved; Precambrian analog; Samarium, dissolved; Sampling on land; Scandium, dissolved; snow-ice; Strontium, dissolved; Syringe, plastic; Terbium, dissolved; Thallium, dissolved; Thorium, dissolved; Thulium, dissolved; Titanium, dissolved; trace elements; Uranium, dissolved; Vanadium, dissolved; Ytterbium, dissolved; Yttrium, dissolved; Zinc, dissolved
Several sites around Itasca State Park that are potentially representative of input sources to Deming Lake were sampled in August 2023. Water from a bog on the southeast margin of Deming Lake represent surface inputs, and water from springs along Nicollet Creek, and from Elk Spring on the margins of Elk Lake represent regional groundwaters. These were sampled with syringes fit 0.22 μm syringe filters, waters were acidified at the University of Minnesota Itasca Biological Station. Water elemental compositions were determined using a Thermo Fisher iCAP-Q inductively coupled plasma mass spectrometer (ICP-MS) at the WHOI Plasma Facility following 200 dilution of a 10 μL aliquot in 2 % HNO3. Indium (In) was added to samples at a concentration of 1 ng/g prior to analyses to monitor and correct for instrument drift by normalizing to In intensities. Concentrations were calculated using a five-point calibration curve obtained by fitting of ion beam intensities measured for serial dilutions of a gravimetrically prepared multi-element standard. The relative standard deviation (RSD) for five measurements of each sample was ~10% on the iCAP-Q. The accuracy and precision of similar concentration measurements on iCAP-Q at WHOI have previously been determined to be ± 5-10 % (1SD) based on comparison with USGS reference materials AGV-1, AGV-2, BHVO-1, BHVO-2, BIR-1, and BCR-2 prepared and analyzed as unknowns during earlier runs (Jochum et al., 2016; Shu et al., 2017).
title Major and trace elements in surface inputs to Deming Lake, MN, USA (2022-2023)
topic Aluminium, dissolved; Barium, dissolved; Cadmium, dissolved; Calcium, dissolved; Cerium, dissolved; Chromium, dissolved; Cobalt, dissolved; Copper, dissolved; DATE/TIME; Deming Lake, Minnesota; DL_Aug2023_Surface-Inputs_0.22; DL_TraceElements_2022-2023; Dysprosium, dissolved; Erbium, dissolved; Europium, dissolved; Gadolinium, dissolved; Holmium, dissolved; Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific Inc., iCAP Q; Iron, dissolved; Lake; Lake sediment; lake water; Lanthanum, dissolved; LATITUDE; Lead, dissolved; Lithium, dissolved; Location; LONGITUDE; Lutetium, dissolved; Magnesum, dissolved; Manganese, dissolved; Molybdenum, dissolved; Neodymium, dissolved; Nickel, dissolved; Phosphorus, dissolved; Praseodymium, dissolved; Precambrian analog; Samarium, dissolved; Sampling on land; Scandium, dissolved; snow-ice; Strontium, dissolved; Syringe, plastic; Terbium, dissolved; Thallium, dissolved; Thorium, dissolved; Thulium, dissolved; Titanium, dissolved; trace elements; Uranium, dissolved; Vanadium, dissolved; Ytterbium, dissolved; Yttrium, dissolved; Zinc, dissolved
url https://doi.org/10.1594/PANGAEA.971080