Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium
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| Natura: | Artículo científico |
| Lingua: | en |
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Universidade Estadual Paulista Júlio de Mesquita Filho
2005
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| _version_ | 1876425512368209920 |
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| author | A. C .D. Angelo |
| author_facet | A. C .D. Angelo |
| contents | Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium A. C .D. Angelo S. M. A. Jorge N. R. Stradiotto Química mechanism electrochemistry sulfonyl compounds sulfinic acid and derivatives The electrochemical reduction of p-nitrobenzenesulfonyl chloride (NBSCl) in dimethylsulfoxide(DMSO) solution is used here as a model to investigate the role of sulfinic acid derivative in this compoundsglobal reduction process. Cyclic voltammetric experiments reveal the production of sulfinic acid derivative,which is important in chemical reactions involving the original compound and other intermediates. Thispaper also discusses the probable mechanisms of the reduction. 2005 artículo científico 0100-4670 https://www.redalyc.org/articulo.oa?id=42930307 en http://www.redalyc.org/revista.oa?id=429 Eclética Química application/pdf Universidade Estadual Paulista Júlio de Mesquita Filho Eclética Química (Brasil) Num.3 Vol.30 |
| format | Artículo científico |
| id | redalyc_42930307 |
| institution | Redalyc |
| language | en |
| publishDate | 2005 |
| publisher | Universidade Estadual Paulista Júlio de Mesquita Filho |
| spellingShingle | Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium A. C .D. Angelo Química mechanism electrochemistry sulfonyl compounds sulfinic acid and derivatives Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium A. C .D. Angelo S. M. A. Jorge N. R. Stradiotto Química mechanism electrochemistry sulfonyl compounds sulfinic acid and derivatives The electrochemical reduction of p-nitrobenzenesulfonyl chloride (NBSCl) in dimethylsulfoxide(DMSO) solution is used here as a model to investigate the role of sulfinic acid derivative in this compoundsglobal reduction process. Cyclic voltammetric experiments reveal the production of sulfinic acid derivative,which is important in chemical reactions involving the original compound and other intermediates. Thispaper also discusses the probable mechanisms of the reduction. 2005 artículo científico 0100-4670 https://www.redalyc.org/articulo.oa?id=42930307 en http://www.redalyc.org/revista.oa?id=429 Eclética Química application/pdf Universidade Estadual Paulista Júlio de Mesquita Filho Eclética Química (Brasil) Num.3 Vol.30 |
| title | Electrochemical evidence of sulfinic acid derivative as an intermediate in the reduction of aromatic sulfonyl chloride in an aprotic medium |
| topic | Química mechanism electrochemistry sulfonyl compounds sulfinic acid and derivatives |
| url | https://www.redalyc.org/articulo.oa?id=42930307 |