Aurovertins from a Marine-Derived Species and Nonenzymatic Reactions in Their Formation.

Fuente: PubMed
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Autori principali: Cheng, Shan, Xu, Yanchao, Kang, Meng, Zhu, Weiming, Wang, Liping, Fu, Peng
Natura: Artículo científico
Lingua:en
Pubblicazione: Journal of natural products 2025
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author Cheng, Shan
Xu, Yanchao
Kang, Meng
Zhu, Weiming
Wang, Liping
Fu, Peng
author_facet Cheng, Shan
Xu, Yanchao
Kang, Meng
Zhu, Weiming
Wang, Liping
Fu, Peng
Cheng, Shan
Xu, Yanchao
Kang, Meng
Zhu, Weiming
Wang, Liping
Fu, Peng
collection PubMed - marine biology
contents Aurovertins from a Marine-Derived Species and Nonenzymatic Reactions in Their Formation. Cheng, Shan Xu, Yanchao Kang, Meng Zhu, Weiming Wang, Liping Fu, Peng Penicillium Molecular Structure Aurovertins Marine Biology Biological Products Six new aurovertins (-) and a new citreoviridin derivative (), together with six known analogues (-), were isolated from the marine-derived sp. OUCMDZ-5930. Their structures were determined based on detailed spectroscopic analysis and ECD calculations. The putative nonenzymatic formation from citreoviridin to various aurovertins was presented, which was confirmed by chemical transformations. These results provide new insights into the formation mechanism of the 2,6-dioxabicyclo[3.2.1]octane ring system present in aurovertin-type natural products.
format Artículo científico
id pubmed_39862218
institution PubMed
language en
publishDate 2025
publisher Journal of natural products
record_format pubmed
spellingShingle Aurovertins from a Marine-Derived Species and Nonenzymatic Reactions in Their Formation.
Cheng, Shan
Xu, Yanchao
Kang, Meng
Zhu, Weiming
Wang, Liping
Fu, Peng
Penicillium
Molecular Structure
Aurovertins
Marine Biology
Biological Products
Aurovertins from a Marine-Derived Species and Nonenzymatic Reactions in Their Formation. Cheng, Shan Xu, Yanchao Kang, Meng Zhu, Weiming Wang, Liping Fu, Peng Penicillium Molecular Structure Aurovertins Marine Biology Biological Products Six new aurovertins (-) and a new citreoviridin derivative (), together with six known analogues (-), were isolated from the marine-derived sp. OUCMDZ-5930. Their structures were determined based on detailed spectroscopic analysis and ECD calculations. The putative nonenzymatic formation from citreoviridin to various aurovertins was presented, which was confirmed by chemical transformations. These results provide new insights into the formation mechanism of the 2,6-dioxabicyclo[3.2.1]octane ring system present in aurovertin-type natural products.
title Aurovertins from a Marine-Derived Species and Nonenzymatic Reactions in Their Formation.
topic Penicillium
Molecular Structure
Aurovertins
Marine Biology
Biological Products
url https://pubmed.ncbi.nlm.nih.gov/39862218/