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Main Authors: Chu, Yongzhi, Li, Xiaohu, Xie, Ruifang C, Conway, Tim M, Xu, Antao, Dong, Yanhui
Format: Dataset Open Access
Language:en
Published: PANGAEA 2026
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Online Access:https://doi.org/10.1594/PANGAEA.991015
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author Chu, Yongzhi
Li, Xiaohu
Xie, Ruifang C
Conway, Tim M
Xu, Antao
Dong, Yanhui
author_facet Chu, Yongzhi
Li, Xiaohu
Xie, Ruifang C
Conway, Tim M
Xu, Antao
Dong, Yanhui
collection Datos científicos de ciencias marinas y ambientales
contents Iron (Fe) is a key micronutrient regulating marine productivity and the global carbon cycle, yet reconstructing the relative contributions of different Fe sources through time remains challenging. Here we present high-resolution iron isotopic compositions (δ56Fe), measured by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), from a Fe-Mn crust sample (CXD31) recovered from the North Pacific Ocean, spanning the past ~23 Myr. The Fe isotopic values vary within the range of modern marine Fe sources, reflecting dynamic mixing among atmospheric dust, sedimentary inputs, and hydrothermal contributions. Using isotope mass-balance calculations, we reconstruct temporal changes in the relative importance of these Fe sources since the Miocene. Three intervals characterized by elevated δ56Fe values (~16.9, ~11.6, and ~2.7 Ma) indicate enhanced inputs of isotopically heavy Fe, which we attribute to increased aeolian dust supply linked to progressive aridification of inland Asia. These Fe isotope data provide a long-term record of Fe source variability in the North Pacific and offer new constraints on the coupling between continental climate evolution and oceanic Fe cycling.
format Dataset Open Access
id pangaea_https___doi_org_10_1594_PANGAEA_991015
institution PANGAEA
language en
publishDate 2026
publisher PANGAEA
record_format pangaea
spellingShingle Measured iron isotopic compositions of Fe-Mn crust sample CXD31
Chu, Yongzhi
Li, Xiaohu
Xie, Ruifang C
Conway, Tim M
Xu, Antao
Dong, Yanhui
Aeolian dust; Age; CXD31; Dredge, rock; DRG_R; DY105-12/14_CXD31; Ferromanganese crust; Iron biogeochemsitry; Isotopic fingerprinting; Marine geochemistry; Multiple-collector inductively coupled plasma mass spectrometer (MC-ICPMS); North Pacific; δ56Fe; δ56Fe, standard deviation
Iron (Fe) is a key micronutrient regulating marine productivity and the global carbon cycle, yet reconstructing the relative contributions of different Fe sources through time remains challenging. Here we present high-resolution iron isotopic compositions (δ56Fe), measured by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), from a Fe-Mn crust sample (CXD31) recovered from the North Pacific Ocean, spanning the past ~23 Myr. The Fe isotopic values vary within the range of modern marine Fe sources, reflecting dynamic mixing among atmospheric dust, sedimentary inputs, and hydrothermal contributions. Using isotope mass-balance calculations, we reconstruct temporal changes in the relative importance of these Fe sources since the Miocene. Three intervals characterized by elevated δ56Fe values (~16.9, ~11.6, and ~2.7 Ma) indicate enhanced inputs of isotopically heavy Fe, which we attribute to increased aeolian dust supply linked to progressive aridification of inland Asia. These Fe isotope data provide a long-term record of Fe source variability in the North Pacific and offer new constraints on the coupling between continental climate evolution and oceanic Fe cycling.
title Measured iron isotopic compositions of Fe-Mn crust sample CXD31
topic Aeolian dust; Age; CXD31; Dredge, rock; DRG_R; DY105-12/14_CXD31; Ferromanganese crust; Iron biogeochemsitry; Isotopic fingerprinting; Marine geochemistry; Multiple-collector inductively coupled plasma mass spectrometer (MC-ICPMS); North Pacific; δ56Fe; δ56Fe, standard deviation
url https://doi.org/10.1594/PANGAEA.991015