Enregistré dans:
| Auteurs principaux: | , , , |
|---|---|
| Format: | Artículo científico |
| Langue: | en |
| Publié: |
The Journal of organic chemistry
2025
|
| Accès en ligne: | https://pubmed.ncbi.nlm.nih.gov/40611558/ |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|
Table des matières:
- Synthesis of Alkyl (-Benzyl)-Aryl Sulfoxides Enabled by Truce-Smiles Rearrangement. Zhang, Zhaoqing Zhang, Xinping Jia, Runyu Jia, Tiezheng An atom-economical and chemoselective synthesis of alkyl (-benzyl)-aryl sulfoxides has been developed. Sulfenate anions, which were generated by the Truce-Smiles rearrangement of heteroaryl (-alkyl)-aryl sulfoxides, have been trapped by primary alkyl halides to deliver the corresponding sulfoxides. A Truce-Smiles rearrangement/cyclization cascade has been designed to expand the scope of secondary cycloalkyl sulfoxides.