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Main Authors: Wong, Wanyee, Risebrobakken, Bjørg, Ödalen, Malin, Tisserand, Amandine, Fahl, Kirsten, Stein, Ruediger, Jansen, Eystein
Format: Dataset Open Access
Language:en
Published: PANGAEA 2025
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Online Access:https://doi.org/10.1594/PANGAEA.980706
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author Wong, Wanyee
Risebrobakken, Bjørg
Ödalen, Malin
Tisserand, Amandine
Fahl, Kirsten
Stein, Ruediger
Jansen, Eystein
author_facet Wong, Wanyee
Risebrobakken, Bjørg
Ödalen, Malin
Tisserand, Amandine
Fahl, Kirsten
Stein, Ruediger
Jansen, Eystein
collection Datos científicos de ciencias marinas y ambientales
contents We present a biomarker dataset from marine sediment core MD99-2304, retrieved from the eastern Fram Strait (77°37'15.6N, 9°56'54E) at a water depth of 1348 m. The core was collected using a piston corer during the Marion Dufresne IMAGES 5 expedition (leg MD114) in 1999. This dataset provides sea ice extent in the eastern Fram Strait between 40 and 33.5 ka b2k, covering a period within Marine Isotope Stage 3 (MIS 3). With a temporal resolution of 20–40 years per sample, it contributes to the mechanical understanding of abrupt climate change during Dansgaard-Oeschger (D-O) events. The biomarker analysis was conducted at the Alfred Wegener Institute (AWI), Germany, in 2022 and 2023. The measured biomarkers include Total Organic Carbon (TOC) (%), Highly Branched Isoprenoids (HBIs) IP25, HBI diene, HBI-III (Z-isomer), and HBI III (E-isomer), and the sterols brassicasterol, dinosterol, campesterol, and sitosterol (μg/TOC). Biomarker measurements were performed using an Agilent 7890B Gas Chromatograph (GC) equipped with a 30 m DB-1MS column (0.25 mm i.d., 0.25 µm film thickness) and coupled to an Agilent 5977A mass selective detector (MSD, 70 eV constant ionization potential, Scan 50–550 m/z, 1 scan/s, ion source temperature 230°C, Performance Turbo Pump), with selected ion monitoring mode (SIM) for HBIs and full scan mode (50-550 m/Z) for sterols. The balance factors (c) for PIP25 indices are 2.82 for PIIIIP25 (IP25-HBI-III (Z)), 0.025 for PBIP25 (IP25-brassicasterol), and 0.044 for PDIP25 (IP25-dinosterol). TOC measurement was conducted using a Leco CS-125 Carbon-Sulfur Analyzer. The age model of MD99-2304 is established by tuning low field magnetic susceptibility to the magnetic susceptibility of Core MD95-2010 from the Norwegian Sea (Kissel et al., 1999); updated in Sadatzki et al. (2020), and the age model of MD95-2010 was tied to the chronology of MD99-2284 (Berben et al., 2020). The age model for MD99-2304 was established by tuning its low-field magnetic susceptibility to that of core MD95-2010 from the Norwegian Sea (Kissel et al., 1999; Sadatzki et al., 2020). The chronology of MD95-2010 was further tied to core MD99-2284 (Berben et al., 2020), ensuring a robust age framework for the dataset.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_980706
institution PANGAEA
language en
publishDate 2025
publisher PANGAEA
record_format pangaea
spellingShingle Biomarker results from the eastern Fram Strait between 40 and 33.5 ka b2k
Wong, Wanyee
Risebrobakken, Bjørg
Ödalen, Malin
Tisserand, Amandine
Fahl, Kirsten
Stein, Ruediger
Jansen, Eystein
(9E)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbon; (9Z)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbon; 2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyl)pentadecane, per unit mass total organic carbon; 24-ethylcholest-5-en-3beta-ol, per unit mass total organic carbon; 24-Methylcholest-5-en-3beta-ol, per unit mass total organic carbon; 24-Methylcholesta-5,22E-dien-3beta-ol, per unit mass total organic carbon; 3280N; 4alpha,23,24-Trimethyl-5alpha-cholest-22E-en-3beta-ol, per unit mass total organic carbon; ABRUPT; ABRUPT Arctic Climate Change; Age; Arctic; CALYPSO; Calypso Corer; Carbon, organic, total; Depth, corrected; DEPTH, sediment/rock; Depth, sediment/rock, bottom/maximum; Depth, sediment/rock, top/minimum; Diene highly branched isoprenoids, per unit mass total organic carbon; Element analyser CHN, LECO CS 125; HBI III; ICP-OES (Agilent 720); IMAGES V; IP25; Marion Dufresne (1995); MD114; MD99-2304; MIS 3; Phytoplankton biomarker Brassicasterol IP25 index; Phytoplankton biomarker C25 HBI (Z) triene IP25 index; Phytoplankton biomarker Dinosterol IP25 index; Sample mass; Sea ice; Spitsbergen slope; Sterols, terrestrial, per unit mass total organic carbon
