Crystal and Molecular Structure of 2-Aminoacetophenone- N(3)-dimethylthiosemicarbazone

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1. Verfasser: Amal A. Nassar
Format: Artículo científico
Sprache:en
Veröffentlicht: Sociedad Química de México 2002
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author Amal A. Nassar
author_facet Amal A. Nassar
contents Crystal and Molecular Structure of 2-Aminoacetophenone- N(3)-dimethylthiosemicarbazone Amal A. Nassar Simón Hernández Ortega Douglas X. West Jesús Valdés Martínez Multidisciplinaria (Ciencias Naturales y Exactas) Ray Crystal structure Thiosemicarbazones Condensation of N(3)-dimethylthiosemicarbazide with 2-aminoacetophenone in anhydrous ethanol produces 2-aminoacetophenone-N(3)-dimethylthiosemicarbazone, 1, which is planar withthe S1 and N1 atoms in a synconformation. The amino group forms abifurcated intramolecular hydrogen bond with the sulfur and theimine nitrogen, and an intermolecular hydrogen bond with the thionesulfur of a second molecule. 2002 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47546313 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.3 Vol.46
format Artículo científico
id redalyc_47546313
institution Redalyc
language en
publishDate 2002
publisher Sociedad Química de México
spellingShingle Crystal and Molecular Structure of 2-Aminoacetophenone- N(3)-dimethylthiosemicarbazone
Amal A. Nassar
Multidisciplinaria (Ciencias Naturales y Exactas)
Ray
Crystal structure
Thiosemicarbazones
Crystal and Molecular Structure of 2-Aminoacetophenone- N(3)-dimethylthiosemicarbazone Amal A. Nassar Simón Hernández Ortega Douglas X. West Jesús Valdés Martínez Multidisciplinaria (Ciencias Naturales y Exactas) Ray Crystal structure Thiosemicarbazones Condensation of N(3)-dimethylthiosemicarbazide with 2-aminoacetophenone in anhydrous ethanol produces 2-aminoacetophenone-N(3)-dimethylthiosemicarbazone, 1, which is planar withthe S1 and N1 atoms in a synconformation. The amino group forms abifurcated intramolecular hydrogen bond with the sulfur and theimine nitrogen, and an intermolecular hydrogen bond with the thionesulfur of a second molecule. 2002 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47546313 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.3 Vol.46
title Crystal and Molecular Structure of 2-Aminoacetophenone- N(3)-dimethylthiosemicarbazone
topic Multidisciplinaria (Ciencias Naturales y Exactas)
Ray
Crystal structure
Thiosemicarbazones
url https://www.redalyc.org/articulo.oa?id=47546313