Thermodynamic properties of water desorption of forage turnip seeds

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Main Author: Kelly Aparecida De Sousa
Format: Artículo científico
Language:en
Published: Universidade Estadual de Maringá 2015
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author Kelly Aparecida De Sousa
author_facet Kelly Aparecida De Sousa
contents Thermodynamic properties of water desorption of forage turnip seeds Kelly Aparecida De Sousa Osvaldo Resende André Luis Duarte Goneli Thaís Adriana De Souza Smaniotto Daniel Emanuel Cabral de Oliveira Agrociencias isosteric heat gibbs free energy compensation theory Hygroscopic equilibrium The purpose of this study was to determine the thermodynamic properties of the process of water sorption in forage turnip seeds. The equilibrium moisture content of forage turnip seeds was determined by the gravimetric-dynamic method for different values of temperature and water activity. According to the results, increasing the moisture content increases the energy required for the evaporation of water in forage turnip seeds, and the values of integral isosteric heat of desorption, within the moisture content range of 3.33 to 11.30 (% d.b.), varies from 4,222.70 to 2,870.34 kJ kg-1. With the elevation in the equilibrium moisture content, there is an increase in differential entropy and Gibbs free energy, which has positive values, demonstrating non-spontaneity in the process of desorption in the seeds. The theory of enthalpy-entropy compensation can be satisfactorily applied to the sorption phenomenon, and the process of water desorption of forage turnip seeds is controlled by enthalpy. 2015 artículo científico 1679-9275 https://www.redalyc.org/articulo.oa?id=303033072002 en http://www.redalyc.org/revista.oa?id=3030 Acta Scientiarum. Agronomy application/pdf Universidade Estadual de Maringá Acta Scientiarum. Agronomy (Brasil) Num.1 Vol.37
format Artículo científico
id redalyc_303033072002
institution Redalyc
language en
publishDate 2015
publisher Universidade Estadual de Maringá
spellingShingle Thermodynamic properties of water desorption of forage turnip seeds
Kelly Aparecida De Sousa
Agrociencias
isosteric heat
gibbs free energy
compensation theory
Hygroscopic equilibrium
Thermodynamic properties of water desorption of forage turnip seeds Kelly Aparecida De Sousa Osvaldo Resende André Luis Duarte Goneli Thaís Adriana De Souza Smaniotto Daniel Emanuel Cabral de Oliveira Agrociencias isosteric heat gibbs free energy compensation theory Hygroscopic equilibrium The purpose of this study was to determine the thermodynamic properties of the process of water sorption in forage turnip seeds. The equilibrium moisture content of forage turnip seeds was determined by the gravimetric-dynamic method for different values of temperature and water activity. According to the results, increasing the moisture content increases the energy required for the evaporation of water in forage turnip seeds, and the values of integral isosteric heat of desorption, within the moisture content range of 3.33 to 11.30 (% d.b.), varies from 4,222.70 to 2,870.34 kJ kg-1. With the elevation in the equilibrium moisture content, there is an increase in differential entropy and Gibbs free energy, which has positive values, demonstrating non-spontaneity in the process of desorption in the seeds. The theory of enthalpy-entropy compensation can be satisfactorily applied to the sorption phenomenon, and the process of water desorption of forage turnip seeds is controlled by enthalpy. 2015 artículo científico 1679-9275 https://www.redalyc.org/articulo.oa?id=303033072002 en http://www.redalyc.org/revista.oa?id=3030 Acta Scientiarum. Agronomy application/pdf Universidade Estadual de Maringá Acta Scientiarum. Agronomy (Brasil) Num.1 Vol.37
title Thermodynamic properties of water desorption of forage turnip seeds
topic Agrociencias
isosteric heat
gibbs free energy
compensation theory
Hygroscopic equilibrium
url https://www.redalyc.org/articulo.oa?id=303033072002