Ab Initio Calculation of the Dynamical Properties of PPP and PPV

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Autore principale: H. W. Leite Alves
Natura: Artículo científico
Lingua:en
Pubblicazione: Sociedade Brasileira de Física 2006
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author H. W. Leite Alves
author_facet H. W. Leite Alves
contents Ab Initio Calculation of the Dynamical Properties of PPP and PPV H. W. Leite Alves R. L. de Sousa Física, Astronomía y Matemáticas PPP and PPV Vibrational modes Ab initio calculation We have calculated the vibrational modes and frequencies of the crystalline PPP (in both the Pbam andPnnm symmetries) and PPV (in the P21/c symmetry). Our results are in good agreement with the availableexperimental data. Also, we have calculated the temperature dependence of their specific heats at constantvolume, and of their vibrational entropies. Based on our results, at high temperatures, the PPP is more stable inthe Pnnm structure than in the Pbam one. 2006 artículo científico 0103-9733 https://www.redalyc.org/articulo.oa?id=46436372 en http://www.redalyc.org/revista.oa?id=464 Brazilian Journal of Physics application/pdf Sociedade Brasileira de Física Brazilian Journal of Physics (Brasil) Num.2A Vol.36
format Artículo científico
id redalyc_46436372
institution Redalyc
language en
publishDate 2006
publisher Sociedade Brasileira de Física
spellingShingle Ab Initio Calculation of the Dynamical Properties of PPP and PPV
H. W. Leite Alves
Física, Astronomía y Matemáticas
PPP and PPV
Vibrational modes
Ab initio calculation
Ab Initio Calculation of the Dynamical Properties of PPP and PPV H. W. Leite Alves R. L. de Sousa Física, Astronomía y Matemáticas PPP and PPV Vibrational modes Ab initio calculation We have calculated the vibrational modes and frequencies of the crystalline PPP (in both the Pbam andPnnm symmetries) and PPV (in the P21/c symmetry). Our results are in good agreement with the availableexperimental data. Also, we have calculated the temperature dependence of their specific heats at constantvolume, and of their vibrational entropies. Based on our results, at high temperatures, the PPP is more stable inthe Pnnm structure than in the Pbam one. 2006 artículo científico 0103-9733 https://www.redalyc.org/articulo.oa?id=46436372 en http://www.redalyc.org/revista.oa?id=464 Brazilian Journal of Physics application/pdf Sociedade Brasileira de Física Brazilian Journal of Physics (Brasil) Num.2A Vol.36
title Ab Initio Calculation of the Dynamical Properties of PPP and PPV
topic Física, Astronomía y Matemáticas
PPP and PPV
Vibrational modes
Ab initio calculation
url https://www.redalyc.org/articulo.oa?id=46436372