New Palladium(II) Tetraorganodichalcogenoimido Diphosphinates. Crystal and Molecular Structure of Pd[(SPMe2)2N]2 and cis-Pd[(OPPh2)(SPMe2)N]2
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| Sprache: | en |
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Sociedad Química de México
2000
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| _version_ | 1876444887133454336 |
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| author | Danut Bilc |
| author_facet | Danut Bilc |
| contents | New Palladium(II) Tetraorganodichalcogenoimido Diphosphinates. Crystal and Molecular Structure of Pd[(SPMe2)2N]2 and cis-Pd[(OPPh2)(SPMe2)N]2 Danut Bilc Anca Silvestru Cristian Silvestru Ionel Haiduc John E. Drake Multidisciplinaria (Ciencias Naturales y Exactas) spiro bicyclic system ray diffractometry monometallic biconnective units Bis(tetraorganodichalcogenoimidodiphosphinato)palladium( II) Bis(tetraorganodichalcogenoimidodiphosphinato)palladium(II), Pd[(XPR2)(YPR2)N]2, were prepared and investigated bymeans of IR and multinuclear (1H, 13C, 31P) NMR spectroscopy. Thecrystal and molecular structures of Pd[(SPMe2)2N]2 (1) and cis-Pd[(OPPh2)(SPMe2)N]2 (2) were determined by X-ray diffractometry.The crystals of both compounds contain discrete mononuclear molecules.The ligands act as monometallic biconnective units throughboth chalcogen atoms which results in a spiro-bicyclic system withdistorted square planar PdS4 and PdS2O2 core, respectively. 2000 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47544211 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.44 |
| format | Artículo científico |
| id | redalyc_47544211 |
| institution | Redalyc |
| language | en |
| publishDate | 2000 |
| publisher | Sociedad Química de México |
| spellingShingle | New Palladium(II) Tetraorganodichalcogenoimido Diphosphinates. Crystal and Molecular Structure of Pd[(SPMe2)2N]2 and cis-Pd[(OPPh2)(SPMe2)N]2 Danut Bilc Multidisciplinaria (Ciencias Naturales y Exactas) spiro bicyclic system ray diffractometry monometallic biconnective units Bis(tetraorganodichalcogenoimidodiphosphinato)palladium( II) New Palladium(II) Tetraorganodichalcogenoimido Diphosphinates. Crystal and Molecular Structure of Pd[(SPMe2)2N]2 and cis-Pd[(OPPh2)(SPMe2)N]2 Danut Bilc Anca Silvestru Cristian Silvestru Ionel Haiduc John E. Drake Multidisciplinaria (Ciencias Naturales y Exactas) spiro bicyclic system ray diffractometry monometallic biconnective units Bis(tetraorganodichalcogenoimidodiphosphinato)palladium( II) Bis(tetraorganodichalcogenoimidodiphosphinato)palladium(II), Pd[(XPR2)(YPR2)N]2, were prepared and investigated bymeans of IR and multinuclear (1H, 13C, 31P) NMR spectroscopy. Thecrystal and molecular structures of Pd[(SPMe2)2N]2 (1) and cis-Pd[(OPPh2)(SPMe2)N]2 (2) were determined by X-ray diffractometry.The crystals of both compounds contain discrete mononuclear molecules.The ligands act as monometallic biconnective units throughboth chalcogen atoms which results in a spiro-bicyclic system withdistorted square planar PdS4 and PdS2O2 core, respectively. 2000 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47544211 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.44 |
| title | New Palladium(II) Tetraorganodichalcogenoimido Diphosphinates. Crystal and Molecular Structure of Pd[(SPMe2)2N]2 and cis-Pd[(OPPh2)(SPMe2)N]2 |
| topic | Multidisciplinaria (Ciencias Naturales y Exactas) spiro bicyclic system ray diffractometry monometallic biconnective units Bis(tetraorganodichalcogenoimidodiphosphinato)palladium( II) |
| url | https://www.redalyc.org/articulo.oa?id=47544211 |