Organic carbon content, stable carbon isotope ratios, and lignin phenol fingerprint of terrestrial material deposited at the paleo-delta of the Lena River at the transition to the Preboreal

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Main Authors: Sabino, Mathia, Gustafsson, Örjan, Wild, Birgit, Semiletov, Igor P, Dudarev, Oleg V, Ingrosso, Gianmarco, Tesi, Tommaso
Format: Dataset Open Access
Language:en
Published: PANGAEA 2024
Subjects:
3,5-dihydroxybenzoic acid/vanillyl phenols ratio; 3,5-dihydroxybenzoic acid per unit mass organic carbon; 77DN20140705; Acetosyringone per unit mass organic carbon; Acetovanillone per unit mass organic carbon; Arctic; Carbon, organic, total; Cinnamyl phenols/vanillyl phenols ratio; Cinnamyl phenols per unit mass organic carbon; Date/Time of event; Deglaciation; DEPTH, sediment/rock; Depth, sediment/rock, bottom/maximum; Depth, top/min; Elevation of event; Event label; Ferulic acid per unit mass organic carbon; Gas chromatography (GC, Agilent 7890A) equipped with a mass selective detector (MSD, Agilent 5975C) and a flame ionization detector (FID, Agilent 7683B); Isotope ratio mass spectrometer, Thermo, DeltaQ; coupled to an Elemental Analyzer; Thermo Flash 2000 via a ConFlo IV; Latitude of event; Lena River, Lena Delta, Siberia, Russia; Longitude of event; Methane; Oden; PC; p-Coumaric acid per unit mass organic carbon; Permafrost; p-Hydroxyacetophenone/p-hydroxyl phenols ratio; p-Hydroxyacetophenone per unit mass organic carbon; p-Hydroxybenzaldehyde per unit mass organic carbon; p-Hydroxybenzoic acid per unit mass organic carbon; p-Hydroxyl phenols/vanillyl phenols ratio; p-Hydroxyl phenols per unit mass organic carbon; Piston corer; Sample code/label; SWERUS-C3; SWERUS-C3_PC23; Syringaldehyde per unit mass organic carbon; Syringic acid/syringaldehyde ratio; Syringic acid per unit mass organic carbon; Syringyl phenols/vanillyl phenols ratio; Syringyl phenols per unit mass organic carbon; Vanillic acid/vanillin ratio; Vanillic acid per unit mass organic carbon; Vanillin per unit mass organic carbon; Vanillyl phenols per unit mass organic carbon; δ13C
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_version_ 1867169162762125312
author Sabino, Mathia
Gustafsson, Örjan
Wild, Birgit
Semiletov, Igor P
Dudarev, Oleg V
Ingrosso, Gianmarco
Tesi, Tommaso
author_facet Sabino, Mathia
Gustafsson, Örjan
Wild, Birgit
Semiletov, Igor P
Dudarev, Oleg V
Ingrosso, Gianmarco
Tesi, Tommaso
collection Datos científicos de ciencias marinas y ambientales
contents The dataset was used to reconstruct the release of permafrost organic carbon from the watershed of the Lena River (Russia) between 11.1 and 11.7 calibrated thousand years Before Present (cal. kyr BP, Present = 1950 AD) and to model potential methane emissions from this carbon source. Data were obtained analyzing plant debris isolated from the low density fraction (<1.8 g/cm3) of muddy sediments from the Piston Core 23 (PC23). The sediment core was retrieved in July 2014 in the mid/outer-shelf of the Laptev Sea shelf (76° 10' 15.6''N; 129° 20' 13.2''E, water depth of 56 m) during Leg 1 of the SWERUS-C3 expedition (Swedish-Russian-U.S. Arctic Ocean – Investigation of Climate-Cryosphere-Carbon interactions). Measurement of total organic carbon (TOC) and stable (d¹³C) carbon isotopes were performed on 0.3 to 0.7 mg of samples on February 2022 using a Thermo DeltaQ isotope-ratio mass spectrometer (IRMS) coupled to a Thermo Flash 2000 Elemental Analyzer via a ConFlo IV interface at the at