_version_ 1868266111382847489
author Chen, Xiangliu
Wong, Ini
Cong, Mengjing
Chen, Weihao
Jin, Meng
Wang, Hong
Chen, Fangfang
Zhang, Qingwen
Liu, Kechun
Liu, Yonghong
Wang, Rongchun
Wang, Junjian
Wang, Junfeng
author_facet Chen, Xiangliu
Wong, Ini
Cong, Mengjing
Chen, Weihao
Jin, Meng
Wang, Hong
Chen, Fangfang
Zhang, Qingwen
Liu, Kechun
Liu, Yonghong
Wang, Rongchun
Wang, Junjian
Wang, Junfeng
Chen, Xiangliu
Wong, Ini
Cong, Mengjing
Chen, Weihao
Jin, Meng
Wang, Hong
Chen, Fangfang
Zhang, Qingwen
Liu, Kechun
Liu, Yonghong
Wang, Rongchun
Wang, Junjian
Wang, Junfeng
collection PubMed - marine biology
contents Oxalicpyridones A-D, 2-pyridone alkaloids from a marine-derived fungus Penicillium oxalicum suppressing proliferation and metastasis against small cell lung cancer. Chen, Xiangliu Wong, Ini Cong, Mengjing Chen, Weihao Jin, Meng Wang, Hong Chen, Fangfang Zhang, Qingwen Liu, Kechun Liu, Yonghong Wang, Rongchun Wang, Junjian Wang, Junfeng Penicillium Humans Pyridones Animals Cell Proliferation Zebrafish Alkaloids Antineoplastic Agents Drug Screening Assays, Antitumor Lung Neoplasms Molecular Structure Small Cell Lung Carcinoma Apoptosis Structure-Activity Relationship Cell Line, Tumor Dose-Response Relationship, Drug Molecular Conformation To explore bioactive specialized metabolites from marine-derived fungi, four previously undescribed 2-pyridone alkaloids, oxalicpyridones A-D (1-4), two unreported tetramic acids, tolypocladenols G and H (5 and 6), together with five known 2-pyridone derivatives (7-11), were isolated from the marine-derived fungus Penicillium oxalicum SCSIO 41320. Their structures, including absolute configurations, were elucidated by extensive nuclear magnetic resonance (NMR) spectroscopic analysis, X-ray single-crystal diffraction, and calculations of electronic circular dichroism (ECD), C NMR, and optical rotation (OR). Additionally, oxalicpyridones A-C (1-3) inhibited the viability of several small-cell lung cancer (SCLC) cell lines in a dose-dependent manner. Among them, oxalicpyridone A (1) not only inhibited proliferation, induced apoptosis, and suppressed metastasis of SCLC cells in vitro, but also significantly inhibited the growth of SCLC cell-derived xenograft tumors in zebrafish in vivo. Collectively, these findings enrich the chemical diversity of marine-derived 2-pyridone alkaloids and provide potential lead compounds for anticancer drug discovery.
format Artículo científico
id pubmed_41397549
institution PubMed
language en
publishDate 2026
publisher Phytochemistry
record_format pubmed
spellingShingle Oxalicpyridones A-D, 2-pyridone alkaloids from a marine-derived fungus Penicillium oxalicum suppressing proliferation and metastasis against small cell lung cancer.
Chen, Xiangliu
Wong, Ini
Cong, Mengjing
Chen, Weihao
Jin, Meng
Wang, Hong
Chen, Fangfang
Zhang, Qingwen
Liu, Kechun
Liu, Yonghong
Wang, Rongchun
Wang, Junjian
Wang, Junfeng
Penicillium
Humans
Pyridones
Animals
Cell Proliferation
Zebrafish
Alkaloids
Antineoplastic Agents
Drug Screening Assays, Antitumor
Lung Neoplasms
Molecular Structure
Small Cell Lung Carcinoma
Apoptosis
Structure-Activity Relationship
Cell Line, Tumor
Dose-Response Relationship, Drug
Molecular Conformation
Oxalicpyridones A-D, 2-pyridone alkaloids from a marine-derived fungus Penicillium oxalicum suppressing proliferation and metastasis against small cell lung cancer. Chen, Xiangliu Wong, Ini Cong, Mengjing Chen, Weihao Jin, Meng Wang, Hong Chen, Fangfang Zhang, Qingwen Liu, Kechun Liu, Yonghong Wang, Rongchun Wang, Junjian Wang, Junfeng Penicillium Humans Pyridones Animals Cell Proliferation Zebrafish Alkaloids Antineoplastic Agents Drug Screening Assays, Antitumor Lung Neoplasms Molecular Structure Small Cell Lung Carcinoma Apoptosis Structure-Activity Relationship Cell Line, Tumor Dose-Response Relationship, Drug Molecular Conformation To explore bioactive specialized metabolites from marine-derived fungi, four previously undescribed 2-pyridone alkaloids, oxalicpyridones A-D (1-4), two unreported tetramic acids, tolypocladenols G and H (5 and 6), together with five known 2-pyridone derivatives (7-11), were isolated from the marine-derived fungus Penicillium oxalicum SCSIO 41320. Their structures, including absolute configurations, were elucidated by extensive nuclear magnetic resonance (NMR) spectroscopic analysis, X-ray single-crystal diffraction, and calculations of electronic circular dichroism (ECD), C NMR, and optical rotation (OR). Additionally, oxalicpyridones A-C (1-3) inhibited the viability of several small-cell lung cancer (SCLC) cell lines in a dose-dependent manner. Among them, oxalicpyridone A (1) not only inhibited proliferation, induced apoptosis, and suppressed metastasis of SCLC cells in vitro, but also significantly inhibited the growth of SCLC cell-derived xenograft tumors in zebrafish in vivo. Collectively, these findings enrich the chemical diversity of marine-derived 2-pyridone alkaloids and provide potential lead compounds for anticancer drug discovery.
title Oxalicpyridones A-D, 2-pyridone alkaloids from a marine-derived fungus Penicillium oxalicum suppressing proliferation and metastasis against small cell lung cancer.
topic Penicillium
Humans
Pyridones
Animals
Cell Proliferation
Zebrafish
Alkaloids
Antineoplastic Agents
Drug Screening Assays, Antitumor
Lung Neoplasms
Molecular Structure
Small Cell Lung Carcinoma
Apoptosis
Structure-Activity Relationship
Cell Line, Tumor
Dose-Response Relationship, Drug
Molecular Conformation
url https://pubmed.ncbi.nlm.nih.gov/41397549/