USE OF ECUADORIAN NATURAL AND ACID-SURFACTANT MODIFIED ZEOLITES FOR REMEDIATION OF OIL- CONTAMINATED SOILS

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Main Author: Gladys-Cristina Pinto-Santamaría
Format: Artículo científico
Language:en
Published: ECOPETROL S.A. 2019
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author Gladys-Cristina Pinto-Santamaría
author_facet Gladys-Cristina Pinto-Santamaría
contents USE OF ECUADORIAN NATURAL AND ACID-SURFACTANT MODIFIED ZEOLITES FOR REMEDIATION OF OIL- CONTAMINATED SOILS Gladys-Cristina Pinto-Santamaría Carlos-Alberto Ríos-Reyes Luz-Yolanda Vargas-Fiallo Ingeniería Oil Soil Uptake Zeolite Absorbent Oil spills have been one of the greatest environmental problems worldwide. The contamination of soils due to oil spills generates an oil migration down the soil until reaching groundwater. The research focused on remediation of oil-contaminated soils by Ecuadorian natural and acid-surfactant modified zeolites of the Cayo Formation. The natural and modified zeolites were characterized by wavelength dispersive X-ray fluorescence, X-ray powder diffraction, environmental scanning electron microscopy, attenuated total reflectance Fourier transform infrared spectroscopy, and solid-state magic-angle spinning nuclear magnetic resonance spectroscopy. The natural and modified zeolites were added to an artificially oil-contaminated soil to immobilize and limit the uptake of contaminants by rape through changing soil physical and chemical properties in the pot experiment under greenhouse conditions. Several oil contaminated soil-zeolite mixes were tested in replicated laboratory analyses in terms of their ability to absorb oil. Results indicated that the addition of natural and modified zeolites could increase or decrease soil pH and absorption capacity, with high potential in removing oil from soil. Statistical analysis of the experimental data was performed by the variance test analysis. The absorption process had an efficiency of 46% under well-optimized experimental conditions, with an absorbent dose of 30-M, pH = 3.8 and 15 days of contact time. 2019 artículo científico 0122-5383 https://www.redalyc.org/articulo.oa?id=46570769009 https://www.redalyc.org/journal/465/46570769009/ https://www.redalyc.org/journal/465/46570769009/html/ https://www.redalyc.org/journal/465/46570769009/46570769009.epub https://www.redalyc.org/journal/465/46570769009/movil 10.29047/01225383.155 en http://www.redalyc.org/revista.oa?id=465 CT&F Ciencia, Tecnología y Futuro application/pdf ECOPETROL S.A. CT&F Ciencia, Tecnología y Futuro (Colombia) Num.1 Vol.9
format Artículo científico
id redalyc_46570769009
institution Redalyc
language en
publishDate 2019
publisher ECOPETROL S.A.
spellingShingle USE OF ECUADORIAN NATURAL AND ACID-SURFACTANT MODIFIED ZEOLITES FOR REMEDIATION OF OIL- CONTAMINATED SOILS
Gladys-Cristina Pinto-Santamaría
Ingeniería
Oil
Soil
Uptake
Zeolite
Absorbent
USE OF ECUADORIAN NATURAL AND ACID-SURFACTANT MODIFIED ZEOLITES FOR REMEDIATION OF OIL- CONTAMINATED SOILS Gladys-Cristina Pinto-Santamaría Carlos-Alberto Ríos-Reyes Luz-Yolanda Vargas-Fiallo Ingeniería Oil Soil Uptake Zeolite Absorbent Oil spills have been one of the greatest environmental problems worldwide. The contamination of soils due to oil spills generates an oil migration down the soil until reaching groundwater. The research focused on remediation of oil-contaminated soils by Ecuadorian natural and acid-surfactant modified zeolites of the Cayo Formation. The natural and modified zeolites were characterized by wavelength dispersive X-ray fluorescence, X-ray powder diffraction, environmental scanning electron microscopy, attenuated total reflectance Fourier transform infrared spectroscopy, and solid-state magic-angle spinning nuclear magnetic resonance spectroscopy. The natural and modified zeolites were added to an artificially oil-contaminated soil to immobilize and limit the uptake of contaminants by rape through changing soil physical and chemical properties in the pot experiment under greenhouse conditions. Several oil contaminated soil-zeolite mixes were tested in replicated laboratory analyses in terms of their ability to absorb oil. Results indicated that the addition of natural and modified zeolites could increase or decrease soil pH and absorption capacity, with high potential in removing oil from soil. Statistical analysis of the experimental data was performed by the variance test analysis. The absorption process had an efficiency of 46% under well-optimized experimental conditions, with an absorbent dose of 30-M, pH = 3.8 and 15 days of contact time. 2019 artículo científico 0122-5383 https://www.redalyc.org/articulo.oa?id=46570769009 https://www.redalyc.org/journal/465/46570769009/ https://www.redalyc.org/journal/465/46570769009/html/ https://www.redalyc.org/journal/465/46570769009/46570769009.epub https://www.redalyc.org/journal/465/46570769009/movil 10.29047/01225383.155 en http://www.redalyc.org/revista.oa?id=465 CT&F Ciencia, Tecnología y Futuro application/pdf ECOPETROL S.A. CT&F Ciencia, Tecnología y Futuro (Colombia) Num.1 Vol.9
title USE OF ECUADORIAN NATURAL AND ACID-SURFACTANT MODIFIED ZEOLITES FOR REMEDIATION OF OIL- CONTAMINATED SOILS
topic Ingeniería
Oil
Soil
Uptake
Zeolite
Absorbent
url https://www.redalyc.org/articulo.oa?id=46570769009
https://www.redalyc.org/journal/465/46570769009/
https://www.redalyc.org/journal/465/46570769009/html/
https://www.redalyc.org/journal/465/46570769009/46570769009.epub
https://www.redalyc.org/journal/465/46570769009/movil