Blue thermoluminescence emission of annealed lithium rich aluminosilicates

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Auteur principal: V. Correcher
Format: Artículo científico
Langue:en
Publié: Sociedade Brasileira de Física 2010
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author V. Correcher
author_facet V. Correcher
contents Blue thermoluminescence emission of annealed lithium rich aluminosilicates V. Correcher Y. Rodriguez- Lazcano J. Garcia- Guinea E. Crespo- Feo Física, Astronomía y Matemáticas Phosphors aluminosilicates thermoluminescence The blue thermoluminescence (TL) emission of different thermally annealed (i) β-eucryptite (LiAlSiO4), (ii) virgilite-petalite (LiAlSi5O12) and (iii) virgilite-petalite-bikitaite (LiAlSi10O22) mixed crystals have been studied. The observed changes in the TL glow curves could be linked to simultaneous processes taking place in the lithium aluminosilicate lattice structure (phase transitions, consecutive breaking linking of bonds, alkali self-diffusion, redox reactions, etc). The stability of the TL signal after four months of storage performed at RT under red light, shows big differences between annealed (12 hours at 1200ºC) and non-annealed samples. The fading process in non-annealed samples can be fitted to a first-order decay mathematical expression; however preheated samples could not be reasonably fitted due to the highly dispersion detected. The changes observed in the X-ray diffractograms are in the intensity of the peaks that denote modifications in the degree of crystallinity and, in addition, there are some differences in the appeareance of new peaks that could suppose new phases (e.g. β-spodumene). 2010 artículo científico 0103-9733 https://www.redalyc.org/articulo.oa?id=46415798017 en http://www.redalyc.org/revista.oa?id=464 Brazilian Journal of Physics application/pdf Sociedade Brasileira de Física Brazilian Journal of Physics (Brasil) Num.3 Vol.40
format Artículo científico
id redalyc_46415798017
institution Redalyc
language en
publishDate 2010
publisher Sociedade Brasileira de Física
spellingShingle Blue thermoluminescence emission of annealed lithium rich aluminosilicates
V. Correcher
Física, Astronomía y Matemáticas
Phosphors
aluminosilicates
thermoluminescence
Blue thermoluminescence emission of annealed lithium rich aluminosilicates V. Correcher Y. Rodriguez- Lazcano J. Garcia- Guinea E. Crespo- Feo Física, Astronomía y Matemáticas Phosphors aluminosilicates thermoluminescence The blue thermoluminescence (TL) emission of different thermally annealed (i) β-eucryptite (LiAlSiO4), (ii) virgilite-petalite (LiAlSi5O12) and (iii) virgilite-petalite-bikitaite (LiAlSi10O22) mixed crystals have been studied. The observed changes in the TL glow curves could be linked to simultaneous processes taking place in the lithium aluminosilicate lattice structure (phase transitions, consecutive breaking linking of bonds, alkali self-diffusion, redox reactions, etc). The stability of the TL signal after four months of storage performed at RT under red light, shows big differences between annealed (12 hours at 1200ºC) and non-annealed samples. The fading process in non-annealed samples can be fitted to a first-order decay mathematical expression; however preheated samples could not be reasonably fitted due to the highly dispersion detected. The changes observed in the X-ray diffractograms are in the intensity of the peaks that denote modifications in the degree of crystallinity and, in addition, there are some differences in the appeareance of new peaks that could suppose new phases (e.g. β-spodumene). 2010 artículo científico 0103-9733 https://www.redalyc.org/articulo.oa?id=46415798017 en http://www.redalyc.org/revista.oa?id=464 Brazilian Journal of Physics application/pdf Sociedade Brasileira de Física Brazilian Journal of Physics (Brasil) Num.3 Vol.40
title Blue thermoluminescence emission of annealed lithium rich aluminosilicates
topic Física, Astronomía y Matemáticas
Phosphors
aluminosilicates
thermoluminescence
url https://www.redalyc.org/articulo.oa?id=46415798017