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Autori principali: Zhou, Ying, Liang, Rongning, Qin, Wei
Natura: Artículo científico
Lingua:en
Pubblicazione: The Analyst 2025
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Accesso online:https://pubmed.ncbi.nlm.nih.gov/39980460/
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author Zhou, Ying
Liang, Rongning
Qin, Wei
author_facet Zhou, Ying
Liang, Rongning
Qin, Wei
Zhou, Ying
Liang, Rongning
Qin, Wei
collection PubMed - marine biology
contents Facile fabrication of anti-fouling polymeric membrane potentiometric ion sensors based on a biocide 4,5-dichloro-2--octyl-4-isothiazolin-3-one-containing self-adhesive waterborne polyurethane coating. Zhou, Ying Liang, Rongning Qin, Wei Potentiometry Polyurethanes Biofouling Thiazoles Ion-Selective Electrodes Disinfectants Membranes, Artificial Water Polymeric membrane ion-selective electrodes (ISEs) are a powerful tool for ion sensing. However, their application in complicated environmental water samples is still a challenge owing to the occurrence of electrode biofouling. To address this issue, we propose a facile and effective method for enhancing the anti-biofouling properties of these sensors. A self-adhesive coating based on waterborne polyurethane and biocide 4,5-dichloro-2--octyl-4-isothiazolin-3-one is prepared. The anti-fouling potentiometric ion sensor can be obtained by simply drop-casting such a self-adhesive coating. The classical poly(vinyl chloride) membrane-based Ca-ISE is chosen as a model. Compared to the unmodified pristine Ca-ISE, the obtained anti-fouling sensor exhibits remarkable improved anti-fouling properties such as a much lower adhesion rate of bacteria (96.8% reduction after modification), higher anti-microbial rate and superior anti-algal properties. More importantly, the proposed potentiometric sensor displays excellent long-term response stability even when immersed in real seawater or a solution with high levels of algae for 30 days. It is anticipated that this simple and flexible approach could be extended to fabricate other anti-fouling electrochemical or optical membrane sensors. This work may lay an important foundation for development of anti-fouling chemical sensors for environmental water monitoring.
format Artículo científico
id pubmed_39980460
institution PubMed
language en
publishDate 2025
publisher The Analyst
record_format pubmed
spellingShingle Facile fabrication of anti-fouling polymeric membrane potentiometric ion sensors based on a biocide 4,5-dichloro-2--octyl-4-isothiazolin-3-one-containing self-adhesive waterborne polyurethane coating.
Zhou, Ying
Liang, Rongning
Qin, Wei
Potentiometry
Polyurethanes
Biofouling
Thiazoles
Ion-Selective Electrodes
Disinfectants
Membranes, Artificial
Water
Facile fabrication of anti-fouling polymeric membrane potentiometric ion sensors based on a biocide 4,5-dichloro-2--octyl-4-isothiazolin-3-one-containing self-adhesive waterborne polyurethane coating. Zhou, Ying Liang, Rongning Qin, Wei Potentiometry Polyurethanes Biofouling Thiazoles Ion-Selective Electrodes Disinfectants Membranes, Artificial Water Polymeric membrane ion-selective electrodes (ISEs) are a powerful tool for ion sensing. However, their application in complicated environmental water samples is still a challenge owing to the occurrence of electrode biofouling. To address this issue, we propose a facile and effective method for enhancing the anti-biofouling properties of these sensors. A self-adhesive coating based on waterborne polyurethane and biocide 4,5-dichloro-2--octyl-4-isothiazolin-3-one is prepared. The anti-fouling potentiometric ion sensor can be obtained by simply drop-casting such a self-adhesive coating. The classical poly(vinyl chloride) membrane-based Ca-ISE is chosen as a model. Compared to the unmodified pristine Ca-ISE, the obtained anti-fouling sensor exhibits remarkable improved anti-fouling properties such as a much lower adhesion rate of bacteria (96.8% reduction after modification), higher anti-microbial rate and superior anti-algal properties. More importantly, the proposed potentiometric sensor displays excellent long-term response stability even when immersed in real seawater or a solution with high levels of algae for 30 days. It is anticipated that this simple and flexible approach could be extended to fabricate other anti-fouling electrochemical or optical membrane sensors. This work may lay an important foundation for development of anti-fouling chemical sensors for environmental water monitoring.
title Facile fabrication of anti-fouling polymeric membrane potentiometric ion sensors based on a biocide 4,5-dichloro-2--octyl-4-isothiazolin-3-one-containing self-adhesive waterborne polyurethane coating.
topic Potentiometry
Polyurethanes
Biofouling
Thiazoles
Ion-Selective Electrodes
Disinfectants
Membranes, Artificial
Water
url https://pubmed.ncbi.nlm.nih.gov/39980460/