Bromination of (AsPh2)2O: The Structure of Tribromo-Diphenylarsenic (V)
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| Format: | Artículo científico |
| Language: | en |
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Sociedad Química de México
2000
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| _version_ | 1876485803705630720 |
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| author | Luminita Silaghi Dumitrescu |
| author_facet | Luminita Silaghi Dumitrescu |
| contents | Bromination of (AsPh2)2O: The Structure of Tribromo-Diphenylarsenic (V) Luminita Silaghi Dumitrescu Ioan Silaghi Dumitrescu Radu Silaghi Dumitrescu Alexander J. Blake D. Bryan Sowerby Ionel Haiduc Multidisciplinaria (Ciencias Naturales y Exactas) Bromination tribromophenylarsenic (V) trigonal bipyramidal monomer Bromination of (AsPh2 )2O leads to cleavage of the oxobridgewith formation of the new organoarsenic (V) bromide,AsPh2Br3. A crystal structure determination shows that the compoundis a trigonal bipyramidal monomer with crystallographically imposedtwo-fold symmetry and one shorter, equatorial, and two longer, axialbromines. There are weak C-H...p and Br...Br intermolecular interactionsin the solid phase. 2000 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47544214 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.44 |
| format | Artículo científico |
| id | redalyc_47544214 |
| institution | Redalyc |
| language | en |
| publishDate | 2000 |
| publisher | Sociedad Química de México |
| spellingShingle | Bromination of (AsPh2)2O: The Structure of Tribromo-Diphenylarsenic (V) Luminita Silaghi Dumitrescu Multidisciplinaria (Ciencias Naturales y Exactas) Bromination tribromophenylarsenic (V) trigonal bipyramidal monomer Bromination of (AsPh2)2O: The Structure of Tribromo-Diphenylarsenic (V) Luminita Silaghi Dumitrescu Ioan Silaghi Dumitrescu Radu Silaghi Dumitrescu Alexander J. Blake D. Bryan Sowerby Ionel Haiduc Multidisciplinaria (Ciencias Naturales y Exactas) Bromination tribromophenylarsenic (V) trigonal bipyramidal monomer Bromination of (AsPh2 )2O leads to cleavage of the oxobridgewith formation of the new organoarsenic (V) bromide,AsPh2Br3. A crystal structure determination shows that the compoundis a trigonal bipyramidal monomer with crystallographically imposedtwo-fold symmetry and one shorter, equatorial, and two longer, axialbromines. There are weak C-H...p and Br...Br intermolecular interactionsin the solid phase. 2000 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47544214 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.44 |
| title | Bromination of (AsPh2)2O: The Structure of Tribromo-Diphenylarsenic (V) |
| topic | Multidisciplinaria (Ciencias Naturales y Exactas) Bromination tribromophenylarsenic (V) trigonal bipyramidal monomer |
| url | https://www.redalyc.org/articulo.oa?id=47544214 |