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| Format: | Artículo científico |
| Language: | en |
| Published: |
Sociedad Química de México
2009
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| Online Access: | https://www.redalyc.org/articulo.oa?id=47512356003 |
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Table of Contents:
- Reactions of Vinylcyclopropane and Bicyclopropyl Compounds With Maleic Anhydride C. K. Jankowski A. Pelletier Eduardo Díaz Díaz Jacqueline M. R. Belanger J.R. J. Paré C. Lamouroux J. Boivin Multidisciplinaria (Ciencias Naturales y Exactas) Microwave thermal Diels Alder reactions diene precursors vinylcyclopropane as a diene Vinylcyclopropane and bicyclopropyl C6 compounds are studied as diene precursors in the Diels-Alder reaction. Their rearrangement under different thermal and microwave conditions leads to specific isomeric hexa-, penta- or butadienes, condensed with maleic anhydride as a dienophile. Adduct stereochemistries were compared to those of previously-synthesized model compounds, and are fully characterized with 2D NMR and GC-MS spectroscopies. Some unsaturated terpenes bearing vinylcyclopropane moieties were also condensed, and their adduct structures assigned. 2009 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47512356003 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.4 Vol.53