Dissolved and particulate trace metal and rare earth element (REE) concentrations during a mesocosm based phytoplankton bloom simulating intertidal coastal conditions
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| Natura: | Dataset Open Access |
| Lingua: | en |
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PANGAEA
2026
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| author | Mori, Corinna Striebel, Maren Brumsack, Hans-Jürgen Dittmar, Thorsten Mustaffa, Nur Ili Hamizah Liisa, Kallajoki Pahnke, Katharina |
| author_facet | Mori, Corinna Striebel, Maren Brumsack, Hans-Jürgen Dittmar, Thorsten Mustaffa, Nur Ili Hamizah Liisa, Kallajoki Pahnke, Katharina |
| collection | Datos científicos de ciencias marinas y ambientales |
| contents | We analyzed concentrations of dissolved and particulate trace metals, including iron (Fe), manganese (Mn), vanadium (V), molybdenum (Mo), thallium (Tl), and rare earth elements (REE), during a mesocosm-based phytoplankton summer bloom mimicking the intertidal zone of the southern North Sea (Jade Bay). The studies aimed to identify key drivers controlling their biogeochemical cycling in dynamic, high-productivity coastal environments. Our results highlight the tidally influenced coastal zone as a critical interface that alters the behavior of supposedly conservative elements such as Mo and Tl (Mori et al., 2021) as well as natural and anthropogenic REE (incl., lanthanum, samarium, and gadolinium) (Mori et al., under review). Trace metal concentrations and shale-normalized REE patterns, determined by quadrupole inductively coupled plasma–mass spectrometry (ICP-MS) and inductively coupled plasma–optical emission spectrometry (ICP-OES), were combined with biogeochemical bulk parameters and pigment-based assessments of phytoplankton growth and community composition (Mustaffa et al., 2020). Trace metal and REE cycling were evaluated in relation to phytoplankton dynamics, particulate organic matter composition (C, N, P), dissolved organic carbon, total dissolved nitrogen, and macronutrient concentrations (nitrate, ammonium, silicate, and inorganic phosphate). The dataset was obtained during a Planktotron-based mesocosm experiment conducted within the framework of the Coastal Ocean Darkening project (Mustaffa et al., 2020). |
| format | Dataset Open Access |
| id | pangaea_https___doi_org_10_1594_PANGAEA_990362 |
| institution | PANGAEA |
| language | en |
| publishDate | 2026 |
| publisher | PANGAEA |
| record_format | pangaea |
| spellingShingle | Dissolved and particulate trace metal and rare earth element (REE) concentrations during a mesocosm based phytoplankton bloom simulating intertidal coastal conditions Mori, Corinna Striebel, Maren Brumsack, Hans-Jürgen Dittmar, Thorsten Mustaffa, Nur Ili Hamizah Liisa, Kallajoki Pahnke, Katharina 9'-cis-Neoxanthin; Alloxanthin; all-trans-Zeaxanthin; Aluminium, particulate; Ammonium; Anthropogenic REE; beta-Cryptoxanthin; calculated after Kulaksiz and Bau (2013); Calculated using equation Ce/Ce*PAAS = CePAAS/(PrPAAS²/NdPAAS) of Lawrence et al. (2006); Carbon, organic, dissolved; Carbon, organic, particulate; Cerium, dissolved; Cerium, labile particulate; Cerium, particulate; Cerium, particulate, refractory; Cerium anomaly; Chlorophyll a; Chlorophyll b; Chlorophyll c1; Chlorophyll c2; coastal ecosystem; Coastal ocean darkening – Light availability in the past and future marine environment; COD; Day of experiment; Dysprosium, dissolved; Dysprosium, labile particulate; Dysprosium, particulate; Dysprosium, particulate, refractory; EcoMol; Elemental analyzer, Thermo Scientific, Flash EA 1112; Erbium, dissolved; Erbium, labile particulate; Erbium, particulate; Erbium, particulate, refractory; Europium, dissolved; Europium, labile particulate; Europium, particulate; Europium, particulate, refractory; Event label; Fucoxanthin; Gadolinium, dissolved; Gadolinium, labile particulate; Gadolinium, particulate; Gadolinium, particulate, refractory; Gadolinium anomaly; Handheld multiparameter instrument, WTW, Multi 250i; Heavy rare-earth elements; Heavy rare-earth