Synergistic effect between oxides semiconductors and zeolites on photobleaching of RB250 textile dye

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Main Author: Jean César Marinozi Vicentini
Format: Artículo científico
Language:en
Published: Universidade Estadual de Maringá 2018
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author Jean César Marinozi Vicentini
author_facet Jean César Marinozi Vicentini
contents Synergistic effect between oxides semiconductors and zeolites on photobleaching of RB250 textile dye Jean César Marinozi Vicentini Gabriela Brunosi Medeiros Maria Clara Chimirri Watanabe Karen Raiane Piccoli Fernanda Carla Camilo Mara Heloisa Neves Olsen Scaliante Ingeniería NaA NaY ZnO TiO2 AOPs The present work aims to evaluate the activity of semiconductor oxides (TiO2, Nb2O5 and ZnO) supported on NaA and NaY zeolites, as well as their synergistic effect on Reactive Blue Dye (RB250) photodegradation process. Prior to deposition, TiO2 particles size was reduced by ultrasonic scattering followed by filtration. The particles on the filtrate were used to conduct the experiments. The semiconductors were immobilized in concentrations of 2.5, 5 and 10% (w w-1) and the photocatalytic tests were performed at catalyst concentrations of 1 and 2 g L-1. Moreover, supported catalysts were characterized by XRD, textural analysis, zero point of charge and temperature programmed desorption of NH3. A comparison between the supported catalysts showed high activity for the ones supported with ZnO and TiO2. Zeolite NaY has broader opened channels than NaA, which reduces the dye molecules blockage, and, as a result, increased the catalyst activity. A higher concentration of supported catalysts (2 g L-1) provides greater photocatalytic activity, while higher concentration of semiconductors immobilized on supports does not present significant differences. 2018 artículo científico 1806-2563 https://www.redalyc.org/articulo.oa?id=303258327049 https://www.redalyc.org/journal/3032/303258327049/ https://www.redalyc.org/journal/3032/303258327049/html/ https://www.redalyc.org/journal/3032/303258327049/303258327049.epub https://www.redalyc.org/journal/3032/303258327049/movil https://doi.org/10.4025/actascitechnol.v40i1.36553 en http://www.redalyc.org/revista.oa?id=3032 Acta Scientiarum. Technology application/pdf Universidade Estadual de Maringá Acta Scientiarum. Technology (Brasil) Vol.40
format Artículo científico
id redalyc_303258327049
institution Redalyc
language en
publishDate 2018
publisher Universidade Estadual de Maringá
spellingShingle Synergistic effect between oxides semiconductors and zeolites on photobleaching of RB250 textile dye
Jean César Marinozi Vicentini
Ingeniería
NaA
NaY
ZnO
TiO2
AOPs
Synergistic effect between oxides semiconductors and zeolites on photobleaching of RB250 textile dye Jean César Marinozi Vicentini Gabriela Brunosi Medeiros Maria Clara Chimirri Watanabe Karen Raiane Piccoli Fernanda Carla Camilo Mara Heloisa Neves Olsen Scaliante Ingeniería NaA NaY ZnO TiO2 AOPs The present work aims to evaluate the activity of semiconductor oxides (TiO2, Nb2O5 and ZnO) supported on NaA and NaY zeolites, as well as their synergistic effect on Reactive Blue Dye (RB250) photodegradation process. Prior to deposition, TiO2 particles size was reduced by ultrasonic scattering followed by filtration. The particles on the filtrate were used to conduct the experiments. The semiconductors were immobilized in concentrations of 2.5, 5 and 10% (w w-1) and the photocatalytic tests were performed at catalyst concentrations of 1 and 2 g L-1. Moreover, supported catalysts were characterized by XRD, textural analysis, zero point of charge and temperature programmed desorption of NH3. A comparison between the supported catalysts showed high activity for the ones supported with ZnO and TiO2. Zeolite NaY has broader opened channels than NaA, which reduces the dye molecules blockage, and, as a result, increased the catalyst activity. A higher concentration of supported catalysts (2 g L-1) provides greater photocatalytic activity, while higher concentration of semiconductors immobilized on supports does not present significant differences. 2018 artículo científico 1806-2563 https://www.redalyc.org/articulo.oa?id=303258327049 https://www.redalyc.org/journal/3032/303258327049/ https://www.redalyc.org/journal/3032/303258327049/html/ https://www.redalyc.org/journal/3032/303258327049/303258327049.epub https://www.redalyc.org/journal/3032/303258327049/movil https://doi.org/10.4025/actascitechnol.v40i1.36553 en http://www.redalyc.org/revista.oa?id=3032 Acta Scientiarum. Technology application/pdf Universidade Estadual de Maringá Acta Scientiarum. Technology (Brasil) Vol.40
title Synergistic effect between oxides semiconductors and zeolites on photobleaching of RB250 textile dye
topic Ingeniería
NaA
NaY
ZnO
TiO2
AOPs
url https://www.redalyc.org/articulo.oa?id=303258327049
https://www.redalyc.org/journal/3032/303258327049/
https://www.redalyc.org/journal/3032/303258327049/html/
https://www.redalyc.org/journal/3032/303258327049/303258327049.epub
https://www.redalyc.org/journal/3032/303258327049/movil
https://doi.org/10.4025/actascitechnol.v40i1.36553