A study of the factors that influence the interference of Fe (III) in the colourimetric analysis of Cr (VI), in polluted waters

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1. Verfasser: Silvia Castillo-Blum
Format: Artículo científico
Sprache:en
Veröffentlicht: Universidad Nacional Autónoma de México 1987
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author Silvia Castillo-Blum
author_facet Silvia Castillo-Blum
contents A study of the factors that influence the interference of Fe (III) in the colourimetric analysis of Cr (VI), in polluted waters Silvia Castillo-Blum Mario Villalobos-Peñalosa Margarita E. Gutiérrez-Ruiz Ciencias de la Tierra The interference of Fe(II1) in the photometric determination of Cr (VI) in water using thediphenylcarbazide method was studied, and the following factors which affected it wereanalyzed: pH, temperature, sequence in the addition of reagents, contact time betweenFe (111) and Cr (VI) before analysis, and elapsed time for colour development. The mostimportant factor proved to be the contact time, as at least one Fe (111)-Cr(V1) species isfonned, in basic, neutral or slightly acid medía. This fact explains the contradictionsfound in literature concerning the existence and magnitude of the interference. Therefore,the separation of Fe (111) or the use of other methods to analyze Cr (VI)-polluted waterswhich also contain Fe (III), is recommended. 1987 artículo científico 0188-4999 https://www.redalyc.org/articulo.oa?id=37030101 en http://www.redalyc.org/revista.oa?id=370 Revista Internacional de Contaminación Ambiental application/pdf Universidad Nacional Autónoma de México Revista Internacional de Contaminación Ambiental (México) Num.1 Vol.3
format Artículo científico
id redalyc_37030101
institution Redalyc
language en
publishDate 1987
publisher Universidad Nacional Autónoma de México
spellingShingle A study of the factors that influence the interference of Fe (III) in the colourimetric analysis of Cr (VI), in polluted waters
Silvia Castillo-Blum
Ciencias de la Tierra
A study of the factors that influence the interference of Fe (III) in the colourimetric analysis of Cr (VI), in polluted waters Silvia Castillo-Blum Mario Villalobos-Peñalosa Margarita E. Gutiérrez-Ruiz Ciencias de la Tierra The interference of Fe(II1) in the photometric determination of Cr (VI) in water using thediphenylcarbazide method was studied, and the following factors which affected it wereanalyzed: pH, temperature, sequence in the addition of reagents, contact time betweenFe (111) and Cr (VI) before analysis, and elapsed time for colour development. The mostimportant factor proved to be the contact time, as at least one Fe (111)-Cr(V1) species isfonned, in basic, neutral or slightly acid medía. This fact explains the contradictionsfound in literature concerning the existence and magnitude of the interference. Therefore,the separation of Fe (111) or the use of other methods to analyze Cr (VI)-polluted waterswhich also contain Fe (III), is recommended. 1987 artículo científico 0188-4999 https://www.redalyc.org/articulo.oa?id=37030101 en http://www.redalyc.org/revista.oa?id=370 Revista Internacional de Contaminación Ambiental application/pdf Universidad Nacional Autónoma de México Revista Internacional de Contaminación Ambiental (México) Num.1 Vol.3
title A study of the factors that influence the interference of Fe (III) in the colourimetric analysis of Cr (VI), in polluted waters
topic Ciencias de la Tierra
url https://www.redalyc.org/articulo.oa?id=37030101