Infrared and Raman Spectra (Solid State) of Diamminediiodidecadmium (II) Complex with 15N and 2H Isotopic Subtitution
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| Format: | Artículo científico |
| Language: | en |
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Sociedad Química de México
2000
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| _version_ | 1876480891546501120 |
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| author | Claudio A. Téllez |
| author_facet | Claudio A. Téllez |
| contents | Infrared and Raman Spectra (Solid State) of Diamminediiodidecadmium (II) Complex with 15N and 2H Isotopic Subtitution Claudio A. Téllez Dilson N. Ishikawa Multidisciplinaria (Ciencias Naturales y Exactas) Infrared Raman spectra Force constants Diamminediiodidecadmium (II) isotopic complex The Raman and infrared spectra of the Cd(NH3)2I2 complexwith 15N and 2H substitution have been obtained in the solidstate. Based on a normal coordinate treatment as an eleven-bodyproblem, the vibrational spectra were assigned. With exclusion of theammine torsional vibration, the vibrational modes of the ligand,framework-coupling and skeletal frequencies have been determined.Valence force constants values fCdN and fCdI were compared with theanalogous force constants of Cd(NH3)2Cl2 and Cd(NH3)2Br2. Theresults of the calculations are discussed in terms of the presentassignment for Cd(NH3)2I2 and previously reported potential constantsfor the Cd(NH3)2X2 and Zn(NH3)2X2 (X = Cl, Br, I). 2000 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47544215 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.44 |
| format | Artículo científico |
| id | redalyc_47544215 |
| institution | Redalyc |
| language | en |
| publishDate | 2000 |
| publisher | Sociedad Química de México |
| spellingShingle | Infrared and Raman Spectra (Solid State) of Diamminediiodidecadmium (II) Complex with 15N and 2H Isotopic Subtitution Claudio A. Téllez Multidisciplinaria (Ciencias Naturales y Exactas) Infrared Raman spectra Force constants Diamminediiodidecadmium (II) isotopic complex Infrared and Raman Spectra (Solid State) of Diamminediiodidecadmium (II) Complex with 15N and 2H Isotopic Subtitution Claudio A. Téllez Dilson N. Ishikawa Multidisciplinaria (Ciencias Naturales y Exactas) Infrared Raman spectra Force constants Diamminediiodidecadmium (II) isotopic complex The Raman and infrared spectra of the Cd(NH3)2I2 complexwith 15N and 2H substitution have been obtained in the solidstate. Based on a normal coordinate treatment as an eleven-bodyproblem, the vibrational spectra were assigned. With exclusion of theammine torsional vibration, the vibrational modes of the ligand,framework-coupling and skeletal frequencies have been determined.Valence force constants values fCdN and fCdI were compared with theanalogous force constants of Cd(NH3)2Cl2 and Cd(NH3)2Br2. Theresults of the calculations are discussed in terms of the presentassignment for Cd(NH3)2I2 and previously reported potential constantsfor the Cd(NH3)2X2 and Zn(NH3)2X2 (X = Cl, Br, I). 2000 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47544215 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.44 |
| title | Infrared and Raman Spectra (Solid State) of Diamminediiodidecadmium (II) Complex with 15N and 2H Isotopic Subtitution |
| topic | Multidisciplinaria (Ciencias Naturales y Exactas) Infrared Raman spectra Force constants Diamminediiodidecadmium (II) isotopic complex |
| url | https://www.redalyc.org/articulo.oa?id=47544215 |