elements/light rare-earth elements ratio; High-temperature catalytic combustion, Shimadzu, Shimadzu TOC-VCPH equipped with TDN unit; Holmium, dissolved; Holmium, labile particulate; Holmium, particulate; Holmium, particulate, refractory; Incubation type; Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific Inc., iCAP TQ; Inductively coupled plasma - mass spectrometry (ICP-MS), Thermo Finnigan, Element 2; Inductively coupled plasma optical emission spectrometer (ICP-OES), Thermo, iCAP 6000; Iron, dissolved; Iron, particulate; Jade_Bay_Mesocosm; Jade Bay; Lanthanum, dissolved; Lanthanum, labile particulate; Lanthanum, particulate; Lanthanum, particulate, refractory; Lanthanum anomaly; LATITUDE; Light rare-earth elements; LONGITUDE; Lutein; Lutetium, dissolved; Lutetium, labile particulate; Lutetium, particulate; Lutetium, particulate, refractory; Manganese, dissolved; Manganese, particulate; mesocosm; Middle rare-earth elements; Molybdenum, dissolved; Molybdenum, particulate; Neodymium, dissolved; Neodymium, labile particulate; Neodymium, particulate; Neodymium, particulate, refractory; Nitrate; Nitrite; Nitrogen, organic, particulate; Nitrogen, total dissolved; Nitrogen oxide; Peridinin; pH; PhD Research Training Group The Ecology of Molecules; Phosphorus, inorganic, dissolved; Phosphorus, organic, particulate; Phytoplankton; Phytoplankton bloom; Planktotron; Planktotrons; Praesodymium, particulate; Praseodymium, dissolved; Praseodymium, labile particulate; Praseodymium, particulate, refractory; Rare earth elements; Replicate; Salinity; Samarium, dissolved; Samarium, labile particulate; Samarium, particulate; Samarium, particulate, refractory; Samarium anomaly; Sample code/label; Sampling date/time, experiment; Silicate, dissolved; Spectrophotometer, Thermo Fisher Scientific, AquaMate Plus UV-VIS; Spectrophotometer, Thermo Fisher Scientific, Multiscan GO Microplate; Spectrophotometry using molybdate reaction after sulfuric acid digestion according to Grasshoff et al. (2009); Suspended particulate matter; Terbium, dissolved; Terbium, labile particulate; Terbium, particulate; Terbium, particulate, refractory; Thallium, dissolved; Thallium, particulate; Thulium, dissolved; Thulium, labile particulate; Thulium, particulate; Thulium, particulate, refractory; Trans-Echinenone; Triple-Quatrupole inductively coupled mass spectometry (ICP-MS, iCAP-TQ), Thermo Scientific; Type of study; Vanadium, dissolved; Vanadium, particulate; Violaxanthin; Ytterbium, dissolved; Ytterbium, labile particulate; Ytterbium, particulate; Ytterbium, particulate, refractory We analyzed concentrations of dissolved and particulate trace metals, including iron (Fe), manganese (Mn), vanadium (V), molybdenum (Mo), thallium (Tl), and rare earth elements (REE), during a mesocosm-based phytoplankton summer bloom mimicking the intertidal zone of the southern North Sea (Jade Bay). The studies aimed to identify key drivers controlling their biogeochemical cycling in dynamic, high-productivity coastal environments. Our results highlight the tidally influenced coastal zone as a critical interface that alters the behavior of supposedly conservative elements such as Mo and Tl (Mori et al., 2021) as well as natural and anthropogenic REE (incl., lanthanum, samarium, and gadolinium) (Mori et al., under review). Trace metal concentrations and shale-normalized REE patterns, determined by quadrupole inductively coupled plasma–mass spectrometry (ICP-MS) and inductively coupled plasma–optical emission spectrometry (ICP-OES), were combined with biogeochemical bulk parameters and pigment-based assessments of phytoplankton growth and community composition (Mustaffa et al., 2020). Trace metal and REE cycling were evaluated in relation to phytoplankton dynamics, particulate organic matter composition (C, N, P), dissolved organic carbon, total dissolved nitrogen, and macronutrient concentrations (nitrate, ammonium, silicate, and inorganic phosphate). The dataset was obtained during a Planktotron-based mesocosm experiment conducted within the framework of the Coastal Ocean Darkening project (Mustaffa et al., 2020). |