We present a biomarker dataset from marine sediment core MD99-2304, retrieved from the eastern Fram Strait (77°37'15.6N, 9°56'54E) at a water depth of 1348 m. The core was collected using a piston corer during the Marion Dufresne IMAGES 5 expedition (leg MD114) in 1999. This dataset provides sea ice extent in the eastern Fram Strait between 40 and 33.5 ka b2k, covering a period within Marine Isotope Stage 3 (MIS 3). With a temporal resolution of 20–40 years per sample, it contributes to the mechanical understanding of abrupt climate change during Dansgaard-Oeschger (D-O) events. The biomarker analysis was conducted at the Alfred Wegener Institute (AWI), Germany, in 2022 and 2023. The measured biomarkers include Total Organic Carbon (TOC) (%), Highly Branched Isoprenoids (HBIs) IP25, HBI diene, HBI-III (Z-isomer), and HBI III (E-isomer), and the sterols brassicasterol, dinosterol, campesterol, and sitosterol (μg/TOC). Biomarker measurements were performed using an Agilent 7890B Gas Chromatograph (GC) equipped with a 30 m DB-1MS column (0.25 mm i.d., 0.25 µm film thickness) and coupled to an Agilent 5977A mass selective detector (MSD, 70 eV constant ionization potential, Scan 50–550 m/z, 1 scan/s, ion source temperature 230°C, Performance Turbo Pump), with selected ion monitoring mode (SIM) for HBIs and full scan mode (50-550 m/Z) for sterols. The balance factors (c) for PIP25 indices are 2.82 for PIIIIP25 (IP25-HBI-III (Z)), 0.025 for PBIP25 (IP25-brassicasterol), and 0.044 for PDIP25 (IP25-dinosterol). TOC measurement was conducted using a Leco CS-125 Carbon-Sulfur Analyzer. The age model of MD99-2304 is established by tuning low field magnetic susceptibility to the magnetic susceptibility of Core MD95-2010 from the Norwegian Sea (Kissel et al., 1999); updated in Sadatzki et al. (2020), and the age model of MD95-2010 was tied to the chronology of MD99-2284 (Berben et al., 2020). The age model for MD99-2304 was established by tuning its low-field magnetic susceptibility to that of core MD95-2010 from the Norwegian Sea (Kissel et al., 1999; Sadatzki et al., 2020). The chronology of MD95-2010 was further tied to core MD99-2284 (Berben et al., 2020), ensuring a robust age framework for the dataset.
title Biomarker results from the eastern Fram Strait between 40 and 33.5 ka b2k
topic (9E)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbon; (9Z)-2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyliden)pentadeca-9-ene, per unit mass total organic carbon; 2,6,10,14-Tetramethyl-7-(3-methylpent-4-enyl)pentadecane, per unit mass total organic carbon; 24-ethylcholest-5-en-3beta-ol, per unit mass total organic carbon; 24-Methylcholest-5-en-3beta-ol, per unit mass total organic carbon; 24-Methylcholesta-5,22E-dien-3beta-ol, per unit mass total organic carbon; 3280N; 4alpha,23,24-Trimethyl-5alpha-cholest-22E-en-3beta-ol, per unit mass total organic carbon; ABRUPT; ABRUPT Arctic Climate Change; Age; Arctic; CALYPSO; Calypso Corer; Carbon, organic, total; Depth, corrected; DEPTH, sediment/rock; Depth, sediment/rock, bottom/maximum; Depth, sediment/rock, top/minimum; Diene highly branched isoprenoids, per unit mass total organic carbon; Element analyser CHN, LECO CS 125; HBI III; ICP-OES (Agilent 720); IMAGES V; IP25; Marion Dufresne (1995); MD114; MD99-2304; MIS 3; Phytoplankton biomarker Brassicasterol IP25 index; Phytoplankton biomarker C25 HBI (Z) triene IP25 index; Phytoplankton biomarker Dinosterol IP25 index; Sample mass; Sea ice; Spitsbergen slope; Sterols, terrestrial, per unit mass total organic carbon
url https://doi.org/10.1594/PANGAEA.980706