the Institute of Polar Sciences from the National Research Council of Italy (Bologna Section, Italy). The methodology for sample preparation followed Nieuwenhuize et al. (1994). Data on biomarkers (lignin phenols) were obtained extracting 2 to 3 mg of samples using a Microwave Accelerated Reaction System (MARS) 5 from CEM and following the methodology from Goñi & Montgomery (2000). The extracts were analysed using a Agilent 7890A gas chromatograph (GC) coupled to an Agilent 5975C mass spectrometer to identify and quantify the compounds of interest. Biomarkers extraction and analyses were carried out on March 2022 in the organic chemistry laboratories of the Ente Nazionale Idrocarburi (ENI)-National Research Council (CNR) of Italy Joint Research Center "Aldo Pontremoli" (Lecce, Italy). Stable isotope ratios and biomarkers were used to gain insights on the main vegetation source of the plant debris and (biomarkers only) to investigate the degradation state of the terrestrial material.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_972409
institution PANGAEA
language en
publishDate 2024
publisher PANGAEA
record_format pangaea
spellingShingle Organic carbon content, stable carbon isotope ratios, and lignin phenol fingerprint of terrestrial material deposited at the paleo-delta of the Lena River at the transition to the Preboreal
Sabino, Mathia
Gustafsson, Örjan
Wild, Birgit
Semiletov, Igor P
Dudarev, Oleg V
Ingrosso, Gianmarco
Tesi, Tommaso
3,5-dihydroxybenzoic acid/vanillyl phenols ratio; 3,5-dihydroxybenzoic acid per unit mass organic carbon; 77DN20140705; Acetosyringone per unit mass organic carbon; Acetovanillone per unit mass organic carbon; Arctic; Carbon, organic, total; Cinnamyl phenols/vanillyl phenols ratio; Cinnamyl phenols per unit mass organic carbon; Date/Time of event; Deglaciation; DEPTH, sediment/rock; Depth, sediment/rock, bottom/maximum; Depth, top/min; Elevation of event; Event label; Ferulic acid per unit mass organic carbon; Gas chromatography (GC, Agilent 7890A) equipped with a mass selective detector (MSD, Agilent 5975C) and a flame ionization detector (FID, Agilent 7683B); Isotope ratio mass spectrometer, Thermo, DeltaQ; coupled to an Elemental Analyzer; Thermo Flash 2000 via a ConFlo IV; Latitude of event; Lena River, Lena Delta, Siberia, Russia; Longitude of event; Methane; Oden; PC; p-Coumaric acid per unit mass organic carbon; Permafrost; p-Hydroxyacetophenone/p-hydroxyl phenols ratio; p-Hydroxyacetophenone per unit mass organic carbon; p-Hydroxybenzaldehyde per unit mass organic carbon; p-Hydroxybenzoic acid per unit mass organic carbon; p-Hydroxyl phenols/vanillyl phenols ratio; p-Hydroxyl phenols per unit mass organic carbon; Piston corer; Sample code/label; SWERUS-C3; SWERUS-C3_PC23; Syringaldehyde per unit mass organic carbon; Syringic acid/syringaldehyde ratio; Syringic acid per unit mass organic carbon; Syringyl phenols/vanillyl phenols ratio; Syringyl phenols per unit mass organic carbon; Vanillic acid/vanillin ratio; Vanillic acid per unit mass organic carbon; Vanillin per unit mass organic carbon; Vanillyl phenols per unit mass organic carbon; δ13C