| title | Dissolved and particulate trace metal and rare earth element (REE) concentrations during a mesocosm based phytoplankton bloom simulating intertidal coastal conditions |
| topic | 9'-cis-Neoxanthin; Alloxanthin; all-trans-Zeaxanthin; Aluminium, particulate; Ammonium; Anthropogenic REE; beta-Cryptoxanthin; calculated after Kulaksiz and Bau (2013); Calculated using equation Ce/Ce*PAAS = CePAAS/(PrPAAS²/NdPAAS) of Lawrence et al. (2006); Carbon, organic, dissolved; Carbon, organic, particulate; Cerium, dissolved; Cerium, labile particulate; Cerium, particulate; Cerium, particulate, refractory; Cerium anomaly; Chlorophyll a; Chlorophyll b; Chlorophyll c1; Chlorophyll c2; coastal ecosystem; Coastal ocean darkening – Light availability in the past and future marine environment; COD; Day of experiment; Dysprosium, dissolved; Dysprosium, labile particulate; Dysprosium, particulate; Dysprosium, particulate, refractory; EcoMol; Elemental analyzer, Thermo Scientific, Flash EA 1112; Erbium, dissolved; Erbium, labile particulate; Erbium, particulate; Erbium, particulate, refractory; Europium, dissolved; Europium, labile particulate; Europium, particulate; Europium, particulate, refractory; Event label; Fucoxanthin; Gadolinium, dissolved; Gadolinium, labile particulate; Gadolinium, particulate; Gadolinium, particulate, refractory; Gadolinium anomaly; Handheld multiparameter instrument, WTW, Multi 250i; Heavy rare-earth elements; Heavy rare-earth elements/light rare-earth elements ratio; High-temperature catalytic combustion, Shimadzu, Shimadzu TOC-VCPH equipped with TDN unit; Holmium, dissolved; Holmium, labile particulate; Holmium, particulate; Holmium, particulate, refractory; Incubation type; Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific Inc., iCAP TQ; Inductively coupled plasma - mass spectrometry (ICP-MS), Thermo Finnigan, Element 2; Inductively coupled plasma optical emission spectrometer (ICP-OES), Thermo, iCAP 6000; Iron, dissolved; Iron, particulate; Jade_Bay_Mesocosm; Jade Bay; Lanthanum, dissolved; Lanthanum, labile particulate; Lanthanum, particulate; Lanthanum, particulate, refractory; Lanthanum anomaly; LATITUDE; Light rare-earth elements; LONGITUDE; Lutein; Lutetium, dissolved; Lutetium, labile particulate; Lutetium, particulate; Lutetium, particulate, refractory; Manganese, dissolved; Manganese, particulate; mesocosm; Middle rare-earth elements; Molybdenum, dissolved; Molybdenum, particulate; Neodymium, dissolved; Neodymium, labile particulate; Neodymium, particulate; Neodymium, particulate, refractory; Nitrate; Nitrite; Nitrogen, organic, particulate; Nitrogen, total dissolved; Nitrogen oxide; Peridinin; pH; PhD Research Training Group The Ecology of Molecules; Phosphorus, inorganic, dissolved; Phosphorus, organic, particulate; Phytoplankton; Phytoplankton bloom; Planktotron; Planktotrons; Praesodymium, particulate; Praseodymium, dissolved; Praseodymium, labile particulate; Praseodymium, particulate, refractory; Rare earth elements; Replicate; Salinity; Samarium, dissolved; Samarium, labile particulate; Samarium, particulate; Samarium, particulate, refractory; Samarium anomaly; Sample code/label; Sampling date/time, experiment; Silicate, dissolved; Spectrophotometer, Thermo Fisher Scientific, AquaMate Plus UV-VIS; Spectrophotometer, Thermo Fisher Scientific, Multiscan GO Microplate; Spectrophotometry using molybdate reaction after sulfuric acid digestion according to Grasshoff et al. (2009); Suspended particulate matter; Terbium, dissolved; Terbium, labile particulate; Terbium, particulate; Terbium, particulate, refractory; Thallium, dissolved; Thallium, particulate; Thulium, dissolved; Thulium, labile particulate; Thulium, particulate; Thulium, particulate, refractory; Trans-Echinenone; Triple-Quatrupole inductively coupled mass spectometry (ICP-MS, iCAP-TQ), Thermo Scientific; Type of study; Vanadium, dissolved; Vanadium, particulate; Violaxanthin; Ytterbium, dissolved; Ytterbium, labile particulate; Ytterbium, particulate; Ytterbium, particulate, refractory |
| url | https://doi.org/10.1594/PANGAEA.990362 |