Nucleophilic Attack at the Pyridine Nitrogen Atom in a Bis(imino)pyridine System: The Local Hard and Soft Acids and Bases Principle Perspective
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| Formato: | Artículo científico |
| Lenguaje: | en |
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Sociedad Química de México
2012
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| _version_ | 1876480994734768128 |
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| author | Arlette Richaud |
| author_facet | Arlette Richaud |
| contents | Nucleophilic Attack at the Pyridine Nitrogen Atom in a Bis(imino)pyridine System: The Local Hard and Soft Acids and Bases Principle Perspective Arlette Richaud Francisco Méndez Multidisciplinaria (Ciencias Naturales y Exactas) bis(imino)Pyridines Nucleophilic reactivity Stereoelectronic Factors Motivated by the unprecedented nucleophilic attack at the pyridine nitrogen atom in bis(imino)pyridines, observed by Gambarotta et al. and Gibson et al., and the fact that normally pyridine undergoes reactions with electrophiles at its nitrogen atom, we applied the local hard and soft acids and bases principle to assert that nucleophilic attack at pyridine nitrogen atom depends fundamentally on stereoelectronic factors. 2012 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47524533019 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.3 Vol.56 |
| format | Artículo científico |
| id | redalyc_47524533019 |
| institution | Redalyc |
| language | en |
| publishDate | 2012 |
| publisher | Sociedad Química de México |
| spellingShingle | Nucleophilic Attack at the Pyridine Nitrogen Atom in a Bis(imino)pyridine System: The Local Hard and Soft Acids and Bases Principle Perspective Arlette Richaud Multidisciplinaria (Ciencias Naturales y Exactas) bis(imino)Pyridines Nucleophilic reactivity Stereoelectronic Factors Nucleophilic Attack at the Pyridine Nitrogen Atom in a Bis(imino)pyridine System: The Local Hard and Soft Acids and Bases Principle Perspective Arlette Richaud Francisco Méndez Multidisciplinaria (Ciencias Naturales y Exactas) bis(imino)Pyridines Nucleophilic reactivity Stereoelectronic Factors Motivated by the unprecedented nucleophilic attack at the pyridine nitrogen atom in bis(imino)pyridines, observed by Gambarotta et al. and Gibson et al., and the fact that normally pyridine undergoes reactions with electrophiles at its nitrogen atom, we applied the local hard and soft acids and bases principle to assert that nucleophilic attack at pyridine nitrogen atom depends fundamentally on stereoelectronic factors. 2012 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47524533019 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.3 Vol.56 |
| title | Nucleophilic Attack at the Pyridine Nitrogen Atom in a Bis(imino)pyridine System: The Local Hard and Soft Acids and Bases Principle Perspective |
| topic | Multidisciplinaria (Ciencias Naturales y Exactas) bis(imino)Pyridines Nucleophilic reactivity Stereoelectronic Factors |
| url | https://www.redalyc.org/articulo.oa?id=47524533019 |