The dataset was used to reconstruct the release of permafrost organic carbon from the watershed of the Lena River (Russia) between 11.1 and 11.7 calibrated thousand years Before Present (cal. kyr BP, Present = 1950 AD) and to model potential methane emissions from this carbon source. Data were obtained analyzing plant debris isolated from the low density fraction (<1.8 g/cm3) of muddy sediments from the Piston Core 23 (PC23). The sediment core was retrieved in July 2014 in the mid/outer-shelf of the Laptev Sea shelf (76° 10' 15.6''N; 129° 20' 13.2''E, water depth of 56 m) during Leg 1 of the SWERUS-C3 expedition (Swedish-Russian-U.S. Arctic Ocean – Investigation of Climate-Cryosphere-Carbon interactions). Measurement of total organic carbon (TOC) and stable (d¹³C) carbon isotopes were performed on 0.3 to 0.7 mg of samples on February 2022 using a Thermo DeltaQ isotope-ratio mass spectrometer (IRMS) coupled to a Thermo Flash 2000 Elemental Analyzer via a ConFlo IV interface at the at the Institute of Polar Sciences from the National Research Council of Italy (Bologna Section, Italy). The methodology for sample preparation followed Nieuwenhuize et al. (1994). Data on biomarkers (lignin phenols) were obtained extracting 2 to 3 mg of samples using a Microwave Accelerated Reaction System (MARS) 5 from CEM and following the methodology from Goñi & Montgomery (2000). The extracts were analysed using a Agilent 7890A gas chromatograph (GC) coupled to an Agilent 5975C mass spectrometer to identify and quantify the compounds of interest. Biomarkers extraction and analyses were carried out on March 2022 in the organic chemistry laboratories of the Ente Nazionale Idrocarburi (ENI)-National Research Council (CNR) of Italy Joint Research Center "Aldo Pontremoli" (Lecce, Italy). Stable isotope ratios and biomarkers were used to gain insights on the main vegetation source of the plant debris and (biomarkers only) to investigate the degradation state of the terrestrial material.
title Organic carbon content, stable carbon isotope ratios, and lignin phenol fingerprint of terrestrial material deposited at the paleo-delta of the Lena River at the transition to the Preboreal
topic 3,5-dihydroxybenzoic acid/vanillyl phenols ratio; 3,5-dihydroxybenzoic acid per unit mass organic carbon; 77DN20140705; Acetosyringone per unit mass organic carbon; Acetovanillone per unit mass organic carbon; Arctic; Carbon, organic, total; Cinnamyl phenols/vanillyl phenols ratio; Cinnamyl phenols per unit mass organic carbon; Date/Time of event; Deglaciation; DEPTH, sediment/rock; Depth, sediment/rock, bottom/maximum; Depth, top/min; Elevation of event; Event label; Ferulic acid per unit mass organic carbon; Gas chromatography (GC, Agilent 7890A) equipped with a mass selective detector (MSD, Agilent 5975C) and a flame ionization detector (FID, Agilent 7683B); Isotope ratio mass spectrometer, Thermo, DeltaQ; coupled to an Elemental Analyzer; Thermo Flash 2000 via a ConFlo IV; Latitude of event; Lena River, Lena Delta, Siberia, Russia; Longitude of event; Methane; Oden; PC; p-Coumaric acid per unit mass organic carbon; Permafrost; p-Hydroxyacetophenone/p-hydroxyl phenols ratio; p-Hydroxyacetophenone per unit mass organic carbon; p-Hydroxybenzaldehyde per unit mass organic carbon; p-Hydroxybenzoic acid per unit mass organic carbon; p-Hydroxyl phenols/vanillyl phenols ratio; p-Hydroxyl phenols per unit mass organic carbon; Piston corer; Sample code/label; SWERUS-C3; SWERUS-C3_PC23; Syringaldehyde per unit mass organic carbon; Syringic acid/syringaldehyde ratio; Syringic acid per unit mass organic carbon; Syringyl phenols/vanillyl phenols ratio; Syringyl phenols per unit mass organic carbon; Vanillic acid/vanillin ratio; Vanillic acid per unit mass organic carbon; Vanillin per unit mass organic carbon; Vanillyl phenols per unit mass organic carbon; δ13C
url https://doi.org/10.1594/PANGAEA.972409