Synthesis and magnetic properties of heteronuclear 3d-4f compound

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Autore principale: B. Cristóvão
Natura: Artículo científico
Lingua:en
Pubblicazione: Universidade Estadual Paulista Júlio de Mesquita Filho 2007
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author B. Cristóvão
author_facet B. Cristóvão
contents Synthesis and magnetic properties of heteronuclear 3d-4f compound B. Cristóvão W. Ferenc Química 3d 4f compound magnetic moment heteronuclear compound magnetic susceptibility A novel heteronuclear 3d-4f compound having formula NdCu3L3·13H2O (whereH3L = Schiff base derived from 5-bromosalicylaldehyde and glycylglycine and L3–= C11H8N2O4Br) was obtained. It was characterized by elemental and thermal analysesand magnetic measurements. The Cu(II)–Nd(III) compound is stable up to 323 K. Duringdehydration process the water molecules are lost in two stages. The magnetic susceptibilitydata for this complex change with temperature according to the Curie-Weiss law withΘ = -35 K. The magnetic moment values decrease from 5.00μB at 303 K to 4.38μB at76 K. 2007 artículo científico 0100-4670 https://www.redalyc.org/articulo.oa?id=42932303 en http://www.redalyc.org/revista.oa?id=429 Eclética Química application/pdf Universidade Estadual Paulista Júlio de Mesquita Filho Eclética Química (Brasil) Num.3 Vol.32
format Artículo científico
id redalyc_42932303
institution Redalyc
language en
publishDate 2007
publisher Universidade Estadual Paulista Júlio de Mesquita Filho
spellingShingle Synthesis and magnetic properties of heteronuclear 3d-4f compound
B. Cristóvão
Química
3d
4f compound
magnetic moment
heteronuclear compound
magnetic susceptibility
Synthesis and magnetic properties of heteronuclear 3d-4f compound B. Cristóvão W. Ferenc Química 3d 4f compound magnetic moment heteronuclear compound magnetic susceptibility A novel heteronuclear 3d-4f compound having formula NdCu3L3·13H2O (whereH3L = Schiff base derived from 5-bromosalicylaldehyde and glycylglycine and L3–= C11H8N2O4Br) was obtained. It was characterized by elemental and thermal analysesand magnetic measurements. The Cu(II)–Nd(III) compound is stable up to 323 K. Duringdehydration process the water molecules are lost in two stages. The magnetic susceptibilitydata for this complex change with temperature according to the Curie-Weiss law withΘ = -35 K. The magnetic moment values decrease from 5.00μB at 303 K to 4.38μB at76 K. 2007 artículo científico 0100-4670 https://www.redalyc.org/articulo.oa?id=42932303 en http://www.redalyc.org/revista.oa?id=429 Eclética Química application/pdf Universidade Estadual Paulista Júlio de Mesquita Filho Eclética Química (Brasil) Num.3 Vol.32
title Synthesis and magnetic properties of heteronuclear 3d-4f compound
topic Química
3d
4f compound
magnetic moment
heteronuclear compound
magnetic susceptibility
url https://www.redalyc.org/articulo.oa?id=